Results 31 to 40 of about 2,406 (182)

From Charge‐Transfer Adducts to (Tri)Halide‐Templated Supramolecular Cages: Covalent vs Ionic Products in the Reactions of Pyridin‐4‐ylthio‐Substituted Tetrathiafulvalene With Dihalogens and Interhalogens

Chemistry – A European Journal, EarlyView.
The reactions between tetra(pyridin‐4‐ylthio)tetrathiafulvalene and Br2/I2/ICl/IBr led to a variety of products, including a rare example of neutral 1:4 CT adduct and ionic products showing supramolecular cage motifs at (tri)halide templates. The nature of the reaction products was elucidated based on XRD analysis, Raman spectroscopy and QTAIM, NCI ...
Anna Caria, Stéphane A. Baudron, M. Carla Aragoni, Vito Lippolis, Anna Pintus, Enrico Podda, Massimiliano Arca   +6 more
wiley   +1 more source

Kinetic evaluation of the solvolysis of isobutyl chloro- and chlorothioformate esters

Beilstein Journal of Organic Chemistry, 2011
The specific rates of solvolysis of isobutyl chloroformate (1) are reported at 40.0 °C and those for isobutyl chlorothioformate (2) are reported at 25.0 °C, in a variety of pure and binary aqueous organic mixtures with wide ranging nucleophilicity and ...
Malcolm J. D’Souza, Matthew J. McAneny, Dennis N. Kevill, Jin Burm Kyong, Song Hee Choi   +4 more
doaj   +1 more source

Selective Modification of the Product Profile of Biocatalytic Hydrolyzed PET via Product‐Specific Medium Engineering

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
The product profile of enzymatically hydrolyzed PET can be modified by medium engineering and thereby adapted to a desired product. TPA, MHET or BHET can be forced as the predominant product using a basic pH (blue), 25 % ethylene glycol (EG) and IsPETasewt (green) or ≥25 % EG and LCCICCG (pink), respectively.
Tobias Heinks, Katrin Hofmann, Simon Last, Igor Gamm, Luise Blach, Ren Wei, Uwe T. Bornscheuer, Christof Hamel, Jan von Langermann   +8 more
wiley   +1 more source

Nonwoven rCF/PA6 Thermoplastic Composites: Hybrid Commingled Fibers vs. Powder Impregnation—Effects on Microstructure and Mechanical Properties

Polymer Composites, EarlyView.
Comparison of powder impregnation and hybrid commingled non‐wovens for PA6/rCF nonwoven composites. The two‐step powder route gives lower voids and higher properties, while the single‐step hybrid route is limited by precursor inhomogeneity and high void content.
Gaia Francesca Lupia, Tommaso Pini, Ilaria Rossitti, Sara Taherinezhad Tayebi, Marco Valente   +4 more
wiley   +1 more source

Investigation of Solvolysis Kinetics of New Synthesized Fluocinolone Acetonide C-21 Esters—An In Vitro Model for Prodrug Activation

Molecules, 2011
In this study the solvolysis of newly synthesized fluocinolone acetonide C-21 esters was analysed in comparison with fluocinonide during a 24-hour period of time.
Katarina D. Karljikovic-Rajic, Vladimir M. Savic, Olivera A. Cudina, Sote M. Vladimirov, Bojan D. Markovic, Vladimir D. Dobricic   +5 more
doaj   +1 more source

A Review of Advances in Composite Materials, Structural Optimization, and Machine Learning for Wind Turbine Blades: Challenges and Future Perspectives

Polymer Composites, EarlyView.
Overview of the holistic engineering lifecycle and core research pillars for wind turbine blades. ABSTRACT This paper reviews recent advancements across the lifecycle of wind turbine blades, focusing on three interconnected areas: advanced composites, structural optimization, and machine learning (ML) diagnostics. In materials, we highlight progress in
Kemal Hasirci, Denizhan Yavas, Alaeddin Burak Irez   +2 more
wiley   +1 more source

Radioimmunoassay of sulfated lithocholates

Journal of Lipid Research, 1977
A sensitive, rapid radioimmunoassay for sulfated species of lithocholic acid (sulfolithocholyglycine, sulfolithocholyltaurine, and sulfolithocholic acid) was developed and used to measure the total concentration of sulfated lithocholates in serum from ...
A E Cowen, M G Korman, A F Hofmann, J Turcotte, J A Carter   +4 more
doaj   +1 more source

solvolysis

, 2014
Citation: 'solvolysis' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.S05762 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Second‐Life Thermoset Manufacturing via Mild Solvolysis of Epoxy‐Matrix Composites and Wet‐Laid Mat Production

Polymer Composites, EarlyView.
From end‐of‐life pultruded CFRP profiles (1) to second life composites (7) through mild solvolysis (2,3), wet‐laid nonwoven mat fabrication (4), resin impregnation (5), and compression molding (6). ABSTRACT The growing use of carbon fiber–reinforced thermosets has led to the accumulation of significant composite waste, posing environmental and economic
Ehsan Zolfaghari, Fabian Rechsteiner, Violetta Schumm, Emanuela Muscolino, Sabina Alessi, Nadka Tz. Dintcheva, Clelia Dispenza   +6 more
wiley   +1 more source

Chemical Recycling as a Tool for Enabling a Second Life for Polyesters

SusMat, EarlyView.
This review presents the elucidation of the life cycle of main polyesters, detailing end‐of‐life methods, with focus of solvolysis technologies, then an analysis of LCA and TEA on literature data, an original data analytic, and, finally, a current industrial mapping of the main processes with a critical perspective on the plastic life‐cycle ecosystem ...
Nícolas Soares Urruth, Cristian de Oliveira Romera, Caio Gomide Otoni, Bruno Francisco Oechsler, Pedro Henrique Hermes de Araújo, Claudia Sayer   +5 more
wiley   +1 more source