Reactivity of an ortho‐Phenylene‐bridged Al/P Frustrated Lewis Pair Towards Small Molecules
Frustrated Lewis Pairs (FLPs) as ambiphilic molecules are prone to activate small molecules and are in the focus of interest for many years. In this paper, we present the first ortho‐phenylene bridged Al/P‐based FLP with only one phosphine moiety. The title compound was employed in various reactions with small molecules featuring different functional ...
Melina E. A. Dilanas, Frank Breher
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The Chemistry of Selenosilanes: A Topic Overview. [PDF]
Tanini D, Capperucci A.
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Late-Stage Photoredox-Catalyzed Aryl C-H Bond Diazomethylation with Atomic Carbon Reagents. [PDF]
Puggioli A+8 more
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Recent Advances in the α‐Hydrazination (α‐Amination) of Carbonyl Compounds
In recent years, notable progress has been achieved in the α‐hydrazination (α‐amination) of carbonyl compounds, especially in the direct asymmetric electrophilic α‐hydrazination with dialkyl azodicarboxylates. This review summarizes all the methods that appeared over the past decade, categorized based on the type of the reactive chiral intermediate ...
Dina Scarpi+2 more
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Molecular docking analysis of Salvia sclarea flower extracts evaluated for protein target affinity based on different extraction methods. [PDF]
Torunoglu EI, Aytar EC, Durmaz A.
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The chemistry of (R)- and (S)-5-trimethylsilyl-2-cyclohexenones.
Morio Asaoka, Hisashi Takei
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Total Synthesis of Ectocarpin A
A total enantioselective synthesis of Ectocarpin A, an oxylipin identified through the first hydroperoxide bicyclase activity of CYP5164A3 in brown algae, has been successfully completed in 12 steps starting from tetrahydro‐1H‐cyclopentafuranone.
Alexandre Guy+2 more
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Evaluation and identification of metabolites produced by Cytobacillus firmus in the interaction with Arabidopsis thaliana plants and their effect on Solanum lycopersicum. [PDF]
Arteaga-Ríos IG+5 more
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Enantioselective Anion‐Binding‐Catalyzed Nucleophilic Addition to 4‐Quinolones
Chiral quinolones and their derivatives are predominant synthetic building blocks and pharmacological agents. Nevertheless, their synthesis mostly relies on transition‐metal‐catalyzed enantioselective 1,4‐additions of organometallic reagents such as Grignard, organozinc or organoboron species for alkylation, arylation and alkynylation reactions. Herein,
Martin Aleksiev+2 more
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Data-driven design of electrolyte additives supporting high-performance 5 V LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4</sub> positive electrodes. [PDF]
Wang B+7 more
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