Results 191 to 200 of about 48,169 (270)

Deprotective Functionalization: An Emerging Concept for Amine Reactivity

open access: yesChemistry – A European Journal, Volume 32, Issue 4, 23 January 2026.
While protecting groups are indispensable in total synthesis to avoid undesired reactivity, installation and removal of protecting groups lead to an increase in the step‐count, cost, waste production and time requirement. One approach tackling these drawbacks is deprotective functionalization, which combines deprotection and postfunctionalization in a ...
Irmgard Tiefenbrunner   +2 more
wiley   +1 more source

On the Nature of Improper Hydrogen Bonding in RCH2F and RCHF2 Motifs

open access: yesAngewandte Chemie, Volume 138, Issue 2, 9 January 2026.
The nature of ‘improper’ hydrogen bonds is explored in FnC─H⋯X systems, such as RCF2H interaction with chloride and water. It is noted that increased fluorination decreases the positive charge density on H but increases it on C, thus these interactions are dominated by electrostatic attraction to C over H.
Bruno A. Piscelli   +3 more
wiley   +2 more sources

Tailored Catalysts Based on Polymers of Intrinsic Microporosity for Asymmetric Aza-Henry Reaction of Pyrazolinone Ketimines in Batch and Flow. [PDF]

open access: yesACS Appl Polym Mater
Sánchez-Molpeceres R   +6 more
europepmc   +1 more source

Bioinspired Synthesis of Twin abeo‐Steroids Bufogargarizins A and B via a Divergent Intramolecular Aldol Addition Reaction

open access: yesAngewandte Chemie, Volume 138, Issue 2, 9 January 2026.
Twin natural products. This manuscript describes a concise biomimetic synthesis of twin abeo‐steroids bufogargarizins A and B with an unusual [7.5.6.5] and [5.7.6.5] skeletons in 19 steps (LLS). The described synthetic approach features the application of a bioinspired regiodivergent intramolecular aldol addition reaction and a selective singlet oxygen‐
Zoey J. Surma   +7 more
wiley   +2 more sources

Thiourea modification of fluorescent nanodiamonds towards enhanced quantum sensing

open access: green
Ádám Gali   +4 more
openalex   +1 more source

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