Results 111 to 120 of about 9,469,736 (295)

Unlocking the Alkynyl Bromide Radical Anion With Alternating Current for Inverse Sonogashira C─H Coupling

Advanced Science, EarlyView.
An alternating current (AC)‐promoted, Pd‐catalyzed ortho‐aryl C─H alkynylation of 2,3‐diaryl acrylaldehydes is described. This synthetic scheme accommodates a broad substrate scope, delivering alkynylated stilbene derivatives with excellent arene site selectivity.
Junya Wang, Xiaozhou Wang, Pui Ying Choy, Chi‐Wai Cheung, Li‐Wen Xu, Hung Kay Lee, Gui‐Juan Cheng, Fuk Yee Kwong   +7 more
wiley   +1 more source

Tunable p–p Interactions Along Linear Chains Control Metavalent Bonding in Chalcogenide Heterostructures

Advanced Science, EarlyView.
Substitution of Sr at the Pb site within an atomic plane of PbTe perturbs the p–p hopping network. Since Sr does not support the p–p interaction key to metavalent bonding along (‐Pb‐Te‐) chains, long‐range electronic charge transfer in response to displacement of Pb is stalked at the Sr site.
Sakshi Verma, Kanishka Biswas, Umesh V. Waghmare, C. N. R. Rao   +3 more
wiley   +1 more source

Ionic Dioxidovanadium(V) Complexes with Schiff-Base Ligands as Potential Insulin-Mimetic Agents-Substituent Effect on Structure and Stability. [PDF]

Molecules, 2022
Jurowska A, Szklarzewicz J, Hodorowicz M, Serafin W, Zangrando E, Mahmoudi G.   +5 more
europepmc   +1 more source

Homogenous catalysis of peroxynitrite conversion to nitrate by diaryl selenide: a theoretical investigation of the reaction mechanism

Frontiers in Chemistry
Quenching peroxynitrite (a reactive oxidant species) is a vital process in biological systems and environmental chemistry as it maintains redox balance and mitigates damaging effects in living cells and the environment.
Yuan Xue, Yuan Xue, Carrie Salmon, Valentin Gogonea, Valentin Gogonea, Valentin Gogonea   +5 more
doaj   +1 more source

DFT Study on the Substituent Effect of Anticancer Picoline-Diazido-Pt(IV) Compounds. [PDF]

Front Oncol, 2021
Mu M, Gao H.
europepmc   +1 more source

Design and Synthesis of New A2B Adenosine Receptor Antagonists [PDF]

, 2009
Starting from chemical structure of N-benzo-[1,3]dioxol-5-yl-2-[5-(2,6dioxo-1,3-dipropyl-2,3,6,7-tetrahydro-1H-purin-8-yl)-1-methyl-1H-pyrazol3-yloxy]-acetamide, MRE2029F20* various structural modifications were realized to afford a new series of A2B ...
Baraldi, Stefania
core  

Electrochemically Driven Regioselective Radical Functionalization of Allenes: Scope and Mechanistic Insights

Advanced Science, EarlyView.
Allenes emerge as powerful platforms for electrochemical functionalization through radical pathways. Selective radical addition at the central carbon triggers anodic oxidation and intramolecular cyclization, enabling efficient synthesis of oxazolines and oxazolidine‐2‐imines without external oxidants.
Pranjal Pyne, Prateek Saini, Rohel Hoque, Shivam Pandey, Srinivasan Ramakrishnan, Chandra M. R. Volla   +5 more
wiley   +1 more source

Arylamine Analogs of Methylene Blue: Substituent Effect on Aggregation Behavior and DNA Binding. [PDF]

Int J Mol Sci, 2021
Khadieva A, Mostovaya O, Padnya P, Kalinin V, Grishaev D, Tumakov D, Stoikov I.   +6 more
europepmc   +1 more source

Perylenediimide-Based Hybrid Materials for the Iodoperfluoroalkylation of Alkenes and Oxidative Coupling of Amines: Bay-Substituent-Mediated Photocatalytic Activity

Inorganic–organic donor–acceptor hybrid compounds are an emerging class of multifunctional crystalline materials with well-defined structures built from semiconductive inorganic and organic components.
Chao Li (145513), Zhengfen Liu (8842586), Jian-Jun Liu (88308), Wenxiu Yin (14129895), Feixiang Cheng (671205), Jian Chen (15340), Xiaobo Li (118828)   +6 more
core   +1 more source

Local Solvent Ordering Drives Supramolecular Chirality Inversion

Advanced Science, EarlyView.
Local solvent organization is shown to govern supramolecular chirality by selecting distinct chiral assembly pathways. A subtle change in water‐DMSO composition reverses the helical sense of a chiral perylene bisimide, while heating induces an irreversible thermal inversion to a more stable enantiomorph.
Triza Pal, Akta Singh, Subinoy Adhikari, Jagannath Mondal, Debangshu Chaudhuri   +4 more
wiley   +1 more source