NiH‐Catalyzed Enantio‐ and Regioselective Hydroselenylation of Unactivated Alkenes
Nickel‐hydride‐catalyzed enantio‐ and regioselective hydroselenylation of unactivated alkenes provides access to chiral organoselenium compounds. Enantiodetermining Ni–H insertion followed by single‐electron diselenide activation generates selenyl radical.
Hyung‐Joon Kang +2 more
wiley +1 more source
Substituent Effects on Sulfur Phenolate Exchange Reactions: Reactivity and Bonding Analysis. [PDF]
Krishna A +4 more
europepmc +1 more source
Bio‐Based Polyurethanes for Sustainable and Multifunctional Applications
Bio‐based polyurethanes prepared from vegetable oils, lignin, and polysaccharides have attracted increasing interest as alternatives to fossil‐derived polyurethanes. This review summarizes recent progress in their chemistry, structural engineering, and advanced applications, highlighting the roles of feedstocks, chain‐segment design, dynamic covalent ...
Xin Li +6 more
wiley +1 more source
Modeling Chelator Substituent Effects as Therapeutic Targets in Neurodegenerative Diseases. [PDF]
Kimbrough CJ, Cundari TR.
europepmc +1 more source
Quantum Interference in Mixed-Valence Complexes: Tuning Electronic Coupling Through Substituent Effects. [PDF]
Harrison DP +9 more
europepmc +1 more source
Substituent effects in triarylphosphines
M.Sc. The main objective of the work presented in this dissertation was to investigate the application of the phosphorus atom as a probe to evaluate stereo-electronic effects in arylphosphines. Traditionally, electronic effects are described as having inductive or resonance origins.
openaire +1 more source
Peptide‐inspired associative polymers with arginine‐like guanidinium stickers and lysine‐like ammonium spacers undergo chain collapse and liquid‐liquid phase separation induced by reversible sticker associations. Sticker valence and tunable association strength jointly control the phase behavior, chain conformation, and interfacial cohesion of these ...
Seung‐Hwan Oh +7 more
wiley +1 more source
Synthesis, Antiparasitic Activity and Substituent Effects of Methyl 5-(Hetero)aryl or Alicyclicaminothieno[2,3-<i>b</i>]pyridine-2-carboxylates. [PDF]
Ribeiro F +5 more
europepmc +1 more source
Substituent Effects and Mechanistic Insights on the Catalytic Activities of (Tetraarylcyclopentadienone)iron Carbonyl Compounds in Transfer Hydrogenations and Dehydrogenations. [PDF]
Werley BK +4 more
europepmc +1 more source
We report a chromogenic release‐based assay system with protease‐cleavage peptide‐modified calcium carbonate microspheres for colorimetric detection of Porphyromonas (P.) gingivalis activity. In response to Arg‐specific gingipain secreted by P. gingivalis, the supernatant becomes colored, enabling colorimetric analysis and providing the monitoring of ...
Yuki Hiruta +9 more
wiley +1 more source

