Advanced Science, EarlyView.Defect‐engineered LiYO2 interlayers are designed through aliovalent Zn2+ and Zr4+ substitution to regulate Li+ point‐defect chemistry in Ni‐rich cathodes. Compared with Li‐excess‐type LYZnO, Li‐vacancy‐type LYZrO enables faster Li+ transport, suppresses Li6PS5Cl decomposition, lowers interfacial resistance, and mitigates polarization growth, thereby ...
Sodam Kim +6 more
wiley +1 more source
Pyrene-Chromone Schiff Base Molecules with Tunable Fluorescence: Structure-Property Relationships and Substituent Effects. [PDF]
MoleculesZurnacı M.
europepmc +1 more source
Aryl‐Tethered Pendant Sterically Shielded Imidazoliums for Durable Anion Exchange Membranes
Advanced Science, EarlyView.An aryl‐tethered, sterically shielded imidazolium architecture protects cationic sites from hydroxide attack while avoiding vulnerable benzylic cation–polymer linkages. Incorporated into poly(arylimidazolium) membranes, this dual‐protection design enhances alkaline and oxidative durability and supports prolonged alkaline water electrolysis, offering a ...
Jinggui Lei +8 more
wiley +1 more source
Radical Stability Paradox: Substituent Effects versus Heats of Formation. [PDF]
ChemistryRodrigues Silva D +3 more
europepmc +1 more source
Spatial Au+ Mapping Reveals a Self‐Amplifying Anti‐Tumor Immunity Loop Driven by Au(I) Complexes
Advanced Science, EarlyView.The first report of spatial Au+ mapping of a representative gold complex (Au9). Macrophages, DCs, and tumor cells ranked as the top three in Au+ enrichment after Au9 treatment. Interestingly, Au9 treatment could induce ferroptosis and suppress cellular cholesterol, further eliciting a self‐amplifying anti‐tumor immunity loop.
Zhongren Xu +5 more
wiley +1 more source
C∙∙∙O and Si∙∙∙O Tetrel Bonds: Substituent Effects and Transfer of the SiF3 Group. [PDF]
Int J Mol Sci, 2023 Niu Z, Wu Q, Li Q, Scheiner S.
europepmc +1 more source
Advanced Science, EarlyView.In this review, the classification and development history of the volatile solid and solvent additives are comprehensively summarized, the underlying mechanisms of morphology optimization are discussed, and a summary of volatile additive‐induced improvements in interfacial layer performance is provided.
Jianqiang Qin +7 more
wiley +1 more source
Structural variation and transmission of substituent effects
, 2015 In our studies on the transmission of electronic substituent effects in Ph-G-X molecules [1], where G is a framework (or spacer) and X a variable substituent, we use a phenyl group (Ph) as a probe, by virtue of its structural variation under the impact ...
Domenicano Aldo, Campanelli Anna Rita
core
Substituent Effects Control the Biological Activity of Mn(II) Imidazo[1,2-a]pyridine Complexes. [PDF]
MoleculesRydz M +8 more
europepmc +1 more source
Tuning the Nucleophilicity and Electrophilicity of Group 10 Elements through Substituent Effects: A DFT Study. [PDF]
Int J Mol Sci, 2023 Burguera S, Bauzá A, Frontera A.
europepmc +1 more source