Results 131 to 140 of about 18,813 (295)

Smart Exploration of Perovskite Photovoltaics: From AI Driven Discovery to Autonomous Laboratories

open access: yesAdvanced Energy Materials, EarlyView.
In this review, we summarize the fundamentals of AI in automated materials science, and review AI applications in perovskite solar cells. Then, we sum up recent progress in AI‐guided manufacturing optimization, and highlight AI‐driven high‐throughput and autonomous laboratories.
Wenning Chen   +4 more
wiley   +1 more source

Dual Impact of Long‐Lived Localized Carriers Induced by Restricted Hole Transfer in Organic Photovoltaics and Photocatalytic Hydrogen Evolution

open access: yesAdvanced Energy Materials, EarlyView.
This work clarifies why organic semiconductors perform differently in photovoltaic devices and photocatalytic nanoparticles. By examining D18:Y5 and PM6:Y6 systems, we show how aggregation, exciton lifetime, and interfacial charge transfer behavior govern energy‐conversion pathways.
Gayoung Ham   +14 more
wiley   +1 more source

Precisely Controlled Electrochemical Phosphonylation: Tailoring π‐Conjugated Polymer Properties for High‐Performance Organic Electrochemical Transistors

open access: yesAngewandte Chemie, EarlyView.
The electrochemical C–H phosphonylation enabled precise control over the degree of functionalization (DOF). Systematic tuning of DOF (0.06–0.16) led to improved µC*, transconductance, and time constant values. This finding demonstrates that moderate functionalization enhances organic electrochemical transistor (OECT) performance, opening new avenues ...
Kohei Taniguchi   +2 more
wiley   +2 more sources

Organic cosmo- and geochemical studies on thiophenes in carbonaceous chondrite and sedimentary rocks [PDF]

open access: yes, 2001
Meteorites are extraterrestrial materials formed in the early solar nebula about 4.6 billion years ago. Carbonaceous chondrites which belong one oh meteorite groups contain various kinds of extraterrestrial organic compounds formed by abiotic process ...
Katsumata Hideyuki, 勝又 英之
core  

Molecular Design and Interfacial Functions of Self‐Assembled Monolayers for Perovskite and Tandem Solar Cells

open access: yesAdvanced Energy Materials, EarlyView.
We identify two decisive levers for SAM interfaces: molecular design (carboxylic acid‐based, phosphonic acid, other anchoring chemistries, and polymeric SAMs) and mixing routes (co‐assembly, in situ assembly, pre‐ and post‐treatment). Coordinated tuning of headgroups and assembly pathways optimises energy alignment and film formation, suppresses ...
Jiaxu Zhang, Bochun Kang, Feng Yan
wiley   +1 more source

Deprotonative C(sp3)/C(sp2)–H (Multi)Silylation of (Hetero)Arenes Mediated by NaTMP

open access: yesAngewandte Chemie, EarlyView.
An operationally simple protocol using a strongly basic sodium amide in combination with sterically emcumbered silicon electrophiles enables the deprotonative C–H (multi)silylation of a myriad of (hetero)arenes. Mechanistic investigations highlight the pivotal role of steric and coordination effects in controlling the regioselectivity and efficiency of
David Sánchez‐Roa   +6 more
wiley   +2 more sources

Electrochromic properties of 'Trimeric' thiophene-pyrrole-thiophene

open access: yes, 2008
A centrosymmetric polymer precursor, namely 6-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)hexan-1-amine (TPHA), was synthesized via a Knorr-Paal reaction using 1,4-di(2-thienyl)-1,4-butanedione and hexane-1,6-diamine. The resultant monomer was characterized by Nuclear Magnetic Resonance (H-1-NMR).
Tarkuc, S, Ak, M, Onurhan, E, Toppare, L
openaire   +1 more source

Organic Photoelectrochemical Cells Beyond Performance: Interface and Catalyst Engineering for Durability

open access: yesAdvanced Energy Materials, EarlyView.
Organic photoelectrochemical cells based on π‐conjugated semiconductors offer a versatile platform for solar fuel generation. This review outlines operating principles, device architectures, and key metrics, and highlights advances in p‐ and n‐type photoelectrodes, interfacial engineering, and catalyst integration.
Jaehyeong Kim   +8 more
wiley   +1 more source

Biocatalytic Synthesis of Isoxazolines Enabled by Cryptic Nitrile Oxide Formation by a Vanadium‐Dependent Chloroperoxidase

open access: yesAngewandte Chemie, EarlyView.
The vanadium‐dependent haloperoxidase (VHPO) class of enzymes has been shown to catalyze cryptic nitrile oxide generation in an oxidative [3+2] cycloaddition reaction between aldoximes and alkenes to generate isoxazolines. This biotechnology has been applied to a chemoenzymatic sequence starting from aldehydes through in situ condensation with ...
Manik Sharma, Kyle F. Biegasiewicz
wiley   +2 more sources

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