Results 31 to 40 of about 12,432 (295)
Biotransformation of the neo-clerodane diterpene, scutebarbatine F (1), by Streptomyces sp. CPCC 205437 was investigated for the first time, which led to the isolation of nine new metabolites, scutebarbatine F1–F9 (2–10). Their structures were determined
Dewu Zhang +8 more
doaj +1 more source
Preparation of 4 '-spirocyclobutyl nucleoside analogues as novel and versatile adenosine scaffolds
Despite the large variety of modified nucleosides that have been reported, the preparation of constrained 4 '-spirocyclic adenosine analogues has received very little attention.
De Vleeschouwer, Freija +10 more
core +1 more source
Stereoselective synthesis of functionalized pyrrolidines by the diverted NH insertion reaction of metallocarbenes with β-aminoketone derivatives [PDF]
A highly stereoselective route to functionalized pyrrolidines from the metal catalyzed diverted N-H insertion of a range of diazocarbonyl compounds with β-aminoketone derivatives is described. A number of catalysts (rhodium(II) carboxylate dimers, copper(
Aviv +38 more
core +2 more sources
Stereoselective Domino Reactions in the Synthesis of Spiro Compounds
AbstractThis review summarizes the latest developments in asymmetric domino reactions, with the emphasis on the preparation of spiro compounds. Discussions on the stereoselectivity of the transformations, the reaction mechanisms, the rationalization of the stereochemical outcome, and the applications of domino reactions to the synthesis of biologically
Regina Westphal +4 more
openaire +1 more source
Synthesis of spiro quasi[1]catenanes and quasi[1]rotaxanes via a templated backfolding strategy
Spiro compounds contain two or more rings linked together through one common atom. Here the authors provide a method to backfold both rings, producing spiro quasi[1]catenanes, via a strategy of temporarily linking the linear intermediates with covalent ...
Luuk Steemers +4 more
doaj +1 more source
(±)-Peniorthoesters A and B (±1 and ±2), two pairs of unprecedented spiro-orthoester enantiomers with a 1,4,6-trioxaspiro[4. 5]decane-7-one unit, were obtained from Penicillium minioluteum. Their structures were determined by spectroscopic methods, X-ray
Xiaorui Liu +10 more
doaj +1 more source
Phenolic enamino compounds, prepared from 2-(4-hydroxyphenyl)-ethylamine and the corresponding β-keto carbonyl compounds, afford spiro cyclohexadienone derivatives on reaction with hypervalent iodine reagents.
Anastasios Varvoglis +3 more
doaj +1 more source
A number of novel spiro-pyrrolidines/pyrrolizines derivatives were synthesized through [3+2]-cycloaddition of azomethine ylides with 3,5-bis[(E)-arylmethylidene]tetrahydro-4(1H)-pyridinones 2a–n.
Abdulrahman I. Almansour +11 more
doaj +1 more source
Recent advances in solid-state organic lasers
Organic solid-state lasers are reviewed, with a special emphasis on works published during the last decade. Referring originally to dyes in solid-state polymeric matrices, organic lasers also include the rich family of organic semiconductors, paced by ...
Ahmad +195 more
core +3 more sources
Experimental and theoretical insights into the sequential oxidations of 3π-2spiro molecules derived from oligophenylenes: A comparative study of 1,2-b-DiSpiroFluorene-IndenoFluorene versus 1,2-b-DiSpiroFluorene(tert-butyl)4-IndenoFluorene [PDF]
International audienceCyclic voltammetry and differential pulse voltammetry have shown too distinct behaviours in the sequential oxidation processes of two closely related compounds, namely 1,2-b-DiSpiroFluorene-IndenoFluorene (1,2-b-DSF-IF) and 1,2-b ...
Barrière, Frédéric +2 more
core +2 more sources

