Results 151 to 160 of about 12,222 (276)

Accelerating Discovery of Organic Molecular Crystals via Materials Informatics and Autonomous Experiments

Advanced Intelligent Discovery, EarlyView.
Materials informatics and autonomous experimentation are transforming the discovery of organic molecular crystals. This review presents an integrated molecule–crystal–function–optimization workflow combining machine learning, crystal structure prediction, and Bayesian optimization with robotic platforms.
Takuya Taniguchi, Kazuki Ishizaki, Ryo Fukasawa   +2 more
wiley   +1 more source

A de‐novo Approach Towards Divergent [3+2π/σ] Photocycloadditions of Nitrones via Assembly‐Controlled Kinetic Electron Transfer Gating

Angewandte Chemie, EarlyView.
A metal‐free photocatalytic platform converts nitrones into 4‐isoxazolines and oxa–aza–bicycloheptanes through divergent [3+2π/σ] cycloadditions. Assembly‐controlled kinetic electron transfer gating dictates substrate activation, enabling selective reactivity beyond thermodynamic expectations.
Nayan Saha, Rajesh Kancherla, Jorge Escorihuela, Shana Chandran, Mrinal K. Bera, Magnus Rueping, Burkhard König   +6 more
wiley   +2 more sources

Assessing cell survival and biosignature preservation of the extremely thermoacidophilic archaeon <i>Acidianus manzaensis</i> after exposure to Mars-like conditions. [PDF]

FEMS Microbes
Gfellner SV, Groninga J, Colas C, Gabant G, Lorek A, Garland S, Baqué M.   +6 more
europepmc   +1 more source

Generative and Experimental Validation of High Refractive Index Polymers via Domain Knowledge Approach with Small Data

Advanced Intelligent Discovery, EarlyView.
This research demonstrates that the combination of domain knowledge–based multiple regression, multi‐objective Bayesian optimization, and generative models is a suitable prediction tool for candidates of high refractive index polymers, even with the constraints in the model trained on limited data. The experimental validation can reproduce the proposed
Takuya Yokoo, Seigo Watanabe, Hana Matsunaga, Kenichi Oyaizu   +3 more
wiley   +1 more source

Cobalt‐Catalyzed C─N Bond Formation via Metal‐Hydride Hydrogen Atom Transfer (MHAT)

Angewandte Chemie, EarlyView.
Cobalt‐catalyzed metal‐hydride hydrogen atom transfer (Co‐MHAT) converts simple alkenes into C─N bonds under mild, near‐neutral conditions. A shared Co─H‐initiated radical/organocobalt intermediate is channeled into radical trapping, radical‐polar crossover, or radical ligand transfer, unifying hydroamination, hydroazidation, hydroamidation, and remote
Arman Khosravi, Ming‐Yu Ngai
wiley   +2 more sources

Beyond Aroma: Analytical Challenges, Metabolism and Biological Significance of Volatile Sulfur Compounds in Tomato Plants. [PDF]

Int J Mol Sci
Nawrocka J, Szymczak K, Świercz-Pietrasiak U, Bonikowski R.   +3 more
europepmc   +1 more source

Electrochromic properties of 'Trimeric' thiophene-pyrrole-thiophene

, 2008
A centrosymmetric polymer precursor, namely 6-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)hexan-1-amine (TPHA), was synthesized via a Knorr-Paal reaction using 1,4-di(2-thienyl)-1,4-butanedione and hexane-1,6-diamine. The resultant monomer was characterized by Nuclear Magnetic Resonance (H-1-NMR).
Tarkuc, S, Ak, M, Onurhan, E, Toppare, L
openaire   +1 more source

The monoethylbenzo(b)thiophenes: syntheses and mass spectra

, 1969
The six monoethylbenzo(b)thiophenes were synthesized, the products characterized and their structures unambiguously proven. Of the six, the 4-, 5- and 6-ethylbenzo(b)thiophenes were previously unreported.
Ritter, Melvin L.
core  

Non‐Covalent PL, CD, and CPL Activation of Linear Aromatic Oligomers within Axially Chiral Aromatic Capsules

Angewandte Chemie, EarlyView.
Linear aromatic oligomers display intense photoluminescence (PL), circular dichroism (CD), and circularly polarized luminescence (CPL) properties upon non‐covalent encapsulation by axially‐chiral aromatic capsules under ambient aqueous conditions.
Yoshihisa Hashimoto, Yuya Tanaka, Daiki Tauchi, Masashi Hasegawa, Michito Yoshizawa   +4 more
wiley   +2 more sources

Stable Vicinal Bisketene Equivalents for Aryne Diels-Alder Reactions. [PDF]

Synlett
Budwitz JE, Newton CG.
europepmc   +1 more source