Results 101 to 110 of about 2,560 (205)

Solvatochromic parameters and linear solvation energy relationships for hydrolysis of hydroxamic acids

open access: yes, 2001
340-344Kinetic solvent effects on hydrolysis of hydroxamic acids of the type R.N (OH). C=O.R'[R=H; R'=CH3, C6H5, C6H4-OH; R=CH3-C6H4Rʹ = C6H5] in aqueous mixtures (10-70% v/v) of some polar protic, polar aprotic and low polarity basic solvents ...
Thakur, Santosh Singh   +2 more
core  

Solvatochromic Shifts in UV-Vis Absorption Spectra: The Challenging Case of 4-Nitropyridine N-Oxide

open access: yes, 2016
International audience4-Nitropyridine N-oxide is a well-known molecular probe for which the experimental UV/vis absorption spectrum has been measured in a large number of solvents.
Jacquemin, Denis   +14 more
core   +1 more source

Chromo- and fluorophoric water-soluble polymers and silica particles by nucleophilic substitution reaction of poly(vinyl amine)

open access: yesBeilstein Journal of Organic Chemistry, 2010
Novel chromophoric and fluorescent carbonitrile-functionalized poly(vinyl amine) (PVAm) and PVAm/silica particles were synthesized by means of nucleophilic aromatic substitution of 8-oxo-8H-acenaphtho[1,2-b]pyrrol-9-carbonitrile (1) with PVAm in water ...
Katja Hofmann   +3 more
doaj   +1 more source

Solvent Effects on the UV–vis Absorption and Emission of Optoelectronic Coumarins: a Comparison of Three Empirical Solvatochromic Models

open access: yes, 2016
Coumarins often function in the solution phase for a diverse range of optoelectronic applications. The associated solvent effects on the UV–vis absorption and/or fluorescence spectral shifts of coumarins need to be understood in order that their ...
Xiaogang Liu (367984)   +2 more
core   +1 more source

ارتباط بيانات تقسيم الأحماض الكربوكسيلية في أوساط من أنظمه الماء/ والمذيبات العضوية بعوامل التذوب ( Solvatochromic )

open access: yes, 1994
The partition coefficients of C2-Cg carboxylic acid monomeric forms between water and various organic solvents as well as the dimerization constants have been shown to be well correlated in terms of the solvatochromic parameters; cohesive energy density,
Hegazi, Mohamed F.   +1 more
core  

Solvatochromic Parameters of the Binary Mixtures of Imidazolium Chloride Ionic Liquid Plus Molecular Solvent [PDF]

open access: yes, 2014
Imidazolium-based chloride ionic liquids (ILs) have exhibited remarkable performance in several important applications such as biomass dissolution and extraction, but their large viscosity is a non-negligible problem.
Hu, Jingyi   +4 more
core  

Synthesis, Spectroscopic Studies, and Computational Analysis of a Solvatochromic Phthalocyanine Derivative

open access: yes, 2016
A near-IR absorbing phthalocyanine containing alkylthio and alyklamino substituents along the periphery was determined to have optical properties that vary depending on surrounding solvent environment.
Roberts, Jessica
core   +1 more source

Experimental and DFT computational studies on solvatochromism of alizarin

open access: yesResults in Chemistry
Herein, solvatochromic behavior and excited state dynamics of alizarin in different solvents are investigated using experimental and theoretical strategies. To quantify solvent-solute interactions, spectral data are analyzed using Bakhshiev, Kausky-Chama-
Hamidreza Jamshidi   +5 more
doaj   +1 more source

O Papel da agua (ou a sua ausencia) na formação de compostos ricos em energia nos sistemas biologicos [PDF]

open access: yes, 1997
Tese (Mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas.Uma das questões mais fascinantes que já foram levantadas pelos pesquisadores nas últimas décadas refere-se ao estudo dos compostos ricos em energia, tais ...
Machado, Vanderlei Gageiro
core  

The solvatochromic, spectral, and geometrical properties of nifenazone: A DFT/TD-DFT and experimental study

open access: yes, 2014
The solvatochromic, spectral, and geometrical properties of nifenazone (NIF), a pyrazole-nicotinamide drug, were experimentally and computationally investigated in several neat solvents and in hydro-organic binary systems such as water-acetonitrile and ...
Al-Balawi, Mona   +1 more
core   +1 more source

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