Bulky 2,6-disubstituted aryl siloxanes and a disilanamine
Acta Crystallographica Section E: Crystallographic Communications, 2020 The crystal structures of 5-bromo-1,3-di-tert-butyl-2-[(trimethylsilyl)oxy]benzene, C17H29BrOSi, (I), 1,3-di-tert-butyl-2-[(trimethylsilyl)oxy]benzene, C17H30OSi, (II), and N-(2,6-diisopropylphenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine ...
Flavia Marszaukowski +2 more
doaj +1 more source
Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents
Molecules, 2022 Derivatives of main group elements containing element–element bonds are characterized by unique properties due to σ-conjugation, which is an attractive subject for investigation.
Kirill V. Zaitsev +2 more
doaj +1 more source
In situ generation of Mes2Mg as a non-nucleophilic carbon-centred base reagent for the efficient one-pot conversion of ketones to silyl enol ethers [PDF]
, 2008 Treatment of commercially available MesMgBr with 1,4-dioxane produces the key Mes2Mg reagent in situ which then mediates the deprotonation of ketones to deliver trimethylsilyl enol ethers, at readily accessible temperatures and without any nucleophilic ...
Hayes, Douglas. +2 more
core +1 more source
Tetrakis(trimethylsilyl)distiban / Tetrakis (trimethylsilyl) distibane
Zeitschrift für Naturforschung B, 1979 Abstract Tetrakis(trimethylsilyl)distibane, (Me3Si)4Sb2 is produced by reaction of tris(trimethylsilyl) stibine, (Me3Si)3Sb, with three or less than three equivalents of t-butyl iodide, with trimethyliodosilane, Me3SiI and iodine. The reaction of (Me3Si)3Sb with three or more equivalents of i-butyl iodide and methyl iodide also yields ...
Vassiliki Breunig-Lyriti +1 more
openaire +2 more sources
N-heterocyclic carbene catalyzed additions of 3-trimethylsilyl propiolate to aldehydes
Journal of Saudi Chemical Society, 2016 A N-heterocyclic carbene (NHC) catalyzed addition reaction of 3-trimethylsilyl propiolate with aldehydes has been developed. Under the catalysis of 2 mol% NHCs, benzaldehyde, furfural, β-naphthaldehyde, meta- and para-substituted aromatic aldehydes ...
Guang-Fen Du +3 more
doaj +1 more source
Self-organization of hydrophobic soil and granular surfaces [PDF]
, 2007 Soil can become extremely water repellent following forest fires or oil spillages, thus preventing penetration of water and increasing runoff and soil erosion. Here the authors show that evaporation of a droplet from the surface of a hydrophobic granular
Dekker L. W. +5 more
core +1 more source
PECULIARITIES OF ISOCYANATES INTERACTION WITH HYDRAZINE DERIVATIVES
Тонкие химические технологии, 2018 The results of studies on chemical transformations of organic and organosilicon isocyanates in their interaction with hydrazine derivatives have been summarized in this review.
A. D. Kirilin +4 more
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Metabolomic analysis by UAE-GC MS and antioxidant activity of Salvia hispanica (L.) seeds grown under different irrigation regimes [PDF]
, 2018 Chia (Salvia hispanica L.) is an emerging crop with a high content of α-linolenic acid and metabolites of industrial and pharmaceutical interest but information on metabolome variations in response to agricultural management is scarce.
Amato, Mariana +4 more
core +1 more source
Electrochemistry, 2020 In this study, we have demonstrated electrochemical synthesis of polyphenylene (PP) deriving from 1,4-bis(trimethylsilyl)benzene using a flow microreactor.
Yuto NAKAMURA +3 more
doaj +1 more source
Pd-Catalyzed α-Arylation of Trimethylsilyl Enolates of α,α-Difluoroacetamides
Journal of the American Chemical Society, 2014 We report the arylation and heteroarylation of α,α-difluoro-α-(trimethylsilyl)acetamides with aryl and heteroaryl bromides catalyzed by an air- and moisture-stable palladacyclic complex containing P(t-Bu)2Cy as ligand.
Shaozhong Ge +3 more
semanticscholar +1 more source