Results 161 to 170 of about 4,327 (260)

Stabilizing the Hexacyanotrimethylenecyclopropane Electron Acceptor—Structural and Photophysical Characterization

open access: yesAngewandte Chemie International Edition, EarlyView.
An improved low‐temperature synthesis enables the first comprehensive structural and spectroscopic characterisation of neutral hexacyanotrimethylenecyclopropane (CN6CP). Combined IR/Raman, UV–Vis and ssNMR analyses reveal a deeper understanding of its oxidation‐state‐dependent charge redistribution, σ‐aromaticity of the cyclopropane core, and redox ...
Jan P. Soyka   +8 more
wiley   +1 more source

Overcrowded Alkene Photo‐Redox‐Switches Based on Quinolinium/Carbene Building Blocks

open access: yesAngewandte Chemie International Edition, EarlyView.
A modular synthesis of a new class of photo‐ and redox‐switches is described based on the combination of quinolinium salts and carbenes. Photochemical switching allows to selectively switch between folded E/Z isomers, while electrochemical switching allows to change between neutral, radical cation and dicationic oxidation states, which are all isolable
Chris Burdenski   +10 more
wiley   +1 more source

Comparative analysis of isokinetic ratios between hamstrings and quadriceps in wrestlers: Resting state versus post-fatigue evaluation. [PDF]

open access: yesPLoS One
Tatlıcı A   +8 more
europepmc   +1 more source

Research on Diaphragm Pump Fault Diagnosis Method Based on Res‐DCB‐Net

open access: yesAsia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT Nonstationary pressure pulsation signals of diaphragm pumps contain strong background noise and coupled characteristics. This makes it challenging to extract incipient fault features and to decouple faults with similar physical mechanisms. To address these limitations, this paper proposes a spatiotemporal fault diagnosis model named Res‐DCB ...
Jiahui Wang   +7 more
wiley   +1 more source

A New Paradigm for Understanding the Rheology and Processability of Poly(p‐Phenylene Terephthalamide) Liquid‐Crystalline Solutions

open access: yesJournal of Applied Polymer Science, EarlyView.
Kevlar is traditionally modeled as a rigid‐rod polymer, yet rheological behavior deviates from this assumption. The review introduces a novel “twist‐tie” entanglement theory for aramid polymer chains in the nematic liquid crystal state, providing a molecular explanation for deviations from rigid‐rod models. Understanding twist‐tie entanglement dynamics
Emma Egli   +3 more
wiley   +1 more source

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