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Host–Guest Assembly of a Molecular Reporter with Chiral Cyanohydrins for Assignment of Absolute Stereochemistry

Chemistry - A European Journal, 2016
The absolute stereochemistry of cyanohydrins, derived from ketones and aldehydes, is obtained routinely, in a microscale and derivatization-free manner, upon their complexation with Zn-MAPOL, a zincated porphyrin host with a binding pocket comprised of a
Babak Borhan, Hadi Gholami, Jun Zhang
exaly   +2 more sources

Assigning Stereochemistry to Single Diastereoisomers by GIAO NMR Calculation: The DP4 Probability

Journal of the American Chemical Society, 2010
GIAO NMR shift calculation has been applied to the challenging task of reliably assigning stereochemistry with quantifiable confidence when only one set of experimental data are available.
Jonathan M Goodman
exaly   +2 more sources

Stereochemistry Game: Creating and Playing a Fun Board Game To Engage Students in Reviewing Stereochemistry Concepts

Journal of Chemical Education, 2019
A bilingual (English and Portuguese) innovative teaching method, Stereochemistry Game, is presented in the form of a board/card game to help students in their studies of stereochemistry.
José Nunes da Silva Júnior   +3 more
semanticscholar   +1 more source

Effects of stereochemistry and copolymerization on the LCST of PNIPAm.

Journal of Chemical Physics, 2017
Poly(N-isopropylacrylamide) (PNIPAm) is a smart polymer that presents a lower critical transition temperature (LCST) of 305 K. Interestingly, this transition point falls within the range of the human body temperature, making PNIPAm a highly suitable ...
T. E. de Oliveira   +3 more
semanticscholar   +1 more source

STEREOCHEMISTRY IN ANAESTHESIA

Clinical and Experimental Pharmacology and Physiology, 1997
SUMMARY1. Interest in the pharmacokinetic and pharmacodynamic properties of the enantiomers of chiral drugs has greatly increased in recent years. This is particularly so for agents used in anaesthesia.2. Chiral compounds are those that can exist in two non‐superimposable forms. Each form is termed an enantiomer or stereoisomer.
Stephan A. Schug, David A. Sidebotham
openaire   +3 more sources

The stereochemistry of pinidine

Tetrahedron, 1965
Abstract The stereochemistry of pinidine, a piperidine alkaloid from Pinus sabiniana, was established by chemical and spectroscopic methods as 2-(R)-methyl-6-(R)-(2-trans-propenyl)-piperidine (XXI). Some interesting rearrangements which occurred during degradative studies are discussed, and the configuration of pinidine is compared with that of ...
Richard K. Hill, T.H. Chan, J.A. Joule
openaire   +3 more sources

Topics In Stereochemistry

, 2016
Thank you for reading topics in stereochemistry. Maybe you have knowledge that, people have search hundreds times for their favorite readings like this topics in stereochemistry, but end up in malicious downloads.
Franziska Wulf
semanticscholar   +1 more source

Addressing the stereochemistry of complex organic molecules by density functional theory‐NMR

, 2015
Determining the stereochemistry of organic molecules is a long‐standing problem, with implications for stereoselective reactions, catalysis, and the structure of natural products.
A. Bagno, G. Saielli
semanticscholar   +1 more source

Reinvestigation of the stereochemistry of the C-glycosidic ellagitannins, vescalagin and castalagin.

Organic Letters, 2015
The stereochemistry of the C-glycosidic ellagitannins, vescalagin and castalagin, has been reinvestigated using computational methods. DFT calculations of their (1)H and (13)C NMR spectra, as well as TDDFT calculations of the ECD spectra of their des ...
Yosuke Matsuo   +3 more
semanticscholar   +1 more source

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