Results 111 to 120 of about 1,340 (176)

The Role of Electron Transfer in Copper-Mediated C(sp²)-H Trifluoromethylation. [PDF]

Angew Chem Int Ed Engl
Ball MAP, Myers PJ, Ritch GD, Bower JK, Moore CE, Szymczak NK, Zhang S.   +6 more
europepmc   +1 more source

Synergizing Electrons and Photons in Motion: Continuous-Flow Implementation in Electro- and Photocatalyzed C-H Functionalization. [PDF]

JACS Au
Peters SE, von Münchow T, Ackermann L.
europepmc   +1 more source

A facile synthesis of CF₃-containing iminoisobenzofurans via copper-catalyzed oxygen trifluoromethylation-cyclization of o-vinyl-N-alkylamide. [PDF]

RSC Adv
Gao S, Zhou Q, Liu Z, Xie S, Yang D, Zhang K, Zhang Z.   +6 more
europepmc   +1 more source

The organophotocatalytic trifluoromethylation of 6-azauracils. [PDF]

RSC Adv
Das KK, Hajra A.
europepmc   +1 more source

Photoelectrochemical High-Value-Added Chemical Production with Improved Selectivity. [PDF]

Research (Wash D C)
Li Y, Chen T, Chen Y.
europepmc   +1 more source

[4 + 2] Cycloaddition of α-bromotrifluoromethylhydrazone with alkenes: synthesis of trifluoromethyltetrahydropyridazines. [PDF]

RSC Adv
Zhao Y, Rong H, Bozorov K, Zhang X, Song B, Liu W.   +5 more
europepmc   +1 more source

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Radical trifluoromethylation

Chemical Society Reviews, 2021
Radical trifluoromethylation has been emerging as a versatile tool for the synthesis of trifluoromethylated compounds that play increasingly important roles in pharmaceuticals, agrochemicals and materials science.
Haiwen Xiao, Zhenzhen Zhang, Yewen Fang, Lin Zhu, Chaozhong Li   +4 more
openaire   +2 more sources

The Trifluoromethyl Anion

Angewandte Chemie, 2015
AbstractFirst evidence for the existence of free trifluoromethyl anion CF3− has been obtained. The 3D‐caged potassium cation in [K(crypt‐222)]+ is inaccessible to CF3−, thus rendering it uncoordinated (“naked”). Ionic [K(crypt‐222)]+ CF3− has been characterized by single‐crystal X‐ray diffraction, solution NMR spectroscopy, DFT calculations, and ...
Anton, Lishchynskyi, Fedor M, Miloserdov, Eddy, Martin, Jordi, Benet-Buchholz, Eduardo C, Escudero-Adán, Andrey I, Konovalov, Vladimir V, Grushin   +6 more
openaire   +2 more sources

Trifluoromethylated Heterocycles

Current Topics in Medicinal Chemistry, 2014
This review is a follow-up to the previous chapter, "Monofluorinated Heterocycles" (Topics in Heterocyclic Chemistry, 2012, 33-63), and presents an overview of synthetic chemistry of heterocycles with only one trifluoromethyl group directly attached to the ring (trifluoromethylated heterocycles).
Andrei A, Gakh, Yuriy, Shermolovich
openaire   +2 more sources

Direct Preparation of Trifluoromethyl Ketones from Carboxylic Esters: Trifluoromethylation with (Trifluoromethyl)trimethylsilane

Angewandte Chemie International Edition, 1998
Previously difficult to prepare, aliphatic and alicyclic trifluoromethylketones (e.g. 1 and 2), which are of pharmacalogic interest as potential enzyme inhibitors, can now be synthesized easily and efficiently. The one-step reaction starting with carbonic esters and trimethyl(trifluoromethyl)silane is induced by tetrabutylammonium fluoride in nonpolar,
Jürgen, Wiedemann, Thomas, Heiner, Gregorz, Mloston, G K Surya, Prakash, George A, Olah   +4 more
openaire   +2 more sources