Results 1 to 10 of about 380,681 (345)

The DmsABC Sulfoxide Reductase Supports Virulence in Non-typeable Haemophilus influenzae

open access: yesFrontiers in Microbiology, 2021
Although molybdenum-containing enzymes are well-established as having a key role in bacterial respiration, it is increasingly recognized that some may also support bacterial virulence.
Rabeb Dhouib   +8 more
doaj   +1 more source

2,5-[C4+C2] Ringtransformation of Pyrylium Salts with α-Sulfinylacetaldehydes

open access: yesMolecules, 2023
A rapid synthesis of chiral sulfoxide-functionalized meta-terphenyl derivatives by a 2,5-[C4+C2] ring transformation reaction of pyrylium salts with in situ generated enantiomerically pure α-sulfinylacetaldehydes is described in this paper.
Dominik Bauer   +2 more
doaj   +1 more source

Synthesis of Polysubstituted Ferrocenesulfoxides

open access: yesMolecules, 2022
The purpose of the study is to design synthetic methodologies, especially directed deprotometalation using polar organometallic reagents, to access polysubstituted ferrocenesulfoxides.
Min Wen   +6 more
doaj   +1 more source

Vibrational spectroscopic force field studies of dimethyl sulfoxide and hexakis(dimethyl sulfoxide)scandium(III) iodide, and crystal and solution structure of the hexakis(dimethyl sulfoxide)scandium(III) ion [PDF]

open access: yes, 2004
Hexakis(dimethyl sulfoxide) scandium(III) iodide, [Sc(OS(CH3)(2))(6)]I-3 contains centrosymmetric hexasolvated scandium(III) ions with an Sc-O bond distance of 2.069(3) Angstrom.
Abbasi, A.   +3 more
core   +1 more source

Aplisulfamines, New Sulfoxide-Containing Metabolites from an Aplidium Tunicate: Absolute Stereochemistry at Chiral Sulfur and Carbon Atoms Assigned Through an Original Combination of Spectroscopic and Computational Methods

open access: yesMarine Drugs, 2012
Two new sulfoxide-containing metabolites, aplisulfamines A (1) and B (2), have been isolated from an Aplidium sp. collected in the Bay of Naples. Their planar structure and geometry of a double bond were readily determined by using standard methods ...
Rocco Vitalone   +5 more
doaj   +1 more source

Enantiomeric oxidation of organic sulfides by the filamentous fungi Botrytis cinerea, Eutypa lata and Trichoderma viride [PDF]

open access: yes, 2007
The biotransformations of a series of substituted sulfides were carried out with the filamentous fungi Botrytis cinerea, Eutypa lata and Trichoderma viride.
Annunziata   +28 more
core   +2 more sources

Crystal structure of methyl (2R,3S)-3-[(tert-butylsulfinyl)amino]-2-fluoro-3-phenylpropanoate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The title compound, C14H20FNO3S, contains two chiral carbon centres and the absolute configuration has been confirmed as (2R,3S). In the crystal, adjacent molecules are linked by weak C—H...O hydrogen bonds, generating zigzag chains along the a-axis ...
Zhiwei Zhao   +3 more
doaj   +1 more source

N-Methyl-(R)-3-(tert-Butyl)-Sulfinyl-1,4-Dihydropyridine: A Novel NADH Model Compound

open access: yesMolecules, 2007
We have synthesized a novel chiral NADH model compound, N-methyl-(R)-3-(tert-butyl)-sulphinyl-1,4-dihydropyridine with high enantioselectivity and used it in the reduction of methyl benzoylformate, producing (S)-methyl mandelate in 95% ee.
Thomas CW Mak   +5 more
doaj   +1 more source

Dimethyl sulfoxide solvates of the aluminium(III), gallium(III) and indium(III) ions. A crystallographic, EXAFS and vibrational spectroscopic study [PDF]

open access: yes, 2003
The isostructural hexakis( dimethyl sulfoxide)-aluminium(III), -gallium(III) and -indium(III) iodides crystallise in the trigonal space group R(3) over bar ( no. 148), Z = 3, at 295 +/- 1 K.
Alireza Molla-Abbassi   +5 more
core   +1 more source

Thiol-free chemoenzymatic synthesis of β-ketosulfides

open access: yesBeilstein Journal of Organic Chemistry, 2019
A preparation of β-ketosulfides avoiding the use of thiols is described. The combination of a multicomponent reaction and a lipase-catalysed hydrolysis has been developed in order to obtain high chemical diversity employing a single sulfur donor.
Adrián A. Heredia   +4 more
doaj   +1 more source

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