Results 61 to 70 of about 9,553 (252)

Research Update: The mechanocaloric potential of spin crossover compounds

open access: yesAPL Materials, 2016
We present a first evaluation of the potential for spin crossover (SCO) compounds to be considered as a new class of giant mechanocaloric effect materials. From literature data on the variation of the spin crossover temperature with pressure, we estimate
Karl G. Sandeman
doaj   +1 more source

Dynamical limits for the molecular switching in a photoexcited material revealed by X-ray diffraction

open access: yesCommunications Physics, 2022
Ultrafast methods have the ability to transiently decouple transitions between subsystems that evolve simultaneously at thermal equilibrium. Here, time-resolved X-ray diffraction reveals a time delay between volumetric and spin-state switching in a spin ...
Alix Volte   +16 more
doaj   +1 more source

Iron(III) Spin Crossover Compounds [PDF]

open access: yes, 2004
In this chapter, selected results obtained so far on Fe(III) spin crossover compounds are summarized and discussed. Fe(III) spin transition materials of ligands containing chalcogen donor atoms are considered with emphasis on those of N,N-disubstituted-dithiocarbamates, N,N-disubstituted-XY-carbamates (XY=SO, SSe, SeSe), X-xanthates (X=O, S), monothio ...
van Koningsbruggen, PJ   +2 more
openaire   +1 more source

Lead Halide Perovskite Photoelectrocatalysis

open access: yesAdvanced Materials, EarlyView.
Lead halide perovskite semiconductors have emerged as highly promising materials for solar fuel and chemical synthesis. This perspective discusses advances made in the rational photoelectrode design to improve solar‐to‐chemical conversion, product scope, and scalability.
Virgil Andrei
wiley   +1 more source

Field‐Programmable Mobile Magneto‐Photonic Metaparticles for Active Light Manipulation and Steering

open access: yesAdvanced Materials, EarlyView.
We report magneto‐photonic metaparticles that integrate magnetic actuation with nanoimprinted metagratings, enabling mobile and programmable beam steering in aqueous environments. This platform achieves real time, directional light control beyond static or line‐of‐sight systems, while remaining compatible with scalable fabrication, providing a ...
Seung Yeol Lee, Yujie Luo, Ognjen Ilic
wiley   +1 more source

Uniaxial Stress Enhanced Anisotropic Magnetoresistance and Superconductivity in the Kagome Superconductor LaRu3Si2

open access: yesAdvanced Materials, EarlyView.
We identify strong anisotropy in the upper critical field and magnetoresistance in the kagome superconductor LaRu3Si2, revealing pronounced electronic anisotropy. Uniaxial stress enhances magnetoresistance and Tc, with a positive correlation suggesting an electronic pairing mechanism.
P. Kral   +12 more
wiley   +1 more source

Spin State Behavior of A Spin-Crossover Iron(II) Complex with N,N′-Disubstituted 2,6-bis(pyrazol-3-yl)pyridine: A Combined Study by X-ray Diffraction and NMR Spectroscopy

open access: yesCrystals, 2020
A series of three different solvatomorphs of a new iron(II) complex with N,N′-disubstituted 2,6-bis(pyrazol-3-yl)pyridine, including those with the same lattice solvent, has been identified by X-ray diffraction under the same crystallization conditions ...
Elizaveta K. Melnikova   +4 more
doaj   +1 more source

Optoelectronic Nanofluidic Neural Networks for Ionic Computing

open access: yesAdvanced Materials, EarlyView.
An ion‐based optoelectronic nanofluidic memristor enables neuromorphic computing in aqueous environments. With tunable ionic memory and multimodal synaptic plasticity, it realizes densely connected ionic neural networks capable of image classification, motion prediction, logic computation, and real‐time in‐sensor computing, advancing fully connected ...
Yaxin Huang   +10 more
wiley   +1 more source

Anion Influence on Spin State in Two Novel Fe(III) Compounds: [Fe(5F-sal2333)]X

open access: yesCrystals, 2018
Structural and magnetic data on two iron (III) complexes with a hexadentate Schiff base chelating ligand and Cl− or BPh4− counterions are reported.
Sriram Sundaresan   +7 more
doaj   +1 more source

Escaping the Scaling Relationships in Oxygen Reduction Catalysis: Implications for PEM Fuel Cells

open access: yesAdvanced Materials, EarlyView.
Escaping the scaling relationships of the oxygen reduction reaction is vital for hydrogen fuel cells. This outlook examines how interfacial heterogeneity, spanning the subsurface lattice, chemisorption layer, and near‐interface solvation volume, mechanistically decouples intermediate binding energetics.
Muhammad Bilal Wazir   +2 more
wiley   +1 more source

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