Results 181 to 190 of about 17,928 (220)

Imidazoline‐Proline and Imidazoline‐Prolinate Ligands for Copper‐Catalyzed Asymmetric Exo‐Selective [3 + 2] Cycloaddition of Iminoesters with Nitroalkenes

open access: yesChemistryEurope, Volume 4, Issue 1, January 2026.
From a modular synthesis of nonphosphine chiral nitrogen‐based chiral imidazoline–amino acid ligands, two new chiral imidazoline–proline‐copper catalysts are developed for targeting exo‐selective [3 + 2] cycloaddition reaction. Density functional theory studies rationalize the observed stereoselectivity and the distinct chiral pockets of the two ...
Yan Yu   +4 more
wiley   +1 more source

Atmospheric oxidation of dimethylsiloxanes, a source of Si=O double bonds? [PDF]

open access: yesEnviron Sci Pollut Res Int
Rücker C, Troegel D, Kümmerer K.
europepmc   +1 more source

Aldehyde Electrophilicity and Ring Strain Govern Xylose Acetalization Pathways for Biobased Chemical Production

open access: yesChemSusChem, Volume 19, Issue 1, January 2026.
Reaction kinetics and operando heteronuclear single quantum coherence nuclear magnetic resonance studies revealed the reaction pathway of xylose acetalization with different aldehydes. Product distribution and yields were significantly influenced by aldehyde electrophilicity and the orientation of xylose hydroxyl groups.
Zezhong John Li   +6 more
wiley   +1 more source

One‐Pot Morita–Baylis–Hillman/Allylic Substitution in Deep Eutectic Solvents: Access to γ‐Hydroxy Derivatives via Sequential CC and CX (X = P, N, S, B, Si) Bond Formation

open access: yesChemSusChem, Volume 19, Issue 1, January 2026.
Sustainable one‐pot synthesis of functionalized γ‐hydroxy derivatives in deep eutectic solvents. A green, sequential CC/CX bond‐forming strategy enables diverse γ‐hydroxy derivatives via Morita–Baylis–Hillman and nucleophilic functionalization in ChCl/Gly deep eutectic solvent.
Marina Ramos‐Martín   +3 more
wiley   +1 more source

The Silk Route to Green Catalysis: Silk Fibroin as a Recyclable Ligand for Iron‐Catalyzed Olefin Epoxidation

open access: yesChemSusChem, Volume 19, Issue 1, January 2026.
Iron coordinated on silk fibroin from Bombyx mori is easily prepared and catalyzes olefin epoxidation under mild, sustainable conditions with O2. With minimal iron loading, the catalyst is highly recyclable and fully regenerable, offering a green route to heterogeneous catalysis.
Carola Ricciardelli   +8 more
wiley   +1 more source

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