Results 11 to 20 of about 112,449 (386)

N-[1-Phenyl-2,5-bis(trimethylsilyl)pent-2-en-4-yn-1-yl]aniline

open access: yesIUCrData, 2016
The molecular structure of the title compound, C23H31NSi2, reveals an acyclic conjugated enyne unit as the main feature. The central pent-2-en-4-yl fragment is essentially planar, with a maximum deviation of 0.0492 (7) Å from the mean plane defined by ...
Vladimir V. Burlakov   +5 more
doaj   +1 more source

Gas phase enthalpies of formation, isomerization, and disproportionation of mono- through tetra-substituted tetrahedranes: A G4MP2/G4 theoretical study [PDF]

open access: yes, 2011
Gas phase (298.15 K, 1 atm) enthalpies of formation (Δ~f~H°~(g)~), enthalpies of disproportionation to two corresponding acetylene molecules (Δ~rxn~H°~(g),Td→acet~), and enthalpies of isomerization from a tetrahedrane ...
Kaya Forest, Sierra Rayne
core   +2 more sources

Differentiation Between Ripening Stages of Iberian Dry-Cured Ham According to the Free Amino Acids Content [PDF]

open access: yes, 2020
In this paper, the differentiation of three ripening stages, postsalting, drying, and cellar, of Iberian dry-cured ham has been carried out according to their free amino acids contents. Eighteen L-amino acids, alanine, 2-aminobutanoic acid, aspartic acid,
Alcázar Rueda, Ángela   +3 more
core   +1 more source

Crystal structure of 1-(2,4-dimethylphenyl)-2-(4-trimethylsilyl-1H-1,2,3-triazol-1-yl)ethanone

open access: yesActa Crystallographica Section E, 2014
The asymmetric unit of the title compound, C15H21N3OSi, contains two molecules with similar conformations (r.m.s. overlay fit for the 20 non-H atoms = 0.163 Å).
G. B. Venkatesh   +4 more
doaj   +1 more source

Trimethylsilyl-Protected Alkynes as Selective Cross-Coupling Partners in Titanium-Catalyzed [2+2+1] Pyrrole Synthesis.

open access: yesAngewandte Chemie, 2018
Trimethylsilyl (TMS)-protected alkynes served as selective alkyne cross-coupling partners in titanium-catalyzed [2+2+1] pyrrole synthesis. Reactions of TMS-protected alkynes with internal alkynes and azobenzene under the catalysis of titanium imido ...
Hsin-Chun Chiu, Ian A. Tonks
semanticscholar   +1 more source

Fast method for the determination of short-chain-length polyhydroxyalkanoates (scl-PHAs) in bacterial samples by In Vial-Thermolysis (IVT) [PDF]

open access: yes, 2017
none8siA new method based on the GC–MS analysis of thermolysis products obtained by treating bacterial samples at a high temperature (above 270 C) has been developed.
Abbondanzi, F.   +7 more
core   +1 more source

Formal Carbene C-H Bond Insertion in the Cu(I)-Catalyzed Reaction of Bis(trimethylsilyl)diazomethane with Benzoxazoles and Oxazoles.

open access: yesOrganic Letters, 2019
A Cu(I)-catalyzed cross-coupling reaction of bis(trimethylsilyl)diazomethane and benzoxazoles/oxazoles is reported. A wide range of functional groups can be tolerated in this transformation. This reaction provides a new method to directly introduce a 1,1-
Shuai Wang   +4 more
semanticscholar   +1 more source

Characterization and Quantification of Isoprene-Derived Epoxydiols in Ambient Aerosol in the Southeastern United States [PDF]

open access: yes, 2010
Isoprene-derived epoxydiols (IEPOX) are identified in ambient aerosol samples for the first time, together with other previously identified isoprene tracers (i.e., 2-methyltetrols, 2-methylglyceric acid, C5-alkenetriols, and organosulfate derivatives of ...
Chan, Man Nin   +10 more
core   +2 more sources

Copolymers of 4-Trimethylsilyl Diphenyl Acetylene and 1-Trimethylsilyl-1-Propyne: Polymer Synthesis and Luminescent Property Adjustment

open access: yesMolecules, 2022
Poly(4-trimethylsilyl diphenyl acetylene) (PTMSDPA) has strong fluorescence emission, but its application is limited by the effect of aggregation-caused quenching (ACQ).
Tanxiao Shen   +4 more
doaj   +1 more source

Synthesis of Ultrathin Copper Nanowires Using Tris(trimethylsilyl)silane for High-Performance and Low-Haze Transparent Conductors.

open access: yesNano letters (Print), 2015
Colloidal metal nanowire based transparent conductors are excellent candidates to replace indium-tin-oxide (ITO) owing to their outstanding balance between transparency and conductivity, flexibility, and solution-processability.
Fan Cui   +7 more
semanticscholar   +1 more source

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