Results 81 to 90 of about 61,381 (342)

Iridium-catalyzed anti-diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol or aldehyde oxidation level.

open access: yesJournal of the American Chemical Society, 2010
Using the ortho-cyclometalated pi-allyl iridium precatalyst (R)-I derived from [Ir(cod)Cl](2), 4-cyano-3-nitrobenzoic acid, (R)-SEGPHOS, and allyl acetate, enantioselective transfer hydrogenation of alpha-(trimethylsilyl)allyl acetate in the presence of ...
S. Han, Xin Gao, M. Krische
semanticscholar   +1 more source

Gas-liquid chromatographic separation of aldose enantiomers as trimethylsilyl ethers of methyl 2-(polyhydroxyalkyl)thiazolidine-4(R)-carboxylates

open access: yes, 1987
Pairs of enantiomers of nine aldoses were separated by gas-liquid chromatography on an OV-17 capillary column as the trimethylsilyl ethers of methyl 2- (polyhydroxyalkyl) -thiazolidine-4 (R) -carboxylates, which were obtained by the reaction of aldoses ...
S. Hara, H. Okabe, K. Mihashi
semanticscholar   +1 more source

Bis(trimethylsilyl)-phosphaethene und Tris(trimethylsilyl)silyl-fluorphosphane

open access: yesZeitschrift für Naturforschung B, 1984
Abstract Phosphaethenes of the type (Me3Si)2C = P -NRSiMe3 R = C10H15 (7), CMe3 (8), 2.4.6-Me3C6H2 (10)), LiF, and Me3SiF are obtained in the reaction of the aminodifluorophosphanes (3-5) with the lithium salt of tris(trimethylsilyl)methane (1). 10 is isolated as by-product. The main product is F2PC(SiMe3)3 (9). The lithium salt of tris(
Uwe Klingebiel   +2 more
openaire   +2 more sources

Escape from Flatland: Stereoselective Synthesis of Hexa‐aryl Borazines and their sp²‐Based 3D Architectures

open access: yesAngewandte Chemie International Edition, Accepted Article.
Borazine and its derivatives can be considered critical doping units for engineering hybrid C(sp2)‐based molecules with tailored optoelectronic properties. Herein, we report the first synthesis of hexaarylborazines that, bearing ortho‐substituted aryl moieties, extend three‐dimensionally.
Vivek C Wakchaure   +8 more
wiley   +1 more source

One-Pot, Highly Stereoselective Synthesis of Dithioacetal-α,α-Diglycosides

open access: yesMolecules, 2018
A one-step access to dithioacetal-α,α-diglycosides is reported. The synthetic strategy is based on the thioacetalization of aldehydes or ketones via highly stereoselective ring-opening of 1,6 anhydrosugars with bis(trimethylsilyl)sulfide.
Maria F. Céspedes Dávila   +4 more
doaj   +1 more source

Bis(stearoyl) Sulfide: A Stable, Odor-free Sulfur Precursor for High-Efficiency Metal Sulfide Quantum Dot Photovoltaics [PDF]

open access: yesarXiv
The synthesis of metal sulfide nanocrystals is a crucial step in the fabrication of quantum dot (QD) photovoltaics. Control over the quantum dot size during synthesis allows for precise tuning of their optical and electronic properties, making them an appealing choice for electronic applications.
arxiv  

Analisis Komposisi Kimia Daun Kelakai (Stenochlaena palustris Bedd.) dengan Berbagai Pelarut menggunakan GCMS (Chemical Composition Analysis of Stenochlaena palustris Bedd. Leaves using Various Solvents on GCMS)

open access: yesJurnal Riset Industri Hasil Hutan, 2017
The selection of suitable solvents is essential for extracting the desired compounds from plant cells. GCMS is an instrument that can be used to identify such compounds.
Nurmilatina Nurmilatina
doaj   +1 more source

Improved Synthesis of 1,2-Bis(trimethylsilyl)benzenes using Rieke-Magnesium or the Entrainment Method

open access: yes, 2010
1,2-Bis(trimethylsilyl)benzene is the key starting material for the synthesis of efficient benzyne precursors and certain luminescent π-conjugated materials.
Andreas Lorbach   +4 more
semanticscholar   +1 more source

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