Results 111 to 120 of about 1,330 (177)

The Role of Electron Transfer in Copper-Mediated C(sp2)-H Trifluoromethylation. [PDF]

open access: yesAngew Chem Int Ed Engl
Ball MAP   +6 more
europepmc   +1 more source

HCl-mediated silylation of C-H bonds in (hetero)arenes with trialkylsilanes. [PDF]

open access: yesChem Sci
Su Y   +6 more
europepmc   +1 more source

A “Renaissance” in Radical Trifluoromethylation

Angewandte Chemie - International Edition, 2012
AbstractThis Minireview highlights recent developments in radical trifluoromethylation reactions. The trifluoromethyl group belongs to the privileged moieties in medicinal chemistry. Many drugs and drug candidates contain a trifluoromethyl substituent. Also in agrochemicals, the CF3 moiety often appears.
Armido Studer
exaly   +3 more sources

Radical trifluoromethylation

Chemical Society Reviews, 2021
Radical trifluoromethylation has been emerging as a versatile tool for the synthesis of trifluoromethylated compounds that play increasingly important roles in pharmaceuticals, agrochemicals and materials science.
Haiwen Xiao   +4 more
openaire   +2 more sources

The Trifluoromethyl Anion

Angewandte Chemie, 2015
AbstractFirst evidence for the existence of free trifluoromethyl anion CF3− has been obtained. The 3D‐caged potassium cation in [K(crypt‐222)]+ is inaccessible to CF3−, thus rendering it uncoordinated (“naked”). Ionic [K(crypt‐222)]+ CF3− has been characterized by single‐crystal X‐ray diffraction, solution NMR spectroscopy, DFT calculations, and ...
Anton, Lishchynskyi   +6 more
openaire   +2 more sources

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