The product profile of enzymatically hydrolyzed PET can be modified by medium engineering and thereby adapted to a desired product. TPA, MHET or BHET can be forced as the predominant product using a basic pH (blue), 25 % ethylene glycol (EG) and IsPETasewt (green) or ≥25 % EG and LCCICCG (pink), respectively.
Tobias Heinks+8 more
wiley +1 more source
A multinuclear solid state NMR, density functional theory and X-Ray diffraction study of hydrogen bonding in Group I hydrogen dibenzoates [PDF]
An NMR crystallographic approach incorporating multinuclear solid state NMR (SSNMR), X-ray structure determinations and density functional theory (DFT) are used to characterise the H bonding arrangements in benzoic acid (BZA) and the corresponding Group ...
Alberth Lari+77 more
core +2 more sources
Increased calcification by erythrophagocytosis in aortic valvular interstitial cells
Abstract Background Calcific aortic valve disease (CAVD) progresses over time to severe aortic stenosis and eventually heart failure. Recent evidence indicates that intraleaflet haemorrhage (ILH) strongly promotes CAVD progression. However, it remains poorly understood how it mechanistically contributes to valvular calcification.
Zihan Qin+3 more
wiley +1 more source
1127 SODIUM BENZOATE IN THE TREATMENT OF HYPERAMMONEMIA IN NEWBORNS [PDF]
Benzoate is effective in increasing the excretion of urinary nitrogen in patients with hyperammonemia. In jaundiced newborns, however, the potential exists for benzoate, if present at high serum concentrations, to displace bilirubin from albumin binding sites and thereby increase the risk of bilirubin toxicity.
Bernard L. Mirkin, Thomas P. Green
openaire +2 more sources
The two novel Zn‐ and Co‐based coordination polymers with the redox‐active (H)PZDB−/2− linker exhibit oxidative color changes due to radical cation formation of the linker as confirmed by spectroelectrochemical analysis. The novel coordination polymers [Zn(PZDB)(DEF)2]n (Zn‐PZDB) and [Co(HPZDB)2(DEF)2]n (Co‐HPZDB) (H2PZDB = 4,4′‐(phenazine‐5,10‐diyl ...
Dietrich Püschel+10 more
wiley +1 more source
Mitigation of Mild Steel Corrosion in Acidic Solution Using Inhibitor
The inhibition efficiency of mild steel corrosion in HCl acidic solution containing various concentrations of mixed inhibitors were evaluated by conducting Tafel polarization and electrochemical impedance studies.
M. Vishnudevan
doaj +1 more source
The development of a micro technique for qualitative organic analysis [PDF]
Thesis (M.A.)--Boston ...
Rapport, Arthur
core +1 more source
Asymmetric Hydrogenation of 1-alkyl and 1-aryl vinyl benzoates: a broad scope procedure for the highly enantioselective synthesis of 1-substituted ethyl benzoates [PDF]
The enantioselective hydrogenation of enol esters of formula CH2=C(OBz)R with rhodium catalysts based on phosphine-phosphite ligands (P-OP) has been studied.
Cadierno, Victorio+4 more
core +1 more source
Transition Metal‐Free Carboxylation of Aryl Boronates in Supercritical CO2
Transition metal‐free carboxylation of aryl boronates catalyzed by ZnO is achieved by using supercritical CO2. Cage‐shaped cyclic trialkoxyboronates, which are both nucleophilic and soluble in supercritical CO2, undergo the carboxylation efficiently in supercritical CO2 at high pressure and temperature to give corresponding aromatic carboxylic acids ...
Jun Odake+2 more
wiley +1 more source
Effect of different stabilizers on the antibacterial activity of “ginger garlic paste”
The effect of five stabilizers i.e. citric acid, sodium metabisulfite, sodium benzoate, olive oil and ascorbic acid mixed in the ginger - garlic paste were evaluated against five pathogens (E.coli, Staphylococcus aureus, Salmonella typhi, Proteus ...
JK Shaista+3 more
doaj +1 more source