Development of a Diastereoselective Csp<sup>2</sup>-Csp<sup>3</sup> Cross-Coupling Reaction Inspired by Macrocyclic RiPP Natural Products. [PDF]
Plouch EV+5 more
europepmc +1 more source
Synthesis of Amides and Amidines by Reaction of Carboxylic Acids and Amines in the Presence of Polyphophoric Acid Trimethylsilyl Ester (PPSE) [PDF]
Shinichi Ogata+3 more
openalex +1 more source
GA: We here report the first perarylated 2,3‐diboratabutadiene dianion and its reaction with Cp2MCl2 (M = Zr, Hf) to afford unprecedented 2,3‐diboratabutadiene π‐complexes with unique coordination modes. Addition of an N‐heterocyclic carbene (NHC) to the complexes gives rise to the donor‐induced oxidation of the BB bond, resulting in two separate NHC ...
Philipp Grewelinger+3 more
wiley +1 more source
SAR-Guided Development of Small-Molecule SERCA2a Activators: Discovery of Potent Indoline, Benzofuran, and Benzodioxole Analogs for Cardiovascular Applications. [PDF]
Ard A+6 more
europepmc +1 more source
Ring the boron, not the bell: cyclotrimerization of borylated diynes with nitriles using Co and Ru catalysts allows the efficient synthesis of a wide variety of borylated pyridines with high regioselectivity, paving the way for multiple post‐functionalizations.
Eva Bednářová+7 more
wiley +1 more source
A Remarkable Catalyst-Free Photochemical Alkene Hydrophosphination with Bis(trimethylsilyl)phosphonite. [PDF]
Bréger E+5 more
europepmc +1 more source
The 1,3-Dipolar Cycloaddition Reactions of Heteroaromatic Dicyanomethylides with Phenylsulfinylethene and Bis(trimethylsilyl)ethyne: Synthesis of 1,2-Unsubstituted 3-Cyanoindolizines [PDF]
Kiyoshi Matsumoto+6 more
openalex +1 more source
Investigating di‐n‐Butylcalcium
A detailed synthetic, crystallographic, and spectroscopic investigation demonstrates that the hitherto elusive di‐n‐butylcalcium is accessible and stable at low temperature, and can be used for deprotometallation reactions. The synthesis and detailed characterization by NMR spectroscopy of di‐n‐butylcalcium are reported. The reaction of [Ca{N(SiMe3)2}2.
Gabriel Duneş+9 more
wiley +1 more source
Hydrophobic Silica Gels and Aerogels for Direct Air Capture: Hybrid Grafting To Suppress Water Uptake and Capillary Condensation. [PDF]
Ziemiański PP+7 more
europepmc +1 more source