Synergizing Electrons and Photons in Motion: Continuous-Flow Implementation in Electro- and Photocatalyzed C-H Functionalization. [PDF]
Peters SE, von Münchow T, Ackermann L.
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The Role of Electron Transfer in Copper-Mediated C(sp2)-H Trifluoromethylation. [PDF]
Ball MAP +6 more
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A facile synthesis of CF3-containing iminoisobenzofurans via copper-catalyzed oxygen trifluoromethylation-cyclization of o-vinyl-N-alkylamide. [PDF]
Gao S +6 more
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The organophotocatalytic trifluoromethylation of 6-azauracils. [PDF]
Das KK, Hajra A.
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[4 + 2] Cycloaddition of α-bromotrifluoromethylhydrazone with alkenes: synthesis of trifluoromethyltetrahydropyridazines. [PDF]
Zhao Y +5 more
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Photoelectrochemical High-Value-Added Chemical Production with Improved Selectivity. [PDF]
Li Y, Chen T, Chen Y.
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HCl-mediated silylation of C-H bonds in (hetero)arenes with trialkylsilanes. [PDF]
Su Y +6 more
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A “Renaissance” in Radical Trifluoromethylation
Angewandte Chemie - International Edition, 2012AbstractThis Minireview highlights recent developments in radical trifluoromethylation reactions. The trifluoromethyl group belongs to the privileged moieties in medicinal chemistry. Many drugs and drug candidates contain a trifluoromethyl substituent. Also in agrochemicals, the CF3 moiety often appears.
Armido Studer
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Radical trifluoromethylation has been emerging as a versatile tool for the synthesis of trifluoromethylated compounds that play increasingly important roles in pharmaceuticals, agrochemicals and materials science.
Haiwen Xiao +4 more
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AbstractFirst evidence for the existence of free trifluoromethyl anion CF3− has been obtained. The 3D‐caged potassium cation in [K(crypt‐222)]+ is inaccessible to CF3−, thus rendering it uncoordinated (“naked”). Ionic [K(crypt‐222)]+ CF3− has been characterized by single‐crystal X‐ray diffraction, solution NMR spectroscopy, DFT calculations, and ...
Anton, Lishchynskyi +6 more
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