Darstellung von Trimethylsilyl‐substituierten Tricarbonyl(cyclohexadien)eisen‐Komplexen [PDF]
Michael Keil, Franz Effenberger
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Novel class of saturated NHPs with phosphoramidothioate substituents exhibit enhanced reactivity in photoinitiated transfer hydrogenation reactions and activate C─O, B─H, B─C, and B─F bonds via phosphenium cation formation. Abstract N‐heterocyclic phosphines (NHPs), and especially their ionic derivatives, phosphenium cations, have gained significant ...
Maksim A. Samsonov+6 more
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Silyl Derivatives in the Synthesis of trans-beta-Trimethylsilyl-alpha,beta-unsaturated Ketones. [PDF]
M. L. CHRISTIANSEN+4 more
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The reported aza‐dibenzodiprromethenes present a rare helical architecture, placing terminal aryl groups in a close, π‐stacked arrangement. Differentially terminated derivatives are prepared by statistical condensation or controlled synthesis via conversion of one partner to its tosylate or triflate.
Budur N. Alanazi+11 more
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Synthesis of Amino-<i>gem</i>-Bisphosphonate Derivatives and Their Application as Synthons for the Preparation of Biorelevant Compounds. [PDF]
Ordoñez M, Argüello Velasco RO.
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REACTIONS OF ALLYLSILANES WITH α-CHLORO ETHERS CATALYZED BY IODOTRIMETHYLSILANE OR TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE. SYNTHESIS OF HOMOALLYL ETHERS [PDF]
Hideki Sakurai+2 more
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The design of fluorescent molecules inspired by natural cofactors to monitor biological processes carries some intrinsic advantages. This is particularly relevant in the case of redox cofactors with innate fluorescence properties, such as flavins, and synthetic strategies toward their functionalized analogues are of high interest to modulate properties.
Oscar Charpentier+5 more
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(Trimethylsilyl)methyl Ketones in the Synthesis of Bromomethyl and Chloromethyl Ketones. [PDF]
Tore Benneche+4 more
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The first experimental identification of the IG head structure of naturally occurring plant GIPCs in Brassicaceae was achieved through the chemical synthesis of three hexose‐type IGs containing d‐glucose, d‐galactose, or d‐mannose as the second monosaccharide linked to d‐glucuronic acid‐α(1→2)‐myo‐inositol.
Yuta Umemura+11 more
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Antibacterial potential and chromatographic profiling of bioactive compounds from endophytic <i>Streptomyces</i> sp. strain MIRK71 isolated from <i>Mirabilis jalapa</i> (L.). [PDF]
Lalrokimi+10 more
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