Results 181 to 190 of about 36,653 (344)

Kinetics of anionic polymerization of β‐myrcene in hydrocarbon solvents

open access: yesPolymer International, EarlyView.
The process of anionic polymerization of β‐myrcene in hydrocarbon solvents was examined by kinetic studies and quantum chemical calculations. Abstract The kinetics of anionic polymerization of β‐myrcene initiated by sec‐butyllithium were examined in saturated and unsaturated hydrocarbon solvents, i.e. cyclohexane, cyclohexene, 4‐vinylcyclohexene and dl‐
Alexander Rösler   +4 more
wiley   +1 more source

Cytotoxicity on human leukemic and rat hepatoma cell lines of alkaloid extracts of Psychotria forsteriana [PDF]

open access: yes, 1989
Adjibadé, Y.   +5 more
core   +1 more source

The continuing significance of chiral agrochemicals

open access: yesPest Management Science, Volume 81, Issue 4, Page 1697-1716, April 2025.
In the time frame 2018–2023, around 43% of the 35 chiral agrochemicals introduced to the market (herbicides, fungicides, insecticides, acaricides, and nematicides) contain one or more stereogenic centers in the molecule, and almost 69% of them have been marketed as racemic mixtures of enantiomers or stereoisomers.
Peter Jeschke
wiley   +1 more source

Autonomous Artificial Molecular Motors and Pumps

open access: yesChemSystemsChem, EarlyView.
Autonomous energy consumption is the only way to introduce molecular motors into more sophisticated, larger systems, capable of life‐like behavior. We reviewed a selection of the most recent advances in the field molecular motors focusing on those capable of performing continuous and autonomous motion under constant experimental conditions, that is ...
Chiara Taticchi   +2 more
wiley   +1 more source

Woodward and Hoffmann on Secondary Orbital Interactions. How to Make a Fine Two‐Course Meal from Leftovers**

open access: yesThe Chemical Record, EarlyView.
In February through April 1965, Hoffmann devised several MO tools to explain the regiochemistry of the Diels‐Alder and the preference of the Cope reaction to proceed by the chair rather than boat orientations, when both were possible. The secret lay in secondary orbital interactions that were revealed through qualitative perturbation theory.
Jeffrey I. Seeman
wiley   +1 more source

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