Results 111 to 120 of about 9,273,531 (285)
Advanced Science, EarlyView.Precise characterization of n‐type organic semiconductors necessitates decoupling interfacial constraints from intrinsic charge transport. This work reveals that disordered polymers are particularly vulnerable to contact‐limited bottlenecks compared to their crystalline counterparts.
Walid Boukhili +15 more
wiley +1 more source
Competitive Heavy‐Atom Tunneling Reactions Controlled Through Electronic Effects
ChemistryEuropeControlling QMT reactivity remains exceptionally challenging and largely unexplored, as it requires rationales distinctly different from those used for classical chemical reactivity.
José P. L. Roque +5 more
doaj +1 more source
NiH‐Catalyzed Enantio‐ and Regioselective Hydroselenylation of Unactivated Alkenes
Advanced Science, EarlyView.Nickel‐hydride‐catalyzed enantio‐ and regioselective hydroselenylation of unactivated alkenes provides access to chiral organoselenium compounds. Enantiodetermining Ni–H insertion followed by single‐electron diselenide activation generates selenyl radical.
Hyung‐Joon Kang +2 more
wiley +1 more source
Advanced Science, EarlyView.Peptide‐inspired associative polymers with arginine‐like guanidinium stickers and lysine‐like ammonium spacers undergo chain collapse and liquid‐liquid phase separation induced by reversible sticker associations. Sticker valence and tunable association strength jointly control the phase behavior, chain conformation, and interfacial cohesion of these ...
Seung‐Hwan Oh +7 more
wiley +1 more source
Printable Piezoresistive Hybrid Hydrogels Based on 2D MoS2 for Flexible Pulse Sensing
Advanced Science, EarlyView.Hybrid 1T‐MoS2‐based hydrogels are engineered through UV curing and 3D printing to achieve tunable electromechanical properties for wearable sensing. These soft architectures enhance mechanical stability and reproducible piezoresistive responses within the physiological pressure range.
Jenny Flores +18 more
wiley +1 more source
Advanced Science, EarlyView.We report a chromogenic release‐based assay system with protease‐cleavage peptide‐modified calcium carbonate microspheres for colorimetric detection of Porphyromonas (P.) gingivalis activity. In response to Arg‐specific gingipain secreted by P. gingivalis, the supernatant becomes colored, enabling colorimetric analysis and providing the monitoring of ...
Yuki Hiruta +9 more
wiley +1 more source
Accurate Prediction of Cation−π Interaction Energy Using Substituent Effects
, 2016 Substituent effects on cation−π interactions have been quantified using a variety of Φ–X···M+ complexes where Φ, X, and M+ are the π-system, substituent, and cation, respectively.
Cherumuttathu H. Suresh (1468816) +1 more
core +1 more source
Advanced Science, EarlyView.This work presents a computational–experimental strategy to engineer material‐binding peptides toward polymer specificity. Molecular dynamics simulations identified residues driving polystyrene binding, enabling targeted substitutions that greatly reduced polystyrene affinity while preserving PET binding.
Julian Luka +3 more
wiley +1 more source
Atomic Charges from Machine-Learned Charge Densities: Consistency and Substituent Effects
ChemistryAtomic charges are widely used to analyze molecular electronic structure and substituent effects, yet their numerical values and interpretations are inherently dependent on the adopted density partitioning scheme.
Xuejian Qin, Taoyuze Lv
doaj +1 more source
Advanced Science, EarlyView.Upon UV irradiation, flexible and tough hydrogels are formed rapidly (>0.5 s) from dilute (>0.5 wt%) solutions of o‐ethylnitrobenzene–modified PVA. At ∼1.5 wt%, the hydrogels withstand up to 10 MPa compression, remain handleable even after 200‐fold swelling.
Masaaki Okihara +4 more
wiley +1 more source