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Chapter 13. Spin Trapping

open access: yes, 2021
The relative stability of nitroxides can be utilized in the detection of various unstable radicals, which can be converted to more persistent nitroxide radicals via one-step addition to a double bond. Detection of short-lived radicals using probes capable of forming more persistent radical adducts is called spin trapping.
Zielonka, Jacek   +2 more
openaire   +3 more sources

Spin Trapping and Associated Vocabulary

Free Radical Research Communications, 1990
Spin trapping as a technique for detecting free radicals in biological systems is developing rapidly. Two conferences have focused on this method and this paper introduces the contributions resulting from the second meeting held in the Ontario Veterinary College of the University of Guelph on July 2-7, 1989.
Edward G Janzen, E G Janzen
exaly   +3 more sources

Lyoluminescence and spin trapping

open access: yesCanadian Journal of Chemistry, 1982
The chemical origin of lyoluminescence has been probed using spin trapping techniques. Radicals derived from amino acids and saccharides by γ-irradiation in the solid state have been identified after trapping with aliphatic and aromatic nitroso compounds. Most of the radicals trapped were secondary alkyl radicals.
Kamil V Ettinger   +2 more
openaire   +2 more sources

“Distant spin trapping”: a method for expanding the availability of spin trapping measurements

Journal of Biochemical and Biophysical Methods, 2005
The technique of spin trapping is used to study a wide range of free radicals in various systems, including those generated in vitro and in vivo. But unfortunately, EPR spectrometers are not always immediately accessible at the site of experimentation, and therefore it is important to find a method that can preserve a radical adduct over longer periods
Nadeem, Khan   +4 more
openaire   +2 more sources

The Chemistry of Spin Traps and Spin Trapped Adducts

1999
Abstract By most accounts, the chemistry of nitrones is dominated by aldol condensations and addition reactions, as this functional group mirrors the reactivity of aldehydes and ketones (Bonnett, et al., 1959; Hamer and Macaluso, 1964; Torssell, 1988).
Gerald M Rosen   +3 more
openaire   +1 more source

Spin trapping with thiocarbonyl compounds

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1988
A wide variety of radicals has been added to three relatively stable thiocarbonyl compounds, namely thiobenzoyltriphenylsilane (TBTPS), 2,4,6-tri-t-butylthiobenzaldehyde (TBTBA), and tris(trimethylsilyl)ethan-ethial or trisylthioaldehyde (TSTA), in order to test their ability to act as radical scavengers and the possibility of using them as spin ...
A ALBERTI   +3 more
openaire   +2 more sources

Spin trapping artifacts in DMSO

Biochemical and Biophysical Research Communications, 1987
Spin-trapping experiments in alkaline aqueous dimethyl sulfoxide (DMSO) solution using sodium 3,5-dibromo-4-nitrosobenzenesulfonate (DBNBS) yielded a strong signal of the sulfur trioxide anion radical adduct. This radical adduct is identical to that obtained by the oxidation of sulfite with horseradish peroxidase/hydrogen peroxide and subsequent spin ...
K, Stolze, R P, Mason
openaire   +2 more sources

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