Results 101 to 110 of about 147,337 (257)

Intrinsic Coordination Architecture Governing Selectivity Divergence Between Extended and Single‐Site Electrocatalysts

Advanced Materials, EarlyView.
Catalyst coordination acts as a loaded dice biasing reaction selectivity. Single‐atom site catalysts lock intermediates in exposed configurations, enabling continued hydrogenation and favoring oxygen‐retaining products. In contrast, extended metal surfaces fully coordinate and shield reactive centers, promoting deoxygenation pathways. This work reveals
Chengyi Zhang, Ziyun Wang
wiley   +1 more source

Plasmonic Nanomachines: Creating Local Potential Gradients and Motions

Advanced Materials, EarlyView.
Plasmonic nanomachines can generate optical, thermal, and chemical potential gradients to drive directional rectilinear, rotational, and twisting motions at the nanometer scale. The integration of multimodal plasmonic forces with functional materials and programmed structural distortions enables precise spatiotemporal actuation, thereby providing a ...
Yoonhee Kim, Soohyun Ji, Donghyun Choi, Jwa‐Min Nam   +3 more
wiley   +1 more source

Steric hindrance, ligand ejection and associated photocytotoxic properties of ruthenium(II) polypyridyl complexes. [PDF]

J Biol Inorg Chem, 2023
Herrera-Ramírez P, Berger SA, Josa D, Aguilà D, Caballero AB, Fontova P, Soto-Cerrato V, Martínez M, Gamez P.   +8 more
europepmc   +1 more source

Backbone Engineering of Carbon‐Centered NHC‐Derived Diradicals: From Electronic State Tuning to High‐Performance Organic Field‐Effect Transistors

Advanced Materials, EarlyView.
The open‐shell nature of diradicals facilitates charge separation, and compounds with moderate diradical character demonstrate remarkable potential in organic field‐effect transistors (OFET) applications due to their low reorganization energies for hole and electron transport.
Xiao‐Xu Liu, Lianghui Li, Xin Li, Can Chen, Man Li, Shun Tian, Paul J. Dyson, Ying‐Feng Han   +7 more
wiley   +1 more source

Enhancing organic cathodes of aqueous zinc-ion batteries via utilizing steric hindrance and electron cloud equalization. [PDF]

Chem Sci, 2023
Ma G, Ju Z, Xu X, Xu Y, Sun Y, Wang Y, Zhang G, Cai M, Pan L, Yu G.   +9 more
europepmc   +1 more source

Composition Restoration Enables Recycling of Mixed‐Cation, Mixed‐Halide Perovskites for Solar Cells

Advanced Materials, EarlyView.
Compositional drift during processing prevents the direct recycling of mixed‐cation, mixed‐halide perovskites. This work introduces a framework to quantitatively audit and restore recovered materials, enabling closed‐loop recycling with efficiencies comparable to virgin perovskites.
Zhenni Wu, Katharina Dammer, Robert Skunde, Mykhailo Sytnyk, Christian Göllner, Fei Ding, Juan S. Rocha‐Ortiz, Albert These, Balázs Imre, Yanxue Wang, Dorothea Wisser, Christoph Brabec, Ian Marius Peters   +12 more
wiley   +1 more source

Steering on-surface reactions through molecular steric hindrance and molecule-substrate van der Waals interactions. [PDF]

Quantum Front, 2022
Wang S, Nishiuchi T, Pignedoli CA, Yao X, Di Giovannantonio M, Zhao Y, Narita A, Feng X, Müllen K, Ruffieux P, Fasel R.   +10 more
europepmc   +1 more source

Nanomaterial Integration at Liquid–Liquid Interfaces for Green Catalysis

Advanced Materials, EarlyView.
Functional nanomaterials assembled at liquid–liquid interfaces create dual‐role platforms serving as emulsion stabilizers and catalytic sites, offering enhanced reaction kinetics with improved catalyst recovery and recyclability. This review examines design strategies, structure‐performance relationships, and industrial implementation prospects of ...
Bokgi Seo, Jaewon Shin, Minkyoung Jang, Kyoungho Choi, Tengfei Pang, Fangrui Zhong, Jin Woong Kim   +6 more
wiley   +1 more source

Steric hindrance-induced selective growth of rhodium on gold nanobipyramids for plasmon-enhanced nitrogen fixation. [PDF]

Chem Sci, 2023
Jia H, Li F, Yang Y, Zhao M, Li J, Zhang CY.   +5 more
europepmc   +1 more source

Engineered Heparinized GQDS/HPEI–Polyamide Membrane for Bilirubin Removal via One Step Anti Coagulation

Advanced Materials Interfaces, EarlyView.
A multifunctional heparinized polyamide membrane embedded with graphene quantum dots (GQDs) and hyperbranched polyethyleneimine (HPEI) is engineered for efficient bilirubin removal via a one‐step anticoagulation–adsorption process. The membrane demonstrates enhanced hemocompatibility, prolonged clotting times, and high bilirubin adsorption capacity ...
Abdur Rehman Mushtaq Ahmad, Maria Wasim, Aneela Sabir, Muhammad Shafiq, Syed Abdul Basit Shah, Maoz Maoz, Vanni Lughi   +6 more
wiley   +1 more source