Results 181 to 190 of about 112,449 (386)

2,3‐Diboratabutadiene Complexes of Group 4 Metals and their Donor‐Induced Oxidative Cleavage to Methyleneboranes

open access: yesChemistryEurope, EarlyView.
GA: We here report the first perarylated 2,3‐diboratabutadiene dianion and its reaction with Cp2MCl2 (M = Zr, Hf) to afford unprecedented 2,3‐diboratabutadiene π‐complexes with unique coordination modes. Addition of an N‐heterocyclic carbene (NHC) to the complexes gives rise to the donor‐induced oxidation of the BB bond, resulting in two separate NHC ...
Philipp Grewelinger   +3 more
wiley   +1 more source

Boronate‐Type‐Controlled Regioselective Catalytic [2 + 2 + 2] Cyclotrimerization for Synthesis of Polysubstituted 2‐ and 3‐Borylated Pyridines

open access: yesChemistryEurope, EarlyView.
Ring the boron, not the bell: cyclotrimerization of borylated diynes with nitriles using Co and Ru catalysts allows the efficient synthesis of a wide variety of borylated pyridines with high regioselectivity, paving the way for multiple post‐functionalizations.
Eva Bednářová   +7 more
wiley   +1 more source

A Remarkable Catalyst-Free Photochemical Alkene Hydrophosphination with Bis(trimethylsilyl)phosphonite. [PDF]

open access: yesJACS Au
Bréger E   +5 more
europepmc   +1 more source

Investigating di‐n‐Butylcalcium

open access: yesChemistryEurope, EarlyView.
A detailed synthetic, crystallographic, and spectroscopic investigation demonstrates that the hitherto elusive di‐n‐butylcalcium is accessible and stable at low temperature, and can be used for deprotometallation reactions. The synthesis and detailed characterization by NMR spectroscopy of di‐n‐butylcalcium are reported. The reaction of [Ca{N(SiMe3)2}2.
Gabriel Duneş   +9 more
wiley   +1 more source

Hydrophobic Silica Gels and Aerogels for Direct Air Capture: Hybrid Grafting To Suppress Water Uptake and Capillary Condensation. [PDF]

open access: yesACS Appl Mater Interfaces
Ziemiański PP   +7 more
europepmc   +1 more source

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