Results 211 to 220 of about 5,424,192 (297)

Oxidation of Allylic Alcohols by Manganese Oxides: Elucidating the Influences of MnOx Structure and Mn Oxidation State on Reactivity

Chemistry – A European Journal, EarlyView.
Manganese oxides (MnOX) of different structures and with different Mn oxidation states exhibit significant variation in their reactivity toward the oxidation of allylic alcohols. Using two allylic alcohol model substrates, we demonstrate the relationship between activity and MnOX structure, Mn4+ content and incorporated secondary cations.
Erdogan Kasisari, Leandra Meyer, S. Esmael Balaghi, Harald Scherer, Patrick Elsässer, Anna Fischer, Philipp Kurz   +6 more
wiley   +1 more source

Creation, implementation, and evaluation of an OER forensic chemistry CURE using high impact practices. [PDF]

Forensic Sci Int Synerg
Landge S, Ghosh D, Ramasamy V, Sargent EC.   +3 more
europepmc   +1 more source

The Mechanism of Visible‐Light Photochemical Rearrangements of Conjugated Amide Enolates

Chemistry – A European Journal, EarlyView.
Visible light irradiation of extended enolates of N‐benzylamides leads to homolytic C─N Bond cleavage, generating a biradical. Computational and mechanistic studies suggest rapid radical recombination within a solvent cage to give either ring‐expanded or rearranged products. ABSTRACT Deprotonation of conjugated amides forms colored solutions of lithium
James Mortimer, William Terry‐Wright, Basile F. E. Curchod, Jonathan Clayden   +3 more
wiley   +1 more source

Nutrition Education in Greek Secondary School Textbooks: A Content Analysis of Coverage and Thematic Orientation. [PDF]

Nutrients
Chronakis AE, Vassilopoulou E, Vardaka E, Papadopoulos A.   +3 more
europepmc   +1 more source

Regioisomerism Rewires Optical and Ion Recognition Properties in Azulenylsumanenes—Curved Non‐Alternant π‐Systems

Chemistry – A European Journal, EarlyView.
Regioisomerism rewires orbital topology and electronic polarity in curved non‐alternant π‐systems, switching both optical response and alkali metal ion recognition from Na+ to Rb+ selectivity. ABSTRACT Herein, we explore the fundamental concept of combining the molecular curvature of a molecular fragment of buckminsterfullerene with the pronounced ...
Jakub Cyniak, Anna Mazur, Bartłomiej Pigulski, Hidehiro Sakurai, Artur Kasprzak   +4 more
wiley   +1 more source

Development of effective 3D digital models for first-time learners of musculoskeletal anatomy. [PDF]

Anat Sci Educ
Safir AH, Bird MM, Orczykowski ME.
europepmc   +1 more source

Comparison of modelling approaches for liquid fluidized beds

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract This study presents a comparison of three promising numerical models for the detailed simulation of liquid–solid fluidized bed. These models differ in their treatment of the solid phase, ranging from treating each particle individually to treating the collection of particles as a continuum.
Andreu Bernad‐Serra, Furkhat Khamitov, Olli H. Sorvari, Ville Alopaeus   +3 more
wiley   +1 more source

Validation of Textbook Outcome in Gastric Surgery (TOGS) for Primary Gastric Cancer in an Eastern High-Volume Center. [PDF]

Ann Surg Oncol
Carbone L, Cho YS, Kang MK, Park K, Kim JC, Kim SH, Kim J, Kalaw NR, Kwak Y, Lee HS, Kong SH, Park DJ, Marrelli D, Yang HK, Roviello F, Lee HJ.   +15 more
europepmc   +1 more source

Gibbs energy minimization thermodynamics for CO2 capture by aqueous amines: Conservation laws, concentration variables, and parameter consistency

The Canadian Journal of Chemical Engineering, EarlyView.
We clarify how Gibbs‐energy‐minimization models for aqueous‐amine CO2 capture fail when conservation constraints and concentration conventions are inconsistent. Exact standard‐state conversions and Reaktoro case studies show that P(CO2)‐loading fits can mask non‐unique parameters and wrong speciation, motivating complete water‐inclusive formulations ...
William R. Smith, William Rutherford, Allan M. M. Leal   +2 more
wiley   +1 more source

Illusion of competence: vision-language models provide confident but inaccurate explanations in cytological diagnostics. [PDF]

Sci Rep
Kukuljan I, Dasdelen MF, Schäfer J, Buck M, Götze KS, Marr C.   +5 more
europepmc   +1 more source