Results 51 to 60 of about 158,251 (314)

Sustainable manganese catalysis for late-stage C–H functionalization of bioactive structural motifs

open access: yesBeilstein Journal of Organic Chemistry, 2021
The late-stage C–H functionalization of bioactive structural motifs is a powerful synthetic strategy for accessing advanced agrochemicals, bioimaging materials, and drug candidates, among other complex molecules.
Jongwoo Son
doaj   +1 more source

Structural insights into an engineered feruloyl esterase with improved MHET degrading properties

open access: yesFEBS Letters, EarlyView.
A feruloyl esterase was engineered to mimic key features of MHETase, enhancing the degradation of PET oligomers. Structural and computational analysis reveal how a point mutation stabilizes the active site and reshapes the binding cleft, expading substrate scope.
Panagiota Karampa   +5 more
wiley   +1 more source

The Phonon Entropy of Transition Metals and Alloys: Effects of Impurities and of a Martensitic Phase Transition [PDF]

open access: yes, 2006
For a fixed configuration of ions on a given crystalline lattice, low energy excitations around the static average configuration can be thermally activated and will contribute to the entropy of the system.
Delaire, Olivier
core   +1 more source

Transition Metal Carbides and Nitrides as Electrode Materials for Low Temperature Fuel Cells

open access: yesEnergies, 2009
Transition metal carbides (TMCs) and transition metal nitrides (TMNs) have attracted attention as promising electrocatalysts that could replace noble metals of high price and limited supply. Relative to parent metals, TMC and TMN behave like noble metals
Jae Sung Lee, Dong Jin Ham
doaj   +1 more source

pH‐mediated activation of the lysosomal arginine sensor SLC38A9

open access: yesFEBS Letters, EarlyView.
Cells monitor nutrient levels via the lysosomal transporter SLC38A9 to activate the mechanistic target of rapamycin complex 1 (mTORC1). This study reveals that SLC38A9 function is regulated by pH. We identified histidine 544 as a critical pH sensor that undergoes conformational changes to control amino acid efflux from lysosomes; therefore, it ...
Xuelang Mu, Ampon Sae Her, Tamir Gonen
wiley   +1 more source

Temperature Dependence of Phonons in Elemental Cubic Metals Studied by Inelastic Scattering of Neutrons and X-Rays

open access: yes, 2009
The vibrations of atoms in a crystal (phonons) make up the majority of its entropy (or heat capacity), and these vibrations are typically modeled by simple harmonic oscillators.
Kresch, Max G.
core   +1 more source

Swelling and removal of metal in zeolit alam lampung (ZAL) using a swelling agent C15H32 [PDF]

open access: yesE3S Web of Conferences
Natural Zeolite, especially Zeolit Alam Lampung (ZAL) from Indonesia is a natural zeolite with a clinoptilatite-type crystal with a hollow structure. One option in modifying ZAL in the chemical field, especially catalysts and adsorbents, is the swelling ...
Susmanto Prahady   +3 more
doaj   +1 more source

On dithiothreitol (DTT) as a measure of oxidative potential for ambient particles: evidence for the importance of soluble ewline transition metals [PDF]

open access: yesAtmospheric Chemistry and Physics, 2012
The rate of consumption of dithiothreitol (DTT) is increasingly used to measure the oxidative potential of particulate matter (PM), which has been linked to the adverse health effects of PM. While several quinones are known to be very reactive in the DTT
J. G. Charrier, C. Anastasio
doaj   +1 more source

Transition-metal-mediated C-C bond activation: Recent advances and its applications in organic synthesis

open access: yesResults in Chemistry, 2023
Transition metals are well known for their catalytic behaviours for the activation of the Carbon-Carbon (C-C) bond. Many chemists have created various important developments in this field during the last decades.
Nand Lal Verma   +6 more
doaj   +1 more source

An unexpected alternative viologen electron mediator site in tungsten‐containing formate dehydrogenase

open access: yesFEBS Letters, EarlyView.
An unexpected alternative interaction site for ethyl viologen was identified in formate dehydrogenase 1 from Methylorubrum extorquens. Combined mutagenesis, kinetic analysis, and docking revealed that aromatic residues near an iron–sulfur cluster enable flavin mononucleotide‐independent electron transfer, offering a framework for engineering improved ...
Eleni G. Poloniataki, Yong Hwan Kim
wiley   +1 more source

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