Results 21 to 30 of about 275,373 (371)

Palladium Catalyzed Allylic C-H Oxidation Enabled by Bicyclic Sulfoxide Ligands

open access: yesOrganics, 2023
The activation of C-H bonds is a potent tool for modifying molecular structures in chemistry. This article details the steps involved in a novel ligand bearing a bicyclic [3.3.1]-nonane framework and bissulfoxide moiety. A palladium catalyzed allylic C-H
Yuming Wen   +3 more
doaj   +1 more source

On the properties of a single OPLS-UA model curcumin molecule in water, methanol and dimethyl sulfoxide. Molecular dynamics computer simulation results [PDF]

open access: yesCondens. Matter Phys., vol. 20, No. 2, 23003 (2017), 2017
The properties of model solutions consisting of a solute --- single curcumin molecule in water, methanol and dimethyl sulfoxide solvents have been studied using molecular dynamics (MD) computer simulations in the isobaric-isothermal ensemble. The united atom OPLS force field (OPLS-UA) model for curcumin molecule proposed by us recently [J. Mol.
arxiv   +1 more source

Inhibition of methionine sulfoxide reduction by dimethyl sulfoxide

open access: yesBMB Reports, 2009
Dimethyl sulfoxide (DMSO) is widely used in chemistry and biology as a solvent and as a cryoprotectant. It is also used as a pharmaceutical agent for the treatment of interstitial cystitis and rheumatoid arthritis. Previous reports described DMSO as being reduced by methionine-S-sulfoxide reductase (MsrA).
Kim   +3 more
openaire   +4 more sources

Chiral cyclopentadienylruthenium sulfoxide catalysts for asymmetric redox bicycloisomerization

open access: yesBeilstein Journal of Organic Chemistry, 2016
A full account of our efforts toward an asymmetric redox bicycloisomerization reaction is presented in this article. Cyclopentadienylruthenium (CpRu) complexes containing tethered chiral sulfoxides were synthesized via an oxidative [3 + 2] cycloaddition ...
Barry M. Trost   +2 more
doaj   +1 more source

Design, Synthesis, and Biological Evaluation of Phenyloxadiazole Sulfoxide Derivatives as Potent Pseudomonas aeruginosa Biofilm Inhibitors

open access: yesMolecules, 2023
With the development of antimicrobial agents, researchers have developed new strategies through key regulatory systems to block the expression of virulence genes without affecting bacterial growth.
Xinyi Ye   +5 more
doaj   +1 more source

Hypoglycemic and hypolipidemic effect of S-allyl-cysteine sulfoxide (alliin) in DIO mice

open access: yesScientific Reports, 2018
Alliin (S-allyl cysteine sulfoxide) is a bioactive sulfoxide compound derived from garlic. To evaluate the preventive effect of alliin against metabolic risk factors in diet induced obese (DIO) mice, we treated the C57BL/6J DIO mice with drinking water ...
Baiqiang Zhai   +7 more
semanticscholar   +1 more source

Biotransformation of fenbendazole in sheep after administration of fenbendazole solid dispersion prepared by mechanochemical technique with arabinogalactane

open access: yesРоссийский паразитологический журнал, 2023
The purpose of the research is to study the biotransformation of fenbendazole in the body of sheep after administration of fenbendazole solid dispersion (FSD) prepared by mechanochemical technique with arabinogalactan. Materials and methods. The FSD at a
I. A. Arkhipov   +3 more
doaj   +1 more source

Apparent molar volume anomaly in water-dimethyl sulfoxide liquid mixtures. Molecular dynamics computer simulations [PDF]

open access: yesCondensed Matter Physics, 2022, vol. 25, No. 4, 44201, 2023
We have studied the composition dependence of density of liquid water-DMSO mixtures at different temperatures by using the isobaric-isothermal (NPT) molecular dynamics computer simulations. The non-polarizable semi-flexible, P1 and P2 models for the DMSO molecule combined with the TIP4P-2005 water model are considered.
arxiv   +1 more source

Adverse reactions of dimethyl sulfoxide in humans: a systematic review

open access: yesF1000Research, 2018
Background: Dimethyl sulfoxide (DMSO) has been used for medical treatment and as a pharmacological agent in humans since the 1960s. Today, DMSO is used mostly for cryopreservation of stem cells, treatment of interstitial cystitis, and as a penetrating ...
Bennedikte Kollerup Madsen   +3 more
semanticscholar   +1 more source

Diethyl Sulfoxide as a Novel Neutral Ligand in the Platinum Complex Anion [PDF]

open access: yesarXiv, 2021
Diethyl sulfoxide (DESO) is far less known than its shorter-alkyl-chain homolog, dimethyl sulfoxide. Although the field of senior dialkyl sulfoxides does not currently exhibit an explosive growth, new fundamental and applied research works routinely appear from a few research groups in the world.
arxiv  

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