Results 91 to 100 of about 45,088 (258)

Low‐Temperature in Situ Upgrading of Ultra‐Deep Heavy Oil Using Ni–Ce/MOF–OTf Superacid Catalysts to Enhance Energy Utilization and Sustainability

open access: yesEcoEnergy, EarlyView.
A triflate‐functionalized Ni–Ce/MOF–OTf superacid enables low‐temperature (∼140°C) in situ upgrading of ultra‐deep heavy oil. It reduces viscosity by 92.11% in 12 h, maintains activity over cycles, and delivers 90.25% recovery with a lower carbon footprint by selective bond cleavage. ABSTRACT Ultra‐deep heavy oil is an important unconventional resource,
Li Wang   +5 more
wiley   +1 more source

Crystal Orientation Regulation and Dynamic Protection via Dual Interface Engineering for Dendrite‐Free Zinc Deposition

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A dual‐interface engineering strategy is innovatively proposed to achieve dendrite‐free Zn anodes through crystallographic orientation regulation and adaptive interfacial protection. By pre‐coating eco‐friendly di‐pentaerythritol, horizontal growth of ZHS along the (001) plane is induced, which in turn guides epitaxial Zn deposition on the (002) plane.
Xin Wu   +8 more
wiley   +1 more source

Novel Zwitterionic Polydopamine Nanofiller‐Reinforced Hybrid Membranes With Superior Antifouling Performance for Wastewater Treatment

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This work reports one‐pot synthesized novel zwitterionic polydopamine‐silica (ZSiPDA) nanofillers for fabricating PES hybrid ultrafiltration membranes with enhanced hydrophilicity, permeability, and antifouling performance. The optimized membrane achieved over 91% humic acid removal and showed strong potential for municipal wastewater treatment.
Roqaya A. Ismail   +5 more
wiley   +1 more source

Integrated Solvent‐Catalyst‐Dopant Strategy via Acidic DES for Synthesizing Lignin‐Derived Carbon Dots With High‐Quantum Yield to Achieve Efficient Photocatalytic Degradation of Tetracycline

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A deep eutectic solvent (ChCl/pTSA) platform enables integrated solvent, catalyst, and dopant functions, producing sulfur‐doped carbon quantum dots with a high sp2‐C content (82.8%) and a quantum yield of 56.9%. When combined with TiO2, the CQDs form TiOC and TiOS interfacial bridges, achieving 97.3% tetracycline photodegradation with excellent ...
Xinhang Li   +4 more
wiley   +1 more source

A Short Total Synthesis of the Daucane Sesquiterpenoid Ferutinin

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Only nine steps were required to access the bioactive daucane sesquiterpene ester ferutinin (1) from 3‐methyl‐2‐cyclopentenone (3) and allyl p‐tolyl sulfoxide. A one‐pot 1,4‐addition/aldol sequence was used to rapidly provide diene 2 (TBS = tert‐butyldimethylsilyl), ring‐closing metathesis of which followed by alkylation and acylation gave rise to the ...
Christiane Osthaar   +3 more
wiley   +1 more source

Sulfur‐Rich Sustainable Copolymers for Enhancing Redox Kinetics and Alleviating Cathode Passivation in Lithium‐Sulfur Batteries

open access: yesExploration, EarlyView.
A molecularly engineered, sustainable sulfur‐rich redox copolymer cathode delivers accelerated sulfur conversion and suppressed passivation, enabling high sulfur utilization and durable, high‐performance LiS batteries. ABSTRACT Lithium‐sulfur (Li‐S) batteries are promising candidates for advanced energy storage systems.
Sangeeta Sahu   +8 more
wiley   +1 more source

Thermally activated delayed fluorescence exciplex sensitizers with fast reverse intersystem crossing for improving efficiency stability of organic light‐emitting diodes based on multi‐resonance emitters

open access: yesFlexMat, EarlyView.
Two exciplex emitters are constructed based on a host‐guest doping strategy, and their exciton dynamics processes are investigated in depth. High‐performance OLEDs are fabricated by employing these exciplexes as emitters or sensitizers, providing excellent electroluminescence efficiencies and low efficiency roll‐offs.
Jingwen Xu   +4 more
wiley   +1 more source

Heteroatom location‐ and orientation mode‐dependent reverse intersystem crossing rate in multiple resonance emitters

open access: yesFlexMat, EarlyView.
By constructing two pairs of isomers with different heteroatom anchoring positions, the relationship between heteroatom location and orientation mode and reverse intersystem crossing rate constant (kRISC) in multiple resonance (MR) emitters is systematically investigated.
Tingting Huang   +5 more
wiley   +1 more source

Material design strategies for flexible n‐type polymer semiconductors

open access: yesFlexMat, EarlyView.
This Perspective surveys recent progress in flexible n‐type polymer semiconductors, emphasizing the interplay between molecular design and microstructure control. It outlines strategies including backbone and side‐chain engineering, multilevel microstructure optimization, to maintain charge‐transport pathways under mechanical deformation.
Xiao‐Yan Zhang   +4 more
wiley   +1 more source

Iron-catalyzed fluoroalkylative alkylsulfonylation of alkenes via radical-anion relay

open access: yesNature Communications
Transition metal-catalyzed reductive difunctionalization of alkenes with alkyl halides is a powerful method for upgrading commodity chemicals into densely functionalized molecules.
Xiaoya Hou, Hongchi Liu, Hanmin Huang
doaj   +1 more source

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