Results 211 to 220 of about 61,381 (342)

Reactivity of an ortho‐Phenylene‐bridged Al/P Frustrated Lewis Pair Towards Small Molecules

open access: yesEuropean Journal of Inorganic Chemistry, Accepted Article.
Frustrated Lewis Pairs (FLPs) as ambiphilic molecules are prone to activate small molecules and are in the focus of interest for many years. In this paper, we present the first ortho‐phenylene bridged Al/P‐based FLP with only one phosphine moiety. The title compound was employed in various reactions with small molecules featuring different functional ...
Melina E. A. Dilanas, Frank Breher
wiley   +1 more source

Late-Stage Photoredox-Catalyzed Aryl C-H Bond Diazomethylation with Atomic Carbon Reagents. [PDF]

open access: yesJ Am Chem Soc
Puggioli A   +8 more
europepmc   +1 more source

Recent Advances in the α‐Hydrazination (α‐Amination) of Carbonyl Compounds

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
In recent years, notable progress has been achieved in the α‐hydrazination (α‐amination) of carbonyl compounds, especially in the direct asymmetric electrophilic α‐hydrazination with dialkyl azodicarboxylates. This review summarizes all the methods that appeared over the past decade, categorized based on the type of the reactive chiral intermediate ...
Dina Scarpi   +2 more
wiley   +1 more source

Total Synthesis of Ectocarpin A

open access: yesEuropean Journal of Organic Chemistry, Accepted Article.
A total enantioselective synthesis of Ectocarpin A, an oxylipin identified through the first hydroperoxide bicyclase activity of CYP5164A3 in brown algae, has been successfully completed in 12 steps starting from tetrahydro‐1H‐cyclopentafuranone.
Alexandre Guy   +2 more
wiley   +1 more source

Evaluation and identification of metabolites produced by Cytobacillus firmus in the interaction with Arabidopsis thaliana plants and their effect on Solanum lycopersicum. [PDF]

open access: yesCurr Res Microb Sci
Arteaga-Ríos IG   +5 more
europepmc   +1 more source

Enantioselective Anion‐Binding‐Catalyzed Nucleophilic Addition to 4‐Quinolones

open access: yesEuropean Journal of Organic Chemistry, Accepted Article.
Chiral quinolones and their derivatives are predominant synthetic building blocks and pharmacological agents. Nevertheless, their synthesis mostly relies on transition‐metal‐catalyzed enantioselective 1,4‐additions of organometallic reagents such as Grignard, organozinc or organoboron species for alkylation, arylation and alkynylation reactions. Herein,
Martin Aleksiev   +2 more
wiley   +1 more source

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