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Kinetics of the Photolysis of Sodium Azide
The Journal of Chemical Physics, 1961The evolution of N2 from solid NaN3 during photolysis is shown to result from active sites located as deep as a few hundred lattice constants within the crystallites. These active sites diffuse to the free surface to produce N2, exhibiting a diffusion constant ∼10—15 cm2/sec.
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The thermal behaviour of sodium azide in zeolites
Thermochimica Acta, 1995Abstract Upon thermal treatment, NaN3-doped zeolite transforms stepwise. After endothermic dehydration, the NaN3 decomposes exothermically in air and under N2 flow. The temperature of decomposition is higher than that of the pure azide. Part of the sodium azide remains intact up to 1000 K. The process was also monitored by IR spectroscopy.
Imre Kiricsi +5 more
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Lattice Dynamics of Rhombohedral Sodium Azide
The Journal of Chemical Physics, 1972The external vibrational modes of rhombohedral NaN3 have been studied by means of normal mode calculations and inelastic neutron scattering measurements on powder samples. Phonon dispersion curves and displacement weighted frequency distributions have been computed using force-constant models in which the coupling parameters are determined by fitting ...
Hamid A. Rafizadeh +2 more
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Acute neurotoxicity of sodium azide and nitric oxide*1
Fundamental and Applied Toxicology, 1991Sodium azide is a chemical of rapidly growing commercial importance with a high acute toxicity and an unknown mechanism of action. Although it has some chemical properties and biological effects in common with cyanide, its lethality does not appear to be due to inhibition of cytochrome oxidase. Unlike cyanide it is a potent vasodilator and inhibitor of
Robert Kruszyna +3 more
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THERMAL DECOMPOSITION OF SODIUM AZIDE CRYSTALS
Canadian Journal of Chemistry, 1962not available
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Inactivation of lignin peroxidase by phenylhydrazine and sodium azide
Archives of Biochemistry and Biophysics, 1990Lignin peroxidase (LiP) is rapidly inactivated in a concentration-dependent manner by H2O2 and either phenylhydrazine or sodium azide. Full inactivation of isozyme 2b (H8) requires approximately 50 eq of phenylhydrazine or 80 eq of sodium azide. Anaerobic incubation of isozyme 2b with [14C]phenylhydrazine and H2O2 results in 77% loss of catalytic ...
Hiroyuki Wariishi +3 more
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ChemInform Abstract: Reduction of Aroyl Azides with Sodium Borohydride.
ChemInform, 1990AbstractThe benzoyl azides (I) are treated with sodium borohydride in methanol to produce mainly the benzylic alcohols (II), together with the benzamides (III).
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Fundamentals, status and promise of sodium-based batteries
Nature Reviews Materials, 2021Robert E Usiskin +2 more
exaly
Recycling of sodium-ion batteries
Nature Reviews Materials, 2023Yun Zhao, Naser Tavajohi Hassan Kiadeh
exaly
Accidental Exposures to Sodium Azide
American Journal of Clinical Pathology, 1974Robert J. Roberts +2 more
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