Hydrophobic Silica Gels and Aerogels for Direct Air Capture: Hybrid Grafting To Suppress Water Uptake and Capillary Condensation. [PDF]
Ziemiański PP +7 more
europepmc +1 more source
Catalysts generated from the halogen‐bridged methylnaphthyl‐palladium dimer [Pd(1‐MeNAP)Br]2 and biarylphosphine ligands in combination with the base LiHMDS promote Buchwald‐Hartwig type aminations and para‐C─H arylations of non‐activated aryl fluorides already at 60 °C.
Jie Shen +4 more
wiley +1 more source
1,3-Dideazaguanosine in Atomic Mutagenesis Provides Unprecedented Insight Into Hydrogen Bonding and Stacking Interactions in Folded RNA. [PDF]
Oberlechner M, Micura R.
europepmc +1 more source
A small set of low‐valency multivalent 3,4,5‐trihydroxypiperidines was prepared through double reductive amination (DRA) of a sugar‐derived dialdehyde. Among them, trivalent derivative 37 emerged as a potent β‐glucocerebrosidase (GCase) inhibitor displaying an unexpected mixed‐type kinetic profile. The integration of kinetic analysis, NMR, docking, and
Maria Giulia Davighi +10 more
wiley +1 more source
Analytical Strategies for Natural Mono- and Disaccharide Isomer Differentiation: Techniques and Applications. [PDF]
Yang R, Deng Z, Liu J, Shi Z, Jiang Y.
europepmc +1 more source
Synthesis and Fluorescent Properties of Alkynylated 3‑Methylidenephthalides with Extended π‑Systems. [PDF]
Vidyakina AA +7 more
europepmc +1 more source
Aluminum–silicon adducts of NHC‐phosphinidenides are synthesized and structurally characterized. Their bonding and electronic structures are compared with those of isosteric NHC‐disilylsilylene complexes by DFT, NBO, and QTAIM analyses, highlighting the interplay of covalent versus coordinative interactions and emphasizing the significance of ...
Jayeeta Bhattacharjee +3 more
wiley +1 more source
Synthesis of Amino-<i>gem</i>-Bisphosphonate Derivatives and Their Application as Synthons for the Preparation of Biorelevant Compounds. [PDF]
Ordoñez M, Argüello Velasco RO.
europepmc +1 more source
Synthesis and Structure of Titanium Imido Complexes With Bi‐ and Tridentate PN and PNP Ligands
The synthesis of PN and PNP supported titanium imido complexes is presented with a variety of alkyl and aryl imido donors on the titanium center, giving access to new potential precatalysts in hydroamination catalysis. We report the synthesis of alkyl and aryl imido titanium(IV) complexes supported by bi‐ or tridentate PNMes and PNP ligands (PNMes = (2‐
Philipp Boos +4 more
wiley +1 more source
Triplett‐Metallovinylidene von Palladium und Platin auf Basis eines chelatisierenden P/Diazoalkens
Es wird eine neue Klasse an chelatisierenden Diazoalkenen vorgestellt und ihre Koordinationskomplexe mit Pd und Pt charakterisiert. Durch Bestrahlung wird ein N2‐Verlust erzeugt, wodurch erstmals spektroskopisch charakterisierte Triplet‐Metallovinylidene unter Verwendung von FD‐FT‐THz‐EPR‐Spektroskopie und SQUID‐Messungen nachgewiesen werden.
Max Amann +11 more
wiley +1 more source

