Results 31 to 40 of about 10,792 (98)

(±)-Peniorthoesters A and B, Two Pairs of Novel Spiro-Orthoester en-antiomers With an Unusual 1,4,6-Trioxaspi-ro[4.5]decane-7-One Unit From Penicillium minioluteum

Frontiers in Chemistry, 2018
(±)-Peniorthoesters A and B (±1 and ±2), two pairs of unprecedented spiro-orthoester enantiomers with a 1,4,6-trioxaspiro[4. 5]decane-7-one unit, were obtained from Penicillium minioluteum. Their structures were determined by spectroscopic methods, X-ray
Xiaorui Liu, Chunmei Chen, Yinyu Zheng, Mi Zhang, Qingyi Tong, Junjun Liu, Qun Zhou, Jianping Wang, Zengwei Luo, Hucheng Zhu, Yonghui Zhang   +10 more
doaj   +1 more source

Spiro Cyclohexadienones from the Reaction of Phenolic Enaminone Derivatives with Hypervalent Iodine Reagents

Molecules, 2000
Phenolic enamino compounds, prepared from 2-(4-hydroxyphenyl)-ethylamine and the corresponding β-keto carbonyl compounds, afford spiro cyclohexadienone derivatives on reaction with hypervalent iodine reagents.
Anastasios Varvoglis, Spyros Spyroudis, Ioannis Papoutsis, Anna Asmanidou   +3 more
doaj   +1 more source

Facile, Regio- and Diastereoselective Synthesis of Spiro-Pyrrolidine and Pyrrolizine Derivatives and Evaluation of Their Antiproliferative Activities

Molecules, 2014
A number of novel spiro-pyrrolidines/pyrrolizines derivatives were synthesized through [3+2]-cycloaddition of azomethine ylides with 3,5-bis[(E)-arylmethylidene]tetrahydro-4(1H)-pyridinones 2a–n.
Abdulrahman I. Almansour, Raju Suresh Kumar, Farzana Beevi, Amir Nasrolahi Shirazi, Hasnah Osman, Rusli Ismail, Tan Soo Choon, Brian Sullivan, Kellen McCaffrey, Alaa Nahhas, Keykavous Parang, Mohamed Ashraf Ali   +11 more
doaj   +1 more source

Peniciadametizine A, a Dithiodiketopiperazine with a Unique Spiro[furan-2,7'-pyrazino[1,2-b][1,2]oxazine] Skeleton, and a Related Analogue, Peniciadametizine B, from the Marine Sponge-Derived Fungus Penicillium adametzioides

Marine Drugs, 2015
Peniciadametizine A (1); a new dithiodiketopiperazine derivative possessing a unique spiro[furan-2,7'-pyrazino[1,2-b][1,2]oxazine] skeleton, together with a highly oxygenated new analogue, peniciadametizine B (2); as well as two known compounds ...
Yang Liu, Attila Mándi, Xiao-Ming Li, Ling-Hong Meng, Tibor Kurtán, Bin-Gui Wang   +5 more
doaj   +1 more source

The synthesis of novel spirocyclic N-aryl-substituted 2-thiopyrimidine-4,6-diones

Журнал органічної та фармацевтичної хімії, 2019
A convenient and efficient method for the synthesis of new unsaturated spiro-annulated N-aryl-4,6-dioxopyrimidine-2-thione derivatives has been developed.
N. I. Kobyzhcha, V. M. Holovatiuk, V. V. Rozhkov, V. I. Kashkovsky   +3 more
doaj   +1 more source

When Poor Light‐Emitting Spiro Compounds in Solution Turn into Emissive Pure Layers in Organic Light‐Emitting Diodes: The Key Role of Phosphine Substituents

Advanced Photonics Research, 2022
Spiro compounds are widely used as host matrices in organic light‐emitting diodes (OLEDs). Here, inspired by the recent developments in thermally activated delayed fluorescence (TADF) materials, the potential as a light emitter of two spiro‐configured ...
Pauline Tourneur, Fabien Lucas, Clément Brouillac, Cassandre Quinton, Roberto Lazzaroni, Yoann Olivier, Pascal Viville, Cyril Poriel, Jérôme Cornil   +8 more
doaj   +1 more source

Studies on the Enantioselective Synthesis of E-Ethylidene-bearing Spiro[indolizidine-1,3′-oxindole] Alkaloids

Molecules, 2021
A synthetic route for the enantioselective construction of the tetracyclic spiro[indolizidine-1,3′-oxindole] framework present in a large number of oxindole alkaloids, with a cis H-3/H-15 stereochemistry, a functionalized two-carbon substituent at C-15 ...
Nihan Yayik, Maria Pérez, Elies Molins, Joan Bosch, Mercedes Amat   +4 more
doaj   +1 more source

Synthesis & Characterization of Oxazinan and 5-oxa-7-aza-spiro[2,5] octane from reaction of Dibenzylidene with malonic anhydride and 5-oxa-spiro[2,3] hexane-4,6-dione.

مجلة بغداد للعلوم, 2007
Di Benzylidenes were prepared by condensation of 1,2-diamino benzene with o- hydroxy benzaldehyde. These dibenzylidenes when treated with one equivalent of malonic anhydride or 5-oxo-spiro[2,3]hexane-4,6-dione in dry benzene give 6-membered heterocyclic
Baghdad Science Journal
doaj   +1 more source

Synthesis and the Spectral Investigations of Spiro, Ansa and Bridged Derivatives of Cyclochlorotriphosphazenes

Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 2011
The reactions of hexachlorocyclotriphosphazatriene, N3P3Cl6 (1) with 2,2-dimethylpropane-1,3-diol yield 9 new cyclophosphazene derivatives. One monospiro, N3P3Cl4[(OCH2)2-CMe2], dispiro, N3P3Cl2[(OCH2)2-CMe2]2 and tris-spiro N3P3[(OCH2)2-CMe2]3 ...
Sedat Ture
doaj   +1 more source

A tris-spiro metalla-aromatic system featuring Craig-Möbius aromaticity

Nature Communications, 2021
Spiroaromatic compounds are advantageous platforms for designing expanded aromatic systems. Herein, the authors present a tris‐spiro metalla‐aromatic Vanadium compound which forms a 40π Craig‐Möbius aromatic system.
Zhe Huang, Yongliang Zhang, Wen-Xiong Zhang, Junnian Wei, Shengfa Ye, Zhenfeng Xi   +5 more
doaj   +1 more source