Results 11 to 20 of about 41,598 (291)

Tetrakis(trimethylsilyl)distiban / Tetrakis (trimethylsilyl) distibane

open access: yesZeitschrift für Naturforschung B, 1979
Abstract Tetrakis(trimethylsilyl)distibane, (Me3Si)4Sb2 is produced by reaction of tris(trimethylsilyl) stibine, (Me3Si)3Sb, with three or less than three equivalents of t-butyl iodide, with trimethyliodosilane, Me3SiI and iodine. The reaction of (Me3Si)3Sb with three or more equivalents of i-butyl iodide and methyl iodide also yields ...
Hans Joachim Breunig   +1 more
openaire   +1 more source

N-[1-Phenyl-2,5-bis(trimethylsilyl)pent-2-en-4-yn-1-yl]aniline

open access: yesIUCrData, 2016
The molecular structure of the title compound, C23H31NSi2, reveals an acyclic conjugated enyne unit as the main feature. The central pent-2-en-4-yl fragment is essentially planar, with a maximum deviation of 0.0492 (7) Å from the mean plane defined by ...
Vladimir V. Burlakov   +5 more
doaj   +1 more source

Bulky 2,6-disubstituted aryl siloxanes and a disilanamine

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
The crystal structures of 5-bromo-1,3-di-tert-butyl-2-[(trimethylsilyl)oxy]benzene, C17H29BrOSi, (I), 1,3-di-tert-butyl-2-[(trimethylsilyl)oxy]benzene, C17H30OSi, (II), and N-(2,6-diisopropylphenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine ...
Flavia Marszaukowski   +2 more
doaj   +1 more source

Copolymers of 4-Trimethylsilyl Diphenyl Acetylene and 1-Trimethylsilyl-1-Propyne: Polymer Synthesis and Luminescent Property Adjustment

open access: yesMolecules, 2022
Poly(4-trimethylsilyl diphenyl acetylene) (PTMSDPA) has strong fluorescence emission, but its application is limited by the effect of aggregation-caused quenching (ACQ).
Tanxiao Shen   +4 more
doaj   +1 more source

Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents

open access: yesMolecules, 2022
Derivatives of main group elements containing element–element bonds are characterized by unique properties due to σ-conjugation, which is an attractive subject for investigation.
Kirill V. Zaitsev   +2 more
doaj   +1 more source

N-heterocyclic carbene catalyzed additions of 3-trimethylsilyl propiolate to aldehydes

open access: yesJournal of Saudi Chemical Society, 2016
A N-heterocyclic carbene (NHC) catalyzed addition reaction of 3-trimethylsilyl propiolate with aldehydes has been developed. Under the catalysis of 2 mol% NHCs, benzaldehyde, furfural, β-naphthaldehyde, meta- and para-substituted aromatic aldehydes ...
Guang-Fen Du   +3 more
doaj   +1 more source

PECULIARITIES OF ISOCYANATES INTERACTION WITH HYDRAZINE DERIVATIVES

open access: yesТонкие химические технологии, 2018
The results of studies on chemical transformations of organic and organosilicon isocyanates in their interaction with hydrazine derivatives have been summarized in this review.
A. D. Kirilin   +4 more
doaj   +1 more source

Flow Electrosynthesis and Molecular Weight Control of Polyphenylene Deriving from 1,4-Bis(trimethylsilyl)benzene: Effect of a Silyl Substituent on the Coupling Position

open access: yesElectrochemistry, 2020
In this study, we have demonstrated electrochemical synthesis of polyphenylene (PP) deriving from 1,4-bis(trimethylsilyl)benzene using a flow microreactor.
Yuto NAKAMURA   +3 more
doaj   +1 more source

Separation of mono- and diglycerides by gas-liquid chromatography

open access: yesJournal of Lipid Research, 1969
The parameters affecting the separation and quantification of trimethylsilyl ethers of mono- and diglycerides have been investigated by gas-liquid chromatography with QF-1 and SE-30 as stationary phases and a flame ionization detector.
Rodney Watts, R. Dils
doaj   +1 more source

N,N,N′-Tris(trimethylsilyl)-2-pyridinecarboximidamide

open access: yesMolbank
N,N,N′-tris(trimethylsilyl)-carboximidamides are effective reagents in synthetic chemistry in reactions with both non-metal and metal halides, because the side product is the mild and volatile ClSi(CH3)3 rather than corrosive HCl.
Mukaila A. Ibrahim   +2 more
doaj   +1 more source

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