Unified Asymmetric Synthesis of Aryltetralin Lactone Cyclolignans via Conformation-Assisted Radical C-H Cyclization. [PDF]
Yin R, Wang X, Zhou R, Zhu L, Huang J.
europepmc +1 more source
After decades of research into metal alkylidyne complexes and their extensive use as catalysts for alkyne metathesis, one might think that there is nothing fundamentally new to be discovered in this field. The present study into formally d4‐configured Ru alkylidynes shows that this notion is incorrect: not only is a novel and convenient entry route ...
Mingxu Cui +3 more
wiley +1 more source
[3 + 2] Cycloaddition of thioformylium methylide with various arylidene-azolones in the synthesis of 7-thia-3-azaspiro[4.4]nonan-4-ones. [PDF]
Rudik DI +7 more
europepmc +1 more source
Triplet Metallovinylidenes of Palladium and Platinum Based on a Chelating P/Diazoalkene Ligand
A new class of chelating diazoalkenes is presented and their coordination complexes with Pd and Pt are characterized. Irradiation triggers N2 loss and gives access to the first triplet metallovinylidenes spectroscopically characterized utilizing FD‐FT THz‐EPR spectroscopy and SQUID measurements.
Max Amann +11 more
wiley +1 more source
Urea enhances the yield and quality of bio-oil produced from corncob through pyrolysis. [PDF]
Bello SI +3 more
europepmc +1 more source
Ring Strain‐Promoted Activation of Pyridines by a Saturated BSi2 Cycle
We report a highly strained boratadisilirane with the elusive anionic BSi2 ring motif. Cleavage of the Si─Si bond during reactions with pyridine derivatives activates them in three different ways: 1) for pyridine itself selective ortho‐CH activation and concomitant hydrogen transfer to a second pyridine molecule occurs, 2) with dimethylaminopyridine ...
Nasrina Parvin +5 more
wiley +1 more source
Identification of Diagnostic Biomarkers for Colorectal Polyps Based on Noninvasive Urinary Metabolite Screening and Construction of a Nomogram. [PDF]
Xie Y +7 more
europepmc +1 more source
Comparative analysis of complanadine A total syntheses. [PDF]
Al-Ahmad R, Dai M.
europepmc +1 more source
Antibacterial potential and chromatographic profiling of bioactive compounds from endophytic <i>Streptomyces</i> sp. strain MIRK71 isolated from <i>Mirabilis jalapa</i> (L.). [PDF]
Lalrokimi +10 more
europepmc +1 more source

