Results 271 to 280 of about 256,202 (345)

London Dispersion as a Design Element in Molecular Catalysis. [PDF]

J Am Chem Soc
Domanski MHJ, Fuhrmann M, Schreiner PR.
europepmc   +1 more source

Practical Considerations in the Design and Use of Non‐Crystalline Metal–Organic Frameworks

Advanced Materials, EarlyView.
This review explores the emerging field of non‐crystalline MOFs ‐ amorphous, liquid, and glassy forms ‐ highlighting how they differ from traditional crystalline MOFs. It discusses their unique synthesis strategies, fundamental principles, and diverse applications.
Hamidreza Mahdavi, Farnaz Zadehahmadi, Mehran Arzani, Leena Melag, Ashley L. Sutton, Muhammad M. Sadiq, Zongli Xie, Matthew R. Hill, Benny D. Freeman   +8 more
wiley   +1 more source

Computational Exploration of Stereoelectronic Relationships in Manganese-Catalyzed Hydrogenation Reactions. [PDF]

Chemistry
Goodfellow AS, Clarke ML, Bühl M.
europepmc   +1 more source

Unraveling the Impact of Electrosorbed Ions on the Scaling Behavior of Fast‐Charging Dynamics of Nanoporous Electrodes Toward Digital Design of Iontronic Devices

Advanced Materials, EarlyView.
Electrosorbed ions under nanoconfinement (see TOC figure) critically reshape electrochemical potentials and impact ion transport in porous electrodes. By integrating modified Poisson–Nernst–Planck simulations with multilayered graphene membrane experiments, this study establishes a scaling relation and reveals electrosorption‐enhanced transport ...
Jinsha Liao, Peiyao Wang, Wen‐Jie Jiang, Xiaoyang Du, Jefferson Zhe Liu, Dan Li   +5 more
wiley   +1 more source

Anchoring Unimolecular Metal Chloride as a Sterically Active Site for Conformal Zinc Electrodeposition

Advanced Materials, EarlyView.
An octahedrally coordinated MnCl2N4 structure anchored on hard carbon tailors the electronic environment of single atoms to lower zinc nucleation barriers. Chloride‐assisted Zn adsorption with Jahn‐Teller distortion and residual Zn enables reduced overpotential.
Yibo Zhu, Ning Wang, Di Liu, Shengyong Gao, Haoqing Liu, Xinyue Hu, Chuang Qiu, Peng Liu, Shuangbin Zhang, Junping Hu, Lianzhou Wang, Bin Luo, Jisheng Zhou   +12 more
wiley   +1 more source

Giant Circularly Polarized Luminescence Driven by Excited‐State Hybridization Between Molecular Emitters and Chiral Environments

Advanced Materials, EarlyView.
A fundamental chiroptical response amplification mechanism is revealed to massively enhance molecular helicene chiral emitters. The luminescent dissymmetry factor of the helicene emitter is amplified by 133 times through excited‐state hybridization with a polymeric chiral environment.
Li Wan, Eunkyung Cho, Rui Zhang, Theis Brock‐Nannestad, Zhaohui Wang, Jean‐Luc Brédas, Veaceslav Coropceanu, Feng Gao   +7 more
wiley   +1 more source

Steric effect of intermediates induces formation of three-dimensional covalent organic frameworks. [PDF]

Nat Commun
Lai J, Liu S, Ma W, Wu F, Yu P, Mao L.
europepmc   +1 more source

A contra-steric chemoselective hydrometallation strategy with bulky NHC for catalytic asymmetric branched allylamine synthesis. [PDF]

Nat Commun
Chen W, Zhang Z, Ho CY.
europepmc   +1 more source

Investigating the closures of sea level budgets in China's adjacent seas. [PDF]

Sci Rep
Li Y, Guo J, Sun Y, Zhou J, Sun H.
europepmc   +1 more source

Protective Group-Dependent Iridium-Catalyzed CH Borylations of Levodopa. [PDF]

J Org Chem
Yang C, Fan J, Maleczka RE.
europepmc   +1 more source