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Beyond traditional defunctionalized cross-coupling reaction: scope, limitations, practicability & future prospects of recent electrochemical methodologies. [PDF]
Dhara S +8 more
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Strategic Synthesis of Sulfinamides as Versatile S(IV) Intermediates. [PDF]
Das S, Dhibar A, Sahoo B.
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Mild Transsulfinamidation Enables Rapid Access to Sulfinamides, Sulfonamides, and Sulfonimidamides. [PDF]
Jno Baptiste C, Shultz ZP, Lopchuk JM.
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Selective N=S Coupling Reactions of N-Methoxy Arylamides and Sulfoxides Catalyzed by Iron Salt. [PDF]
Jiang D +6 more
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Synthesis and Transformations of NH-Sulfoximines [PDF]
Abstract Recent years have seen a marked increase in the occurrence of sulfoximines in the chemical sciences, often presented as valuable motifs for medicinal chemistry. This has been prompted by both pioneering works taking sulfoximine containing compounds into clinical trials and the concurrent development of powerful synthetic ...
Leonardo Degennaro +2 more
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Syntheses and Transformations of Sulfoximines
The Chemical Record, 2020Abstract Sulfoximines are widely used as medicines, agricultural chemicals, chiral precursors, and chiral ligands in asymmetric synthesis, as well as pivotal intermediates for the construction of heterocyclic compounds. NH‐sulfoximines may be synthesized from thioethers, sulfoxides, sulfilimines, and sulfinamides.
Wenting Zheng +4 more
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International audienceAn efficient and convenient method is described that allows the synthesis of a set of difluoromethyl sulfoximines, as well as chlorofluoromethyl sulfoxides, sulfones, and sulfoximines.
Bruce Pégot +2 more
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The N-silylation of sulfoximines
Organic & Biomolecular Chemistry, 2015The copper-catalyzed N -silylation of sulfoximines was achieved in good to moderate yields in the presence of di- tert -butyl peroxide.
Haibo, Peng +4 more
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Copper-Catalyzed Oxidative Cross-Coupling of Sulfoximines and Alkynes
Copper-catalyzed oxidative cross-coupling of sulfoximines and ...
Carsten Bolm, Daniel L. Priebbenow
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Halocyclizations of Unsaturated Sulfoximines
Organic Letters, 2016A method for halocyclizations of S-alkenylsulfoximines is reported. When unsaturated NH-sulfoximines are treated with a combination of iodobenzene diacetate and potassium iodide, a transformation to the corresponding five- and six-membered cyclic products occurs providing S-oxides of dihydro isothiazoles and tetrahydro-1,2-thiazines, respectively, in ...
Han, Wang, Marcus, Frings, Carsten, Bolm
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