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[μ-Bis(trimethylsilyl)amido]bis[μ-N,N-dimethyl-N′,N′′-bis(trimethylsilyl)guanidinato]-triangulo-tricopper(I)

open access: yesActa Crystallographica Section E, 2009
The title compound, [Cu3(C6H18NSi2)(C9H24N3Si2)2], is a trinuclear CuI complex. A crystallographic twofold axis passes through one CuI atom and the N atom of the bis(trimethylsilyl)amide ligand that bridges between the other two CuI atoms.
Donglong Guo   +3 more
doaj   +1 more source

Silylation of Carbohydrate Syrups [PDF]

open access: yes, 1979
Introduction Carbohydrates are usually difficult to analyze in solutions. Gas chromatography provides a suitable means for analysis. However most carbohydrate compounds are not volatile enough for use by this method.
Gorwitz, Mark
core   +1 more source

Rapid Deep Vat Printing Using Photoclickable Collagen‐Based Bioresins

open access: yesAdvanced Healthcare Materials, EarlyView.
Collagen‐based resin formulations based on thiol‐ene photoclick chemistry are demonstrated. These resins enable easy handleability under neutral conditions and further allow facile fabrication of multicellular tissue constructs via tomographic or FLight printing.
Michael Winkelbauer   +8 more
wiley   +1 more source

Fully Chlorinated N-Silyl Amides of Titanium and Tungsten [PDF]

open access: yes, 1997
The reaction of hexachlorodisilazanyllithium (Cl3Si)2NLi (1), with TiCl4 leads selectively to the novel fully chlorinated amides (Cl3Si)2NTiCl3 (2) or [(Cl3Si)2N]2 TiCl2 (3), respectively, depending on the molar ratio of the starting materials.
Milius, Wolfgang   +2 more
core   +1 more source

Supramolecular Chemistry in Metal–Organic Framework Materials

open access: yesAdvanced Materials, EarlyView.
This review highlights synergies between reticular chemistry and supramolecular chemistry. The role of supramolecular interactions in determining framework…guest interactions and attempts to understand dynamic behavior in metal–organic frameworks (MOFs), particularly emphasizing the development of crystal sponges, studying reactions in frameworks and ...
Eugenia Miguel‐Casañ   +3 more
wiley   +1 more source

6,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol)

open access: yesMolbank, 2013
Functionalizable salen derivative, 6,6'-(1E,1'E)-((1R,2R)-1,2-diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl) ethyn-yl)phenol) (3), was synthesized by condensation between (1R,2R)-1,
David Díaz Díaz   +4 more
doaj   +1 more source

Synthesis of Aminobisphosphinates through a Cascade Reaction between Hypophosphorous Acid and Bis(trimethylsilyl)imidates Mediated by ZnI2

open access: yesMolecules, 2023
Among phosphorylated derivatives, phosphinates occupy a prominent place due to their ability to be bioisosteres of phosphates and carboxylates. These properties imply the necessity to develop efficient methodologies leading to phosphinate scaffolds.
Nouha Ayadi   +8 more
doaj   +1 more source

Metabolomics driven analysis by UAEGC-MS and antioxidant activity of Chia (Salvia hispanica L.) commercial and mutant seeds [PDF]

open access: yes, 2018
Chia is a food plant producing seeds which have seen increasing interest owing to their health benefits. This work is the first report on the metabolite profile, total polyphenols and antioxidant activity of chia seeds, determined by ultrasound-assisted ...
Amato, Mariana   +4 more
core   +1 more source

A Perspective on Pathways Toward Commercial Sodium‐Ion Batteries

open access: yesAdvanced Materials, EarlyView.
Comprehensive analysis of the existing and prospective sodium‐ion battery (SIB) systems unveils that a wider application of SIBs should primarily focus on i) regulating the composition, morphology, surface chemistry, safety performance, and production feasibility of mainstream cathodes, ii) enhancing the high‐voltage stability, film formation ability ...
Zehao Cui, Chen Liu, Arumugam Manthiram
wiley   +1 more source

2-Acetylamino-1,3,4,6-tetra-O-(trimethylsilyl)-2-deoxy-α-d-glucopyranose

open access: yesActa Crystallographica Section E, 2013
The title compound, C20H47NO6Si4, was synthesized by per-O-trimethylsilylation of N-acetyl-d-glucosamine using chlorotrimethylsilane in the presence of hexamethyldisiloxane. The trimethylsilyl group and acetamido group are located on the same side of the
Zhao-Dong Cheng   +2 more
doaj   +1 more source

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