Zum Mechanismus der Carbodesilylierung 4‐ bzw. 5‐substituierter 2‐(Trimethylsilyl)pyridine mit Benzaldehyd [PDF]
, 1992 Franz Effenberger +2 more
openalex +1 more source
A Base‐Mediated Rearrangement of the Benzylic 1,5‐Hexadipyridynyl Moiety
ChemPlusChem, EarlyView.A rearrangement unheard of! When exposed to base, benzylic 1,5‐hexadipyridynyl moieties skip a beat—disregarding Cope‐like rearrangement and instead readily rearrange through a deprotonation–reprotonation–electrocyclization cascade. The result is a highly rigid vinyl‐pyridine cyclobutene, fashioned via a novel pathway.A previously unrecognized base ...
Wouter A. Remmerswaal +8 more
wiley +1 more source
The Puzzle of the Regioselectivity and Molecular Mechanism of the (3+2) Cycloaddition Reaction Between E-2-(Trimethylsilyl)-1-Nitroethene and Arylonitrile N-Oxides: Molecular Electron Density Theory (MEDT) Quantumchemical Study. [PDF]
MoleculesSadowski M, Dresler E, Jasiński R.
europepmc +1 more source
Anthraquinone Sulfonates as Water‐Soluble Photocatalysts: Synthetic Applications and Perspectives
ChemPhotoChem, EarlyView.The development of photochemistry in water is rapidly advancing, and the demand for water‐soluble photocatalysts is increasing. Accordingly, anthraquinone sulfonates are interesting options for the activation of organic molecules through H‐atom transfer, proton‐coupled electron transfer, or the generation of reactive oxygen species.
Daniel Kolb +2 more
wiley +1 more source
Synthesis of Heteroleptic Amidinato Calcium Halides via the In-Situ Grignard Addition Method (iGAM) Complementing the Metalation of Amidines. [PDF]
ChemistrySengupta S +3 more
europepmc +1 more source
Tetrakis[(trimethylsilyl)ethynyl] Group 14 metal derivatives: an examination of the electronic interaction between two Group 14 metals connected by an acetylene wire [PDF]
, 1993 Carol Dallaire +4 more
openalex +1 more source
ChemSusChem, EarlyView.EDA complexes can be profitably exploited to enhance the overall sustainability of the chemical transformations, as demonstrated by a careful evaluation of the mass‐based metrics. A novel and sustainable method is presented for the enantioselective β‐alkylation of enals using an electron donor–acceptor (EDA) complex‐based strategy.
Simone Di Remigio +7 more
wiley +1 more source
Titanium-Mediated Rearrangement of Bis(alkynyl)boranes: B─C Activation versus C─H Activation. [PDF]
Angew Chem Int Ed EnglMa C +5 more
europepmc +1 more source
Biobased Poly(dodecylene Furanoate) with Inherent Advantages in Performance and Circularity
ChemSusChem, EarlyView.Thanks to its inherent biomass furan motif that can promote polymer H‐bonding networks, biobased polyester PDDF is shown to exhibit advantages not only in performance (e.g., superior modulus, crystallinity, gas barrier properties) but also in end‐of‐life management (biodegradability and closed‐loop chemical circularity), as compared to petroleum‐based ...
Hesham Aboukeila +10 more
wiley +1 more source