Results 21 to 30 of about 61,381 (342)

PECULIARITIES OF ISOCYANATES INTERACTION WITH HYDRAZINE DERIVATIVES

Тонкие химические технологии, 2018
The results of studies on chemical transformations of organic and organosilicon isocyanates in their interaction with hydrazine derivatives have been summarized in this review.
A. D. Kirilin, L. O. Belova, N. I. Kirilina, A. V. Petrogradsky, N. L. Shembel   +4 more
doaj   +1 more source

Reactions of Dihaloboranes with Electron-Rich 1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadienes

Molecules, 2020
The reactions of electron-rich organosilicon compounds 1,4-bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene (1), 2,3,5,6-tetramethyl-1,4-bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene (2), and 1,1′-bis(trimethylsilyl)-1,1′-dihydro-4,4′-bipyridine (12 ...
Li Ma, Xiaolin Zhang, Wenbo Ming, Shengxin Su, Xiaoyong Chang, Qing Ye   +5 more
doaj   +1 more source

Pd-Catalyzed α-Arylation of Trimethylsilyl Enolates of α,α-Difluoroacetamides

Journal of the American Chemical Society, 2014
We report the arylation and heteroarylation of α,α-difluoro-α-(trimethylsilyl)acetamides with aryl and heteroaryl bromides catalyzed by an air- and moisture-stable palladacyclic complex containing P(t-Bu)2Cy as ligand.
Shaozhong Ge, Sophie I Arlow, Michael G. Mormino, J. Hartwig   +3 more
semanticscholar   +1 more source

Development of (Trimethylsilyl)ethyl Ester Protected Enolates and Applications in Palladium-Catalyzed Enantioselective Allylic Alkylation: Intermolecular Cross-Coupling of Functionalized Electrophiles

Organic Letters, 2014
The development of (trimethylsilyl)ethyl ester protected enolates is reported. The application of this class of compounds in palladium-catalyzed asymmetric allylic alkylation is explored, yielding a variety of α-quaternary six- and seven-membered ketones
Corey M. Reeves, D. Behenna, B. Stoltz
semanticscholar   +1 more source

Exploring the transport properties of equatorially low coordinated erbium single ion magnets [PDF]

, 2019
Single-molecule spin transport represents the lower limit of miniaturization of spintronic devices. These experiments, although extremely challenging, are key to understand the magneto-electronic properties of a molecule in a junction. In this context, theoretical screening of new magnetic molecules provides invaluable knowledge before carrying out ...
arxiv   +1 more source

Silylaryl triflates in the formation of arynes with application in the preparation of N,N-diarylamino acid derivatives

Orbital: The Electronic Journal of Chemistry, 2012
Through this work we are developing our research involving the formation of arynes from 2-(trimethylsilyl)aryl triflates, under relatively mild reaction conditions.
Danilo Y. Albuquerque, Irlon M. Ferreira, Cristiano Raminelli   +2 more
doaj   +1 more source

Solution-processed sky-blue phosphorescent organic light-emitting diodes based on 2-(5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene-8-yl)-4-(trimethylsilyl)pyridine chelated iridium complex

Journal of Information Display, 2022
A new 2-(5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene-8-yl)-4-(trimethylsilyl)pyridine-based iridium complex was synthesized for efficient solution-processed sky-blue phosphorescent organic light-emitting diodes (PhOLEDs).
Yeong Heon Jeong, Chul Woong Joo, Hyein Jeong, Jonghee Lee, Yun-Hi Kim   +4 more
doaj   +1 more source

[μ-Bis(trimethylsilyl)amido]bis[μ-N,N-dimethyl-N′,N′′-bis(trimethylsilyl)guanidinato]-triangulo-tricopper(I)

Acta Crystallographica Section E, 2009
The title compound, [Cu3(C6H18NSi2)(C9H24N3Si2)2], is a trinuclear CuI complex. A crystallographic twofold axis passes through one CuI atom and the N atom of the bis(trimethylsilyl)amide ligand that bridges between the other two CuI atoms.
Donglong Guo, Xiaoli Qiao, Hong-Bo Tong, Meisu Zhou   +3 more
doaj   +1 more source

N-(Trimethylsilyl)methanesulfonamide

Acta Crystallographica Section E, 2011
There are two molecules in the asymmetric unit of the title compound, C4H13NO2SSi. In the crystal, molecules are linked via intermolecular N—H...O hydrogen bonds, forming chains along [001].
Alan J. Lough, Sossina Gezahegna, Andrew R. McWilliams   +2 more
doaj   +1 more source

Synthesis of Aminobisphosphinates through a Cascade Reaction between Hypophosphorous Acid and Bis(trimethylsilyl)imidates Mediated by ZnI₂

Molecules, 2023
Among phosphorylated derivatives, phosphinates occupy a prominent place due to their ability to be bioisosteres of phosphates and carboxylates. These properties imply the necessity to develop efficient methodologies leading to phosphinate scaffolds.
Nouha Ayadi, Aurélie Descamps, Thibaut Legigan, Jade Dussart-Gautheret, Maelle Monteil, Evelyne Migianu-Griffoni, Taïcir Ben Ayed, Julia Deschamp, Marc Lecouvey   +8 more
doaj   +1 more source