Results 61 to 70 of about 20,684 (285)

Chelator‐Free Radiometal Labeling Inside Engineered Affibodies

open access: yesAngewandte Chemie, EarlyView.
Affibodies are compact and robust three‑helix binders used in imaging and therapy. Engineering a triple‑cysteine motif into their core enables chelator‑free binding of important radiometals, like Bi(III), Pb(II), In(III), and Ga(III) with rapid uptake and exceptional stability.
Lani J. Davies   +6 more
wiley   +2 more sources

(Table 1) Whole rock sulfur isotope and sulfur concentrations of rocks from ODP Site 209-1270

open access: yes, 2007
(Table 1) Whole rock sulfur isotope and sulfur concentrations of rocks from ODP Site 209 ...
Alt, Jeffrey C   +9 more
core   +1 more source

Enhancing Biogenic Formic Acid Production in the Modified OxFA Process by Acetonitrile Addition

open access: yesAdvanced Science, EarlyView.
In this study, the beneficial effect of using acetonitrile as a co‐solvent in the modified OxFA process is shown, outperforming methanol, demonstrating improved reaction kinetics combined with high selectivity for the HPA‐2 (H5PV2Mo10O40) catalyzed oxidation of xylose to FA.
Jan‐Dominik H. Krueger   +7 more
wiley   +1 more source

A Non‐Covalent [4Fe–4S]/[2Fe] Interface in HydF Guides [FeFe]‐Hydrogenase Maturation

open access: yesAngewandte Chemie, EarlyView.
Bridged or not? 57Fe NRVS reveals a non‐covalent, electronically coupled interaction between the HydF [4Fe–4S] cluster and the [2Fe] precursor. Boltz‐2 structure predictions suggest that the cubane organizes lipoate‐dependent Hmet chemistry, positioning intermediates for assembly of the CH2–NH–CH2 bridge during H‐cluster biosynthesis.
Giorgio Caserta   +6 more
wiley   +2 more sources

New Frontiers for Sulfur Isotopic Analyses

open access: yesProcedia Earth and Planetary Science, 2015
AbstractMeasurements of sulfur stable isotope ratios (34S/32S) have suffered in the past from technical difficulties in analyzing low-S materials reducing their use despite their undeniable scientific interest. The measurement of 34S/32S ratios is a powerful tool for deciphering problems such as determining the sources of environmental pollutants, to ...
Fourel, François   +2 more
openaire   +2 more sources

(Table 1) Whole rock sulfur isotope and sulfur concentrations of rocks from ODP Hole 209-1272A

open access: yes, 2007
(Table 1) Whole rock sulfur isotope and sulfur concentrations of rocks from ODP Hole 209 ...
Alt, Jeffrey C   +9 more
core   +1 more source

Interfacial Proton‐Relay Microenvironment Enables Self‐Driven Singlet Oxygen Generation under Neutral Conditions

open access: yesAdvanced Science, EarlyView.
An interfacial proton‐relay microenvironment at MoS2‐CuCl heterostructures enables selective O2 activation to 1O2 under neutral conditions. Electron‐deficient sulfur sites mediate proton transfer to Cu‐bound O2, accelerating *OOH hydrogenation while suppressing O─O bond cleavage, achieving stable, efficient pollutant removal.
Qiaoyu Gao   +9 more
wiley   +1 more source

Quantitative Photo‐Reforming of Biomass to CO Spurred by In Situ Protonation of Carbon Dioxide Radical Anions

open access: yesAngewandte Chemie, EarlyView.
A “two‐in‐one” photoreduction strategy enabled by electron‐rich yolk Cd species both remote from and adjacent to sulfur vacancies is delivered to be ultraselective for the reduction of O2 and •CO2− in situ formed on the shell Bi2S3 composition (hole) by water oxidation and oxidative C–C cleavage of various biomass organic acids, furnishing CO with > 99%
Tengyu Liu   +5 more
wiley   +2 more sources

A Simple Elemental Sulfur Reduction Method for Isotopic Analysis and Pilot Experimental Tests of Symmetry‐Dependent Sulfur Isotope Effects in Planetary Processes

open access: yesGeochemistry, Geophysics, Geosystems, 2020
Recent insights into fundamental mechanisms underlying quadruple stable sulfur isotope (32S, 33S, 34S, and 36S) mass‐independent fractionation (S‐MIF) chemistry and potential implications for planetary processes highlight the urgent need of conducting ...
Mang Lin, Mark H. Thiemens
doaj   +1 more source

(Table 4) Sulfur isotope ratios of pyrite of ODP Hole 160-969D sediments

open access: yes, 2010
(Table 4) Sulfur isotope ratios of pyrite of ODP Hole 160-969D ...
James Farquhar (6968588)   +9 more
core   +1 more source

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