The cyclopropylcarbinyl route to γ-silyl carbocations
The mesylate derivative of cis-1-hydroxymethyl-2-trimethylsilylcyclopropane has been prepared, along with a number of related mesylates and triflates with substituents on the 1-position.
Xavier Creary
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Notizen: Bis-(trimethylsilyl-methansulfonsäure)-imid [PDF]
Armand Blaschette
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A Novel Method for Synthesis of Substituted Naphthofurans and Naphthopyrans [PDF]
Substituted naphthofurans and naphthopyrans were constructed at high temperature from allyl or propargyl naphthyl ethers via Claisen rearrangement in moderate to good yields.
Mohammad Reza Saidi+3 more
doaj
ORGANOGERMANIUM COMPOUNDS: PART II. INFRARED SPECTRA OF SOME ACOXYGERMANES AND THE RELATIVE INDUCTIVE EFFECTS OF TRIMETHYLSILYL AND TRIMETHYLGERMYL GROUPS [PDF]
T. N. Srivastava, M. Onyszchuk
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Isolation and characterization of glucosylsphingosine from Gaucher's spleen
Glucosylsphingosine has been isolated for the first time as a natural constituent from Gaucher's spleen. On thinlayer chromatography, it migrates with authentic glucosylsphingosine, yielding a positive color reaction with ninhydrin for the amino group ...
Srinivasa S. Raghavan+2 more
doaj
Stepwise [2 + 2] and [3 + 2] "cycloaddition" reactions of allenyl cations with olefins [PDF]
Halberstadt-Kausch, Inge K.+2 more
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THE ALCOHOLYSIS OF TRIALKYLALKOXYSILANES: PART II. THE PREPARATION AND CHEMISTRY OF METHYL 2,3,4-TRI-O-TRIMETHYLSILYL-α-
D. T. Hurst, A. G. McInnes
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Summary: As a privileged motif, tetrazoles can be widely found in pharmaceuticals and materials science. Herein, a five-component reaction of cycloketone oxime esters, alkynes, DABCO·(SO2)2, and two molecules of trimethylsilyl azide under iron catalysis ...
Jun Zhang+3 more
doaj
Heat resistant polymers of oxidized styrylphosphine [PDF]
Homopolymers, copolymers and terpolymers of a styrene based monomer are prepared by polymerizing at least one oxidized styrylphosphine monomer or by polymerizing p-diphenylphosphinestyrene and then oxidizing the polymerized monomer with an organoazide ...
Paciorek, K. J. L.
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Study of localization in the quantum sawtooth map emulated on a quantum information processor
Quantum computers will be unique tools for understanding complex quantum systems. We report an experimental implementation of a sensitive, quantum coherence-dependent localization phenomenon on a quantum information processor (QIP).
David G. Cory+7 more
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