Deprotective Functionalization: An Emerging Concept for Amine Reactivity
While protecting groups are indispensable in total synthesis to avoid undesired reactivity, installation and removal of protecting groups lead to an increase in the step‐count, cost, waste production and time requirement. One approach tackling these drawbacks is deprotective functionalization, which combines deprotection and postfunctionalization in a ...
Irmgard Tiefenbrunner +2 more
wiley +1 more source
On the Nature of Improper Hydrogen Bonding in RCH2F and RCHF2 Motifs
The nature of ‘improper’ hydrogen bonds is explored in FnC─H⋯X systems, such as RCF2H interaction with chloride and water. It is noted that increased fluorination decreases the positive charge density on H but increases it on C, thus these interactions are dominated by electrostatic attraction to C over H.
Bruno A. Piscelli +3 more
wiley +2 more sources
Tailored Catalysts Based on Polymers of Intrinsic Microporosity for Asymmetric Aza-Henry Reaction of Pyrazolinone Ketimines in Batch and Flow. [PDF]
Sánchez-Molpeceres R +6 more
europepmc +1 more source
Twin natural products. This manuscript describes a concise biomimetic synthesis of twin abeo‐steroids bufogargarizins A and B with an unusual [7.5.6.5] and [5.7.6.5] skeletons in 19 steps (LLS). The described synthetic approach features the application of a bioinspired regiodivergent intramolecular aldol addition reaction and a selective singlet oxygen‐
Zoey J. Surma +7 more
wiley +2 more sources
Enhancing faba bean (Vicia faba) productivity under drought stress through modulation of physiological traits and antioxidant enzyme system using thiourea and hydrogel. [PDF]
Ramadan AA +4 more
europepmc +1 more source
Evaluation of Various Thiourea Derivatives as Reducing Agents in Two-Component Methacrylate-Based Materials. [PDF]
Ohl C +5 more
europepmc +1 more source
Thiourea modification of fluorescent nanodiamonds towards enhanced quantum sensing
Ádám Gali +4 more
openalex +1 more source
Harnessing Noncovalent π‑Type Interactions in Thiourea-Chloride Supramolecular Complexes: Toward the Asymmetric Dearomatization of Diazaheterocycles. [PDF]
Velázquez M +6 more
europepmc +1 more source

