DFT investigation of the mechanism and role of N-heterocyclic carbene (NHC) in constructing asymmetric organosilanes using NHC-catalyzed [4+2] cycloaddition reaction. [PDF]
Alipour B.
europepmc +1 more source
Molecular Structure of Omniphobic, Surface-Grafted Polydimethylsiloxane Chains. [PDF]
Khatir B+10 more
europepmc +1 more source
Influence of Ionic Liquid Film Thickness and Flow Rate on Macrocyclization Efficiency and Selectivity in Supported Ionic Liquid-Liquid Phase Catalysis. [PDF]
Högler M+6 more
europepmc +1 more source
Plant Oil Nano-Emulsions as a Potential Solution for Pest Control in Sustainable Agriculture. [PDF]
Abd-Elnabi AD, El-Sawy EAF, Badawy MEI.
europepmc +1 more source
Stereodivergent Synthesis of Complex N-Sulfonimidoyl Lactams via the Castagnoli-Cushman Reaction. [PDF]
Spock M, Fettinger JC, Ando K, Shaw JT.
europepmc +1 more source
Bis(trimethylsilyl)phosphide chemistry: a half-century of advances across the periodic table.
Baldwin J, Mills DP.
europepmc +1 more source
Related searches:
The trimethylsilylation of acetylene
Chemical Communications, 2002The gas-phase reaction of Me3Si+ ions with acetylene is remarkably sensitive to the environment, leading to substitution products in radiolytic systems at atmospheric pressure and to rearranged adduct ions in the FT-ICR cell at 10−8 Torr, while seeming unproductive in an intermediate pressure range.
CHIAVARINO, Barbara+2 more
openaire +3 more sources
The Rearrangement of the trimethylsilyl group in (trimethylsilyl)pyrazoles
Journal of Organometallic Chemistry, 1971Abstract A new class of compounds, the N-(trimethylsilyl)pyrazoles, has been prepared. Four compounds with differing substituents on the pyrazole ring show non-equivalent 3,5-substituents in their NMR spectra. These compounds undergo temperature-dependent NMR spectral changes with the 3,5-substituents becoming equivalent at high temperatures.
Daniel H. O'Brien, Chang-po Hrung
openaire +2 more sources
MASS SPECTROMETRIC FRAGMENTATION OF TRIMETHYLSILYL AND RELATED ALKYLSILYL DERIVATIVES.
Mass spectrometry reviews (Print), 2019This review describes the mass spectral fragmentation of trimethylsilyl (TMS) and related alkylsilyl derivatives used for preparing samples for analysis, mainly by combined gas chromatography and mass spectrometry (GC/MS).
D. Harvey, P. Vouros
semanticscholar +1 more source
Chemical reduction of transition metals provides the corresponding low-valent transition metal species as a key step for generating catalytically active species in metal-assisted organic transformations and is a fundamental unit reaction for preparing ...
H. Tsurugi, K. Mashima
semanticscholar +1 more source