Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism
Chemistry – A European Journal, EarlyView.A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew +3 more
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Innovative Strategies in X-ray Crystallography for Exploring Structural Dynamics and Reaction Mechanisms in Metabolic Disorders. [PDF]
J Pers MedGrieco A +2 more
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N─H or O─H Bond Activation With a Bicyclic Si4 Ring Compound
Chemistry – A European Journal, EarlyView.The bicyclic Si4 ring compound with zwitterionic character reacts with NH3, H2O, and selected alcohols to give functionalized saturated silicon rings, siliconoid clusters with unsubstituted Si atoms, or simple 1,3‐addition products. The experimentally observed reactivity could be rationalized based on results from mechanistic calculations employing ...
Michael Quest +7 more
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Understanding Cation-Anion Ionic Bonding in Tetramethylammonium Salts: Insights from Density Functional Theory and X-ray Crystallography. [PDF]
ACS OmegaHollinsed WC, Taber A.
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Mild C─F Activation of Azido(per)Fluoroalkanes
Chemistry – A European Journal, EarlyView.Mild and selective activation of C(sp3)–F bonds in azido(per)fluoroalkanes using thiolates was developed, leading to novel functionalized azides. The reaction is initiated by nucleophilic attack of the sulfur atom to the terminal nitrogen of the azido group, followed by fluoride ion elimination.
Olena Shaitanova +7 more
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Exploring the Antibacterial and Antibiofilm Efficacy of Psammogeton biternatum Edgew and Identification of a Novel Quinoline Alkaloid using X-ray Crystallography. [PDF]
ACS OmegaMasood F +10 more
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Stepwise Synthesis of Tetrabenzotriazaporphyrins (TBTAPs) and Their Open 2‐ and 3‐Ring Fragments
Chemistry – A European Journal, EarlyView.Unexpected reaction pathways to porphyrin‐phthalocyanine hybrids are uncovered by the synthesis of “half‐macrocycle” fragments and subsequent macrocyclization. Rather than the expected 2:2 “ABBA” product, the 3:1 “ABBB” hybrid is isolated as the only macrocyclic product.
Jacob Gretton +10 more
wiley +1 more source
Ray-tracing analytical absorption correction for X-ray crystallography based on tomographic reconstructions. [PDF]
J Appl CrystallogrLu Y +11 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.Ni2 bispincer complexes with an embedded central imido anchor are presented. The bispincer complexes leverage the high basicity of imido ligands to facilitate 1,2 addition of weak B─H and Si─H bonds, resulting in hydrido–amido complexes and resultingly a contortion of a Ni─Ni sigma bond to form an S = 1 species. The 1,2 addition is proposed to serve as
David de los Santos +2 more
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