Results 91 to 100 of about 168,162 (295)

DNA‐Templated 2D Heterostructures as Phototriggered Dynamic Nanohybrids: From Releasing Molecular Loads to Controlling Enzyme Biocatalytic Function

open access: yesAdvanced Functional Materials, EarlyView.
DNA strands are employed both as dynamic linkers and nanoscale templates for the integration of Ag2S nanoparticles on MoS2, which in turn imparted photothermal responsiveness; this feature permits the selective cargo (fluorophore, quantum dots or an enzyme) release from the MoS2 surface in response to local heat induced by light irradiation.
Kai Chen   +3 more
wiley   +1 more source

2-(2-Nitrophenyl)-1,3-dioxan-5-ol

open access: yesActa Crystallographica Section E, 2009
In the title compound, C10H11NO5, the six-membered 1,3-dioxane ring displays a chair conformation, with the hydroxy and 2-nitrophenyl groups in equatorial positions, which minimizes steric hindrance. In the crystal, molecules are linked into chains along
Jin Chen   +3 more
doaj   +1 more source

Steric Hindrance Effect as a Decisive Factor for the Self-Assembly of Metallocages

open access: yes, 2023
In the past decades, many supramolecular cages with different sizes and shapes have been achieved through coordination-driven self-assembly. However, the strategy of topology adjustment by using a steric hindrance effect has not been fully developed.
Zhengguang Li (3967622)   +15 more
core   +1 more source

From Food to Power: Hydrogel Thermoelectrics for Ingestible Electronics

open access: yesAdvanced Functional Materials, EarlyView.
We introduce a fully edible thermoelectric–electrochromic platform that harvests heat from food and converts it into a visible color change. N‐type and p‐type hydrogel thermoelectric generators connected in series power anthocyanin‐based electrochromic displays, demonstrating the feasibility of safe, biodegradable, ingestible systems for on‐food ...
Antonia Georgopoulou   +3 more
wiley   +1 more source

Performance Analysis of a Dual‐Drain Dual‐Gate Schottky Tunnel Field Effect Transistor Biosensor for Non‐Ideal Hybridization

open access: yesNano Select
In this study, we analyzed the sensing characteristics of a MoS₂‐based dual‐drain, dual‐gate Schottky tunnel field effect transistor (DD‐DG‐STFET) based on the hybridization process to achieve groundbreaking sensitivity.
Anusuya Periyasami, Prashanth Kumar
doaj   +1 more source

Advances in structures required of polyphenols for xanthine oxidase inhibition

open access: yesFood Frontiers, 2020
Polyphenols have been used as natural medicaments for the management of hyperuricemia for a long history. They have been attracted many interests because of the little side effects in curing hyperuricemia, which is an important advantage over the ...
Liangliang Liu   +3 more
doaj   +1 more source

Steric-Hindrance-Induced Diastereoselective Radical Nitration of 3‑Alkylidene-2-oxindoles Followed by Tosylhydrazine-Mediated Sulfonation

open access: yes
Metal-free radical nitration of the β C–H bond of 3-alkylidene-2-oxindoles with tert-butyl nitrite (TBN) has been explored. Interestingly, (E)-3-(2-(aryl)-2-oxoethylidene)­oxindole and (E)-3-ylidene oxindole give different diastereomers on nitration. The
Prasanta Ghosh (1655155)   +3 more
core   +1 more source

X‐Functionality–Driven Photocatalytic Hydrogen Evolution in 2D 4‐X‐PEA2SnI4 Perovskites

open access: yesAdvanced Functional Materials, EarlyView.
We report a water‐based synthesis of 2D 4‐X‐PEA2SnI4 perovskite microcrystals with prominent photocatalytic (PC) activity for H2 production. The synergy between organic functionalization and HI‐derived iodide scavenges holes suppress octahedral distortion, and favor electron accumulation, enabling a PC H2 evolution ∼20 µmol·g−1 and long‐term stability ...
Taeyeon Kim   +21 more
wiley   +1 more source

Steric Maps to Evaluate the Role of Steric Hindrance on the IPr NHC Ligand

open access: yesProcedia Computer Science, 2013
AbstractDensity functional theory (DFT) calculations were used to predict and rationalize the effect of the modification of the structure of the prototype 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) (IPr) N-heterocyclic carbene (NHC) ligand. The modification consists in the substitution of the methyl groups of ortho isopropyl substituent with ...
Albert Poater   +5 more
openaire   +2 more sources

Is Fe-catalyzed ortho C–H Arylation of Benzamides Sensitive to Steric Hindrance and Directing Group?

open access: yes, 2019
The previously reported Fe-catalyzed ortho C–H arylation of benzamides relied on bi- or tridentate amide groups and specific iron ligands and was sensitive to steric hindrance.
Meng-Fei Wang (7139576)   +2 more
core   +1 more source

Home - About - Disclaimer - Privacy