First Evidence for Ozonido‐TMC Complexes of Iron and Cobalt
Reaction of ozone with iron(II) complexes [(TMC)Fe(OTf)]BArF, [(D12‐TMC)Fe(OTf)]BArF, and cobalt(II) complexes [(TMC)Co(OTf)]BArF, [(D12‐TMC)Co(X)]BArF (X = OTf, F) gives ozonido and oxido complexes at temperatures as low as –155°C in a 4:1 mixture of 2‐Me‐THF and THF. ABSTRACT We present compelling evidence for the first Fe‐ and Co‐ozonido complexes: [
Stefan Schaub +14 more
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Kim DH, Eckhert CD.
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Correction to "Chemical Synthesis of Functionalized Peptidomelanin for Groundwater Uranium Extraction". [PDF]
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Taoussi O +9 more
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Deep Ultraviolet Laser Ablation Electrospray Ion Mobility Mass Spectrometry. [PDF]
Hines KB, Feizi N, Solouki T, Murray KK.
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KO‐NH2 is a synthetic metallophore that preferentially binds Ga3+ over Fe3+ and is recognized by bacterial transporters. Photocrosslinking identifies CirA and Fiu as key uptake proteins in E. coli. KO‐NH2 enables targeted imaging and treatment of E. coli soft tissue infections.
Phuong Nguyen Tran +5 more
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