Results 151 to 160 of about 18,813 (295)

Intermolecular Electrophilic Germylation Using GeCl4 and Al2Cl6

Angewandte Chemie, EarlyView.
While electrophilic aromatic substitution is well‐established for carbon and silicon‐based electrophiles, it is extremely underdeveloped for germanium. Herein we report the first effective intermolecular Germa–Friedel–Crafts reaction. The process can be modified to enable selective synthesis of the mono‐ or the di‐aryl germane derivatives, ArGeCl3 and ...
Justyna Łosiewicz, Milan Kumar Bisai, Zachary A. Bub, Stuart A. Macgregor, Michael J. Ingleson   +4 more
wiley   +2 more sources

Radikale Kaskadenreaktion, welche die Kreuzkupplung von Olefinen mit der Smiles‐Truce‐Umlagerung kombiniert

Angewandte Chemie, EarlyView.
Wir stellen eine kobaltkatalysierte Radikalkaskade vor, die zwei Alken Ausgangsstoffe effizient miteinander verbindet und so in einem einzigen Schritt mehrere Bindungen aufbaut. Der Prozess beginnt mit einem kobaltkatalysierten Wasserstoffatomtransfer an eine Styrol‐Doppelbindung, gefolgt von einer Giese‐Addition.
Jingyang Qin, Lucas Popek, Moritz Wyrtki, Christopher J. Teskey   +3 more
wiley   +1 more source

Stable Vicinal Bisketene Equivalents for Aryne Diels-Alder Reactions. [PDF]

Synlett
Budwitz JE, Newton CG.
europepmc   +1 more source

Thiophene Derivatives as Versatile Precursors for (Hetero)Arene and Natural Product Synthesis. [PDF]

Angew Chem Int Ed Engl
Keimer A, Haut FL.
europepmc   +1 more source

Regioselective C-Arylation of Functionalized Nitroalkanes with Furan, Thiophene, and Substituted Thiophenes. [PDF]

J Org Chem
Detková KR, Jakubcová K, Malatinský T, Filo J, Cigáň M, Budzák Š, Medved' M, Jakubec P.   +7 more
europepmc   +1 more source

Radical Cascade Combining Cross‐Olefin Coupling with the Smiles‐Truce Rearrangement

Angewandte Chemie International Edition, EarlyView.
We present a cobalt‐catalysed radical cascade that efficiently merges two alkene starting materials to form multiple bonds in a single step. The process begins with a cobalt‐catalysed hydrogen‐atom transfer‐to a styrene double bond, followed by a Giese addition.
Jingyang Qin, Lucas Popek, Moritz Wyrtki, Christopher J. Teskey   +3 more
wiley   +1 more source

Inter-and Intramolecular (4+3) Cycloadditions With Epoxy Allylsilanes as Dienophiles. [PDF]

Chem Asian J
Teo QH, Zhou Y, Krenske EH, Chiu P.
europepmc   +1 more source

Thiadizoloquinoxaline-Based Low-Bandgap Conjugated Polymers as Ambipolar Semiconductors for Organic Field Effect Transistors [PDF]

, 2014
An, C., Baumgarten, M., Berger, R., Li, D., Li, M., Marszalek, T., Pisula, W.   +6 more
core   +2 more sources

Feedstock-Derived Thiophene Radical Anions Exhibiting Redox Stability at Extreme Potentials. [PDF]

Angew Chem Int Ed Engl
Gasser AC, Käch D, Bezdek MJ.
europepmc   +1 more source

Combined Gravimetric, Electrochemical, and Computational Research on Benzothiophene Derivatives as Effective Corrosion Inhibitors for Mild Steel

Asia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT Four benzothiophenes, thianaphthene (BT‐1), 3‐bromothianaphthene (BT‐2), benzo[b]thiophene‐2‐carboxaldehyde (BT‐3), and benzo[b]thiophene‐2‐carbonitrile (BT‐4), were tested as mild steel corrosion inhibitors in 1‐M HCl. The compounds have the similar benzothiophene core but differ in the substituents bound to the ring.
Nhlanhla G. Chirwa, Motsie Elija Mashuga, Mohammad Salman, Indra Bahadur   +3 more
wiley   +1 more source