Results 11 to 20 of about 41,598 (291)
Tetrakis(trimethylsilyl)distiban / Tetrakis (trimethylsilyl) distibane
Abstract Tetrakis(trimethylsilyl)distibane, (Me3Si)4Sb2 is produced by reaction of tris(trimethylsilyl) stibine, (Me3Si)3Sb, with three or less than three equivalents of t-butyl iodide, with trimethyliodosilane, Me3SiI and iodine. The reaction of (Me3Si)3Sb with three or more equivalents of i-butyl iodide and methyl iodide also yields ...
Hans Joachim Breunig +1 more
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N-[1-Phenyl-2,5-bis(trimethylsilyl)pent-2-en-4-yn-1-yl]aniline
The molecular structure of the title compound, C23H31NSi2, reveals an acyclic conjugated enyne unit as the main feature. The central pent-2-en-4-yl fragment is essentially planar, with a maximum deviation of 0.0492 (7) Å from the mean plane defined by ...
Vladimir V. Burlakov +5 more
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Bulky 2,6-disubstituted aryl siloxanes and a disilanamine
The crystal structures of 5-bromo-1,3-di-tert-butyl-2-[(trimethylsilyl)oxy]benzene, C17H29BrOSi, (I), 1,3-di-tert-butyl-2-[(trimethylsilyl)oxy]benzene, C17H30OSi, (II), and N-(2,6-diisopropylphenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine ...
Flavia Marszaukowski +2 more
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Poly(4-trimethylsilyl diphenyl acetylene) (PTMSDPA) has strong fluorescence emission, but its application is limited by the effect of aggregation-caused quenching (ACQ).
Tanxiao Shen +4 more
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Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents
Derivatives of main group elements containing element–element bonds are characterized by unique properties due to σ-conjugation, which is an attractive subject for investigation.
Kirill V. Zaitsev +2 more
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N-heterocyclic carbene catalyzed additions of 3-trimethylsilyl propiolate to aldehydes
A N-heterocyclic carbene (NHC) catalyzed addition reaction of 3-trimethylsilyl propiolate with aldehydes has been developed. Under the catalysis of 2 mol% NHCs, benzaldehyde, furfural, β-naphthaldehyde, meta- and para-substituted aromatic aldehydes ...
Guang-Fen Du +3 more
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PECULIARITIES OF ISOCYANATES INTERACTION WITH HYDRAZINE DERIVATIVES
The results of studies on chemical transformations of organic and organosilicon isocyanates in their interaction with hydrazine derivatives have been summarized in this review.
A. D. Kirilin +4 more
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In this study, we have demonstrated electrochemical synthesis of polyphenylene (PP) deriving from 1,4-bis(trimethylsilyl)benzene using a flow microreactor.
Yuto NAKAMURA +3 more
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Separation of mono- and diglycerides by gas-liquid chromatography
The parameters affecting the separation and quantification of trimethylsilyl ethers of mono- and diglycerides have been investigated by gas-liquid chromatography with QF-1 and SE-30 as stationary phases and a flame ionization detector.
Rodney Watts, R. Dils
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N,N,N′-Tris(trimethylsilyl)-2-pyridinecarboximidamide
N,N,N′-tris(trimethylsilyl)-carboximidamides are effective reagents in synthetic chemistry in reactions with both non-metal and metal halides, because the side product is the mild and volatile ClSi(CH3)3 rather than corrosive HCl.
Mukaila A. Ibrahim +2 more
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