Results 121 to 130 of about 61,381 (342)

Identification of 3 beta, 7 beta-dihydroxy-5 beta-cholan-24-oic acid in serum from patients treated with ursodeoxycholic acid.

open access: yesJournal of Lipid Research, 1984
An unknown bile acid was found by gas-liquid chromatography in the serum of patients who were administered ursodeoxycholic acid for the treatment of cholesterol gallstones.
M Maeda   +5 more
doaj  

Catalytic Silylation of Alkynyl C(sp)–H bonds with tert‐Butyl‐Substituted Silyldiazenes

open access: yesChemCatChem, Accepted Article.
The deprotonative silylation of terminal alkynes constitutes one of the most privileged strategies to prepare alkynylsilanes owing to the relatively high acidity of C(sp)–H bonds. While the key deprotonation step is usually mediated by stoichiometric amounts of strong Brønsted bases (e.g.
Yan Zeng   +2 more
wiley   +1 more source

Ferrocene derivatives with planar chirality and their enantioseparation by liquid‐phase techniques

open access: yesELECTROPHORESIS, Volume 44, Issue 1-2, Page 158-189, January 2023., 2023
Abstract In the last decade, planar chiral ferrocenes have attracted a growing interest in several fields, particularly in asymmetric catalysis, medicinal chemistry, chiroptical spectroscopy and electrochemistry. In this frame, the access to pure or enriched enantiomers of planar chiral ferrocenes has become essential, relying on the availability of ...
Paola Peluso, Victor Mamane
wiley   +1 more source

Dual Nickel/Titanium Catalyzed Cross‐Electrophile Coupling of Thioesters with Benzylic Alcohols

open access: yesChemCatChem, Accepted Article.
This work focuses on the development of a new method for ketone synthesis via cross electrophile coupling (XEC) starting from widely available and low‐cost reagents. We demonstrate the XEC of benzylic alcohols and thioesters under reductive conditions and in the presence of trimethylsilyl chloride (TMSCl) using a dual catalytic system consisting of an ...
Anne Haupt, Ivana Fleischer
wiley   +1 more source

Gas-liquid chromatography-mass spectrometry of synthetic ceramides

open access: yesJournal of Lipid Research, 1969
Two series of ceramides with either sphingosine (sphing-4-enine) or sphinganine as base and with one of the saturated fatty acids C16, C18, C20, C22, C24, C26, or oleic acid were analyzed as the 1,3-di-O-trimethylsilyl ether derivatives by gas ...
Bengt Samuelsson, Karin Samuelsson
doaj  

Palladium‐Catalyzed Allylation of (Hetero)Aryl Fluorosulfates

open access: yesChemCatChem, Accepted Article.
Reported herein is the palladium‐catalyzed allylation of (hetero)aryl fluorosulfates. When employing a [Pd(cinnamyl)Cl]2/XantPhos catalyst system and using either allyl pinacolboronate or potassium allyltrifluoroborate, allyl (hetero)arene products were successfully prepared and isolated in synthetically useful yields, including examples featuring ...
Kathleen Morrison   +9 more
wiley   +1 more source

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