Results 91 to 100 of about 280,815 (357)

Photoswitchable Conductive Metal–Organic Frameworks

open access: yesAdvanced Functional Materials, EarlyView.
A conductive material where the conductivity can be modulated remotely by irradiation with light is presented. It is based on films of conductive metal–organic framework type Cu3(HHTP)2 with embedded photochromic molecules such as azobenzene, diarylethene, spiropyran, and hexaarylbiimidazole in the pores.
Yidong Liu   +5 more
wiley   +1 more source

Three-Dimensional Mesoporous Covalent Organic Frameworks through Steric Hindrance Engineering.

open access: yesJournal of the American Chemical Society, 2020
The development of three-dimensional (3D) covalent organic frameworks (COFs) with large pores and high surface areas is of great importance for various applications.
Yujie Wang   +8 more
semanticscholar   +1 more source

The first solvent-free cyclotrimerization reaction of arylethynes catalyzed by rhodium porphyrins [PDF]

open access: yes, 2003
Different rhodium(III) porphyrin chlorides have been used as catalysts for the cyclotrimerization of several arylethynes, giving in many cases high yields in substituted benzenes and selectivities based on the steric hindrance of the macrocycles and on ...
D'Arcangelo, G   +4 more
core   +1 more source

Enhancing Low‐Temperature Performance of Sodium‐Ion Batteries via Anion‐Solvent Interactions

open access: yesAdvanced Functional Materials, EarlyView.
DOL is introduced into electrolytes as a co‐solvent, increasing slat solubility, ion conductivity, and the de‐solvent process, and forming an anion‐rich solvent shell due to its high interaction with anion. With the above virtues, the batteries using this electrolyte exhibit excellent cycling stability at low temperatures. Abstract Sodium‐ion batteries
Cheng Zheng   +7 more
wiley   +1 more source

steric hindrance

open access: yes, 2014
Citation: 'steric hindrance' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.S06000 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Unlocking Ultra‐Long Cycle Stability of Li Metal Electrode by Separators Modified by Porous Red Phosphorus Nanosheets

open access: yesAdvanced Functional Materials, EarlyView.
Coating the standard polypropylene separator with a porous red phosphorous nanosheet greatly improves cycling performance in Li electrode cells. The phosphorus‐based surface chemistry deactivates electrolyte solvent decomposition and enhances the cleavage of F‐containing salt, resulting in an inorganic‐dominated electrolyte interphase (SEI) composition
Jiangpeng Wang   +9 more
wiley   +1 more source

N,N-Diethyl-N′-phenylacetylthiourea

open access: yesActa Crystallographica Section E, 2008
The title thiourea molecule, C13H18N2OS, adopts a folded conformation due to the steric hindrance of the two ethyl groups and the acetyl group. In the crystal structure, the acetyl O atom is not involved in hydrogen bonding, but intermolecular N—H..
Liang Xian
doaj   +1 more source

Steric hindrance in the upper 50 kDa domain of the motor Myo2p leads to cytokinesis defects in fission yeast [PDF]

open access: yes, 2017
Cytokinesis in many eukaryotes requires a contractile actomyosin ring that is placed at the division site. In fission yeast, which is an attractive organism for the study of cytokinesis, actomyosin ring assembly and contraction requires the myosin II ...
Balasubramanian, Mohan K.   +5 more
core   +1 more source

Transcription within Condensed Chromatin: Steric Hindrance Facilitates Elongation [PDF]

open access: yesBiophysical Journal, 2010
During eukaryotic transcription, RNA-polymerase activity generates torsional stress in DNA, having a negative impact on the elongation process. Using our previous studies of chromatin fiber structure and conformational transitions, we suggest that this torsional stress can be alleviated, thanks to a tradeoff between the fiber twist and nucleosome ...
Bécavin, Christophe   +3 more
openaire   +3 more sources

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