Results 121 to 130 of about 112,449 (386)
1,2-Bis(trimethylsilyl)benzene is the key starting material for the synthesis of efficient benzyne precursors and certain luminescent π-conjugated materials.
Andreas Lorbach+4 more
semanticscholar +1 more source
The Chemistry and Biology of the Tetrodotoxin Natural Product Family
Tetrodotoxin is best known as the poison of the pufferfish, which is a delicacy in Japanese cuisine. Its toxicity arises from the selective blockage of NaV channels, which is depicted for the NaV1.7 pore, highlighting the DEKA motif, which permeates sodium ions.
Benedikt Nißl+6 more
wiley +1 more source
Notizen: Infrarotspektren von Trimethylsilyl- und Trimethylgermanyl-trimethylstannan [PDF]
Herbert Schumann, Siegfried Ronecker
openalex +1 more source
Total Synthesis and Structural Revision of (−)‐Sodagnitin E
Malabaricane triterpenoid sodagnitin E is a chromogen found in various toadstools. This work represents the first total synthesis of (−)‐sodagnitin E as well as the first total synthesis of any malabaricane natural product. A Mukaiyama aldol reaction was utilized to perform a convergent synthesis from two enantioselectively synthesized fragments ...
Philipp Schoch, Tanja Gaich
wiley +1 more source
Pseudouridine‐5′‐triphosphate (ΨTP) and its N1‐methylated derivative (m1ΨTP) are crucial components in mRNA vaccine technology. Here, an atom‐economic, high‐yielding biocatalytic route for ΨTP synthesis is presented. A new chemoenzymatic route for m1ΨTP synthesis was developed.
Martin Pfeiffer+4 more
wiley +1 more source
Design of Fluorine‐Free Weakly Coordinating Electrolyte Solvents with Enhanced Oxidative Stability
Incorporation of silicon is systematically explored as a sustainable strategy to design weakly solvating electrolytes for lithium‐based batteries. After identifying a promising molecular structure via computational screening, coordination spheres and their correlation with electrochemical key performance indicators are compared between electrolyte ...
Lennart Wichmann+9 more
wiley +1 more source
Compound oxidized styrylphosphine [PDF]
A process is described for preparing flame resistant, nontoxic vinyl polymers which contain phosphazene groups and which do not emit any toxic or corrosive products when they are oxidatively degraded.
Paciorek, K. J. L.
core +1 more source
Characterization of Bacteria by Gas Chromatography: Comparison of Trimethylsilyl Derivatives of Whole-Cell Hydrolysates [PDF]
Davood Farshtchi, C W Moss
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Stereochemically defined inositol pyrophosphate isomers (PP‐InsP4) were synthesized and assigned by NMR spectroscopy using a chiral solvating agent. In the form of isotopically labeled standards, they were applied in CE‐MS‐based profiling of plant extracts and kinase assays, enabling structural reassignment and functional insight into enzymatic ...
Kevin Ritter+6 more
wiley +1 more source