Results 181 to 190 of about 289,056 (278)

Convergent-beam attosecond x-ray crystallography. [PDF]

Struct Dyn
Chapman HN, Li C, Bajt S, Butola M, Dresselhaus JL, Egorov D, Fleckenstein H, Ivanov N, Kiene A, Klopprogge B, Kremling V, Middendorf P, Oberthuer D, Prasciolu M, Scheer TES, Sprenger J, Wong JC, Yefanov O, Zakharova M, Zhang W.   +19 more
europepmc   +1 more source

A Novel Heterometallic Ring {Cr5Ni3} and New {Cr6Co2} and {Cr6Zn2} Rings

Chemistry – A European Journal, EarlyView.
A novel heterometallic ring containing five Cr(III) and three Ni(II) centers is reported. It forms an octagon and has a single isomer, as revealed by a combination of magnetic and EPR studies and collision‐induced dissociation mass spectrometry. ABSTRACT A new heterometallic ring, [Me4N][(Me4N)2Cr5Ni3F8(BTFB)16] (BTFB = 3,5‐bis(trifluoromethyl)benzoate)
Abdulelah Alsuhaymi, Niklas Geue, Adam Brookfield, Grigore A. Timco, Selena J. Lockyer, Gareth D. Smith, George F. S. Whitehead, Perdita E. Barran, David Collison, Richard E. P. Winpenny   +9 more
wiley   +1 more source

Instrumentation and methods for efficient time-resolved X-ray crystallography of biomolecular systems with sub-10 ms time resolution. [PDF]

IUCrJ
Indergaard JA, Mahmood K, Gabriel L, Zhong G, Lastovka A, McLeod MJ, Thorne RE.   +6 more
europepmc   +1 more source

Phosphorescent Iridium Hydrazinonicotinic Acid (HYNIC) Complexes That Bind to Prostate Specific Membrane Antigen: Potential Photodynamic Therapy of Prostate Cancer

Chemistry – A European Journal, EarlyView.
A phosphorescent iridium(III) complex has been prepared with a 6‐hydrazinonicotinic acid (HYNIC) ligand tethered to a lysine‐ureido‐glutamatic acid pharmacophore, which binds to an enzyme, called prostate‐specific membrane antigen (PSMA), which is overexpressed in prostate cancer.
La'El Kimchi, Emily R. McGowan, Katherine A. Morgan, Jonathan M. White, Trevor A. Smith, Stacey E. Rudd, Paul S. Donnelly   +6 more
wiley   +1 more source

A Low‐Symmetry FeII Tetrahedron From a Flexible Tritopic Ligand

Chemistry – A European Journal, EarlyView.
A highly symmetric and flexible tris‐bidentate tritopic ligand forms an S4 meso homoleptic face‐capped FeII tetrahedron near‐quantitatively in acetonitrile. The addition of nitromethane solvent causes partial isomerization of this meso cage to the racemic homochiral tetrahedron, with the complexity of the system being moderated through solvophobic ...
Rosemary J. Goodwin, Nina R. Lawson, Michael G. Gardiner, Jack D. Evans, Paul E. Kruger, Dan Preston   +5 more
wiley   +1 more source

Transcription-Coupled Template Reconfiguration of 8-Oxoguanine for Error-Prone Transcription Revealed by Time-Resolved X-ray Crystallography and Molecular Dynamics. [PDF]

J Am Chem Soc
Oh J, Konovalov KA, Hou P, Chong J, Huang X, Wang D.   +5 more
europepmc   +1 more source

Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives

Chemistry – A European Journal, EarlyView.
Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch, Krzysztof Piech, Aurélien Crochet, Andreu Tortajada   +3 more
wiley   +1 more source

Stereoselective Higher‐Order [10+4]‐ and [10+6] Cycloadditions Between Two Highly Unsaturated and Ambiphilic π‐Addends

Chemistry – A European Journal, EarlyView.
Aminocatalytically generated isobenzofulvenes and 3‐oxidopyridinium betaines act as ambiphilic reaction partners in orbital‐symmetry‐allowed [10+4] cycloadditions or formally symmetry‐forbidden concerted thermal [10+6] cycloadditions. The reaction furnishes three cycloadducts: one [10+4] cycloadduct and two regioisomeric [10+6] cycloadducts.
Jonas Faghtmann, Anne Kristensen, Fabien Fritz, Signe Sofie Pladsbjerg Andresen, Anne Rask Østergaard, Johannes Nygaard Lamhauge, K. N. Houk, Karl Anker Jørgensen   +7 more
wiley   +1 more source

Crystal engineering of a 1:1 5-fluoro-cytosine-4-hy-droxy-benzaldehyde cocrystal: insights from X-ray crystallography and Hirshfeld analysis. [PDF]

Acta Crystallogr E Crystallogr Commun
Sangavi M, Mohana M, Butcher RJ, McMillen CD.   +3 more
europepmc   +1 more source

Antisolvent crystallization of lithium hydroxide monohydrate: Significant factors and kinetics analysis

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Crystallization is the final stage in lithium hydroxide monohydrate (LiOH · H2O) production, and antisolvent crystallization offers a lower‐energy route compared with evaporative methods. In this study, we investigated bench‐scale ethanol‐based antisolvent crystallization of LiOH · H2O, and identified the significant impact parameter via a ...
Chentao He, Liuyin Xia
wiley   +1 more source