Results 81 to 90 of about 9,526 (252)

Electronic transport properties of spin-crossover polymer plus polyaniline composites with Fe3O4 nanoparticles

JPhys Materials
Adding Fe _3 O _4 nanoparticles to composites of [Fe(Htrz) _2 (trz)](BF _4 ) spin-crossover polymer and polyaniline (PANI) drives a phase separation of both and restores the molecular structure and cooperative effects of the spin-crossover polymer ...
Esha Mishra, WaiKiat Chin, Kayleigh A McElveen, Thilini K Ekanayaka, M Zaid Zaz, Gauthami Viswan, Ruthi Zielinski, Alpha T N’Diaye, David Shapiro, Rebecca Y Lai, Robert Streubel, Peter A Dowben   +11 more
doaj   +1 more source

Synthesis, Structure, and Photomagnetic Properties of a Hydrogen-Bonded Lattice of [Fe(bpp)₂]²⁺ Spin-Crossover Complexes and Nicotinate Anions

Crystals, 2018
In this paper, we report on the synthesis, crystal structure, and photomagnetic properties of the spin-crossover salt of formula [Fe(bpp)2](C6H4NO2)2·4H2O (1·4H2O) (bpp = 2,6-bis(pyrazol-3-yl)pyridine; C6H4NO2− = nicotinate anion).
Verónica Jornet-Mollá, Carlos Giménez-Saiz, Francisco M. Romero   +2 more
doaj   +1 more source

Microscopic models of spin crossover

Comptes Rendus. Chimie, 2018
The basic model for thermal spin crossover (SCO) is discussed in its microscopic and thermodynamic formulation. Compared to the basic model, its more elaborated forms formulated in course of almost 50 years are briefly reviewed with emphasis on their additional features.
Pavlik, Ján, Linares, Jorge
openaire   +2 more sources

Giant Conductivity Modulation and Chemical Neuromodulation via Proton‐Electron Coupling in a Hydrogen‐Bonded Coordination Polymer

Advanced Science, EarlyView.
A “de‐doping” strategy positions mixed protonic–electronic conductors (MPECs) as adaptive neuromorphic platforms with dynamically tunable transport. Co‐BAND achieves giant conductivity modulation (>106) and chemically tunable synaptic plasticity. Analogous to biological neuromodulation, solvent vapors dynamically reprogram the device's learning rules ...
Kwangmin Park, Jumin Park, Huiyeong Ju, Nasim Arafat, Byoung Gwan Lee, Joohee Oh, Eejin Jang, Hyunseob Lim, Seok Min Yoon, Dae‐Woon Lim, Intek Song   +10 more
wiley   +1 more source

Spin Hall and Edelstein effects in a ballistic quantum dot with Rashba spin-orbit coupling

SciPost Physics
We study spin-resolved transport in a ballistic quantum dot with Rashba spin–orbit coupling, focusing on charge-to-spin conversion and spin Hall effect. In the regime where the dot size is comparable to the Fermi wavelength, we identify a clear crossover
Alfonso Maiellaro, Francesco Romeo, Mattia Trama, Jacopo Settino, Claudio Guarcello, Carmine Antonio Perroni, Pawel Wójcik, Bartłomiej Szafran, Daniela Stornaiuolo, Marco Salluzzo, Thomas Sand Jespersen, Nicolas Bergeal, Manuel Bibes, Roberta Citro
doaj   +1 more source

Magnetostructural Relationships For Fe(III) Spin Crossover Complexes

Nova Biotechnologica et Chimica, 2015
Structural data for fifteen complexes of Fe(III) of a general formula [FeL5X], with pentadentate Schiff-base ligands L5 and unidentate coligands X−, were subjected to a statistical analysis.
Augustín Peter, Boča Roman
doaj   +1 more source

High Free‐Volume Imidazole‐Based Ionomers for High‐Temperature Proton Exchange Membrane Fuel Cells

Advanced Science, EarlyView.
High free‐volume imidazole‐based ionomers (PF4IM‐72) enable enhanced phosphoric acid uptake and efficient proton transport, delivering peak power densities of 0.645 W cm−2 at 160 °C and 0.838 W cm−2 at 200 °C in HT‐PEMFCs. This work highlights a promising platform for next‐generation ionomers with improved high‐temperature performance and stability ...
Ge Chao, Hyeon Keun Cho, Chang Yeon Hyun, Shirong Li, Jong Geun Seong, So Young Lee, Nanwen Li, Young Moo Lee   +7 more
wiley   +1 more source

Targeting a Myeloid–Regulatory B Cell Network Reverses Immune Paralysis in Periprosthetic Joint Infections

Advanced Science, EarlyView.
Periprosthetic joint infection establishes a sophisticated immunosuppressive network between CXCR4+ PMN‐MDSCs and Bregs, inducing profound CD8+ T cell paralysis. Alendronate effectively disrupts this CXCR4+ PMN‐MDSC–Breg axis by targeting STAT3, thereby restoring local immune surveillance.
Jintao Wu, Shutao Zhang, Yumin Lin, Juyang Jiao, Zhiwei Fu, Qimin Hong, Ziyi Zhao, Xinhua Qu, Fei Su, Bing Yue   +9 more
wiley   +1 more source

Interfacial Control in Cu–MXene Hybrids Enables Selective NOx‐to‐NH3 Electroconversion: A Critical Review

Advanced Science, EarlyView.
Cu‐MXene interfacial catalysts provide a promising platform for electrochemical NOx upcycling to ammonia. The synergy between Cu active sites and conductive, surface‐tunable MXene supports promotes NOx adsorption, intermediate stabilization, and selective NH3 formation while suppressing competing hydrogen evolution, offering a route toward sustainable ...
Hafiz Muhammad Adeel Sharif, Gechuanqi Pan, Yuwei Wang, Yasir Abbas, Asif Mahmood, Changping Li   +5 more
wiley   +1 more source

Conformal Reconfigurable Intelligent Surfaces: A Cylindrical Geometry Perspective

Advanced Electronic Materials, EarlyView.
Cylindrical reconfigurable intelligent surfaces are explored for low‐complexity beam steering using one‐bit meta‐atoms. A multi‐level modeling approach, including optimization‐based synthesis, demonstrates that even minimal hardware can support directive scattering.
Filippo Pepe, Ivan Iudice, Giuseppe Castaldi, Marco Di Renzo, Vincenzo Galdi   +4 more
wiley   +1 more source