Results 211 to 220 of about 8,211 (262)

Unconventional hysteresis due to time-reversal symmetry breaking superconductivity in RbV<sub>3</sub>Sb<sub>5</sub>. [PDF]

open access: yesNat Commun
Wang S   +15 more
europepmc   +1 more source

Modulating Local Coordination in Single‐Atom Catalysts: From Fundamental Concepts to Emerging Breakthroughs in Electrocatalysis

open access: yesAngewandte Chemie, EarlyView.
This review summarizes atomic‐level design strategies for single‐atom catalysts, emphasizing modulation of the local coordination environment, active‐site geometry, and metal‐support interactions to optimize catalytic activity and stability in electrocatalytic energy conversion applications.
Ashwani Kumar, Harun Tüysüz
wiley   +1 more source

Fundamental Understanding of Oxidative Stability in Fluorinated Asymmetric Ethers for Li Batteries

open access: yesAngewandte Chemie, EarlyView.
To improve Li‐metal battery electrolytes, we analyze fluorinated 1‐ethoxy‐2‐methoxyethane (FxEME) oxidative stability via density functional theory (DFT) and molecular dynamics (MD). Fluorination strengthens ethoxy C–H bonds and alters solvent orientation at the cathode, weakening interfacial interactions.
Liang‐Ting Wu   +3 more
wiley   +1 more source

[O─I─O]+ Halogen‐Bonded Complexes of Pyridine N‐Oxides

open access: yesAngewandte Chemie, EarlyView.
The missing puzzle of 3‐center‐4‐electron halogen‐bonded complexes viz. [O─I─O]+ of pyridine N‐oxides are structurally characterized by x‐ray diffraction. Monodentate N‐oxide O‐atom acts as the halogen bond acceptor. Their solution complexations are characterized by 15N NMR spectroscopy.
Rakesh Puttreddy   +3 more
wiley   +1 more source

<i>N</i>-Aryl substituents have an influence on the photophysics of tetraaryl-pyrrolo[3,2-<i>b</i>]pyrroles.

open access: yesPhys Chem Chem Phys
Petrykowski WD   +5 more
europepmc   +1 more source

Defect‐Rich CoNi Prussian Blue Analogues Enable Highly Selective Electrochemical Hydrogen Peroxide Production

open access: yesAngewandte Chemie, EarlyView.
Introducing [Co(CN)6]3− defects into CoNi Prussian Blue analogues exposes square‐planar Ni–N4 active sites, leading to remarkable H2O2 selectivity during the electrochemical oxygen reduction reaction in alkaline media. ABSTRACT Decentralized electrosynthesis of hydrogen peroxide (H2O2) via the two‐electron oxygen reduction reaction (2e− ORR) offers a ...
Kai Sun   +4 more
wiley   +1 more source

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