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Up to date, only a few kinds of poly(azomethine-urethane)s (PAMUs) were synthesized and studied with thermal degradation steps. However, polyphenol based PAMUs including azomethine linkages have not been investigated yet.
Avci, A, Kaya, I
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Toluene 2,4-diisocyanate and bowel obstruction: occupational medicine aspect of a case report.
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Form, function and functionality of two dimeric toluene-2,4-diisocyanate polymorphs
2,4-Dioxo-1,3-diazetidine-1,3-bis(methyl-m-phenylene) diisocyanate (dimerized toluene-2,4-diisocyanate, TDI) is one of the most widely used aromatic diisocyanates in the polymer industry, and it crystallizes in at least two polymorphic forms (form A and form B) depending on reaction conditions.
Vella-Zarb, L., Dinnebier, R.
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Catalytic synthesis of toluene-2,4-diisocyanate from dimethyl carbonate
Journal of Chemical Technology and Biotechnology, 2001AbstractThe process for catalytic synthesis of toluene‐2,4‐diisocyanate (TDI) from dimethyl carbonate (DMC) consists of two steps. Starting from the catalytic reaction between toluene‐2,4‐diamine (TDA) and DMC, dimethyl toluene‐2,4‐dicarbamate (TDC) is formed, and then decomposed to TDI. For the first step, the yield of TDC is 53.5% at a temperature of
Yanji Wang, Xinqiang Zhao, Fang Li
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Journal of Hazardous Materials, 2013
Toluene diisocyanate (TDI) is a large volume chemical used for the production of polyurethanes. It is sparingly soluble in water, but hydrolyses instantaneously liberating toluene diamine (TDA), which is highly reactive to TDI. The ecotoxicity of TDI is dominated by TDA.
Thomas Schupp
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Toluene diisocyanate (TDI) is a large volume chemical used for the production of polyurethanes. It is sparingly soluble in water, but hydrolyses instantaneously liberating toluene diamine (TDA), which is highly reactive to TDI. The ecotoxicity of TDI is dominated by TDA.
Thomas Schupp
exaly +3 more sources
The effects of toluene diisocyanate and of capsaicin on human bronchial smooth muscle in vitro
Toluene diisocyanate contracts guinea-pig bronchial smooth muscle through a mechanism involving capsaicin-sensitive sensory nerves. In the present study, we investigated the effects of toluene diisocyanate, capsaicin and tachykinins on isolated human ...
Francesco Calabro +2 more
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Isocyanates are an important cause of occupational asthma. The mechanism of isocyanate-induced asthma is still unknown. To determine whether toluene diisocyanate stimulates the 'efferent' function of peripheral endings of capsaicin-sensitive sensory ...
C E Mapp +2 more
exaly +1 more source
Diisocyanate is a leading cause of occupational asthma (OA). Diisocyanate-induced OA is an inflammatory disease of the airways that is associated with airway remodelling.
Seung-Hyun Kim +2 more
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