Results 201 to 210 of about 184,219 (281)

Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism

open access: yesChemistry – A European Journal, EarlyView.
A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew   +3 more
wiley   +1 more source

N─H or O─H Bond Activation With a Bicyclic Si4 Ring Compound

open access: yesChemistry – A European Journal, EarlyView.
The bicyclic Si4 ring compound with zwitterionic character reacts with NH3, H2O, and selected alcohols to give functionalized saturated silicon rings, siliconoid clusters with unsubstituted Si atoms, or simple 1,3‐addition products. The experimentally observed reactivity could be rationalized based on results from mechanistic calculations employing ...
Michael Quest   +7 more
wiley   +1 more source

Peroxodisulfate‐Enhanced Leaching of Deep‐Sea Manganese Crusts and Sulfides

open access: yesChemie Ingenieur Technik, EarlyView.
Ammonium peroxodisulfate enables efficient leaching of deep‐sea manganese crusts and massive sulfides while offering electrolytic recycling. High leaching yields for V, Mn, Co, Mo, Sn, and W, along with complete leaching of As and Sb, highlight its potential as a powerful and sustainable oxidant for marine resource processing.
Bastian Hansel   +5 more
wiley   +1 more source

Automated multiconformer model building for X-ray crystallography and cryo-EM. [PDF]

open access: yesElife
Wankowicz SA   +9 more
europepmc   +1 more source

Antisolvent crystallization of lithium hydroxide monohydrate: Significant factors and kinetics analysis

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Crystallization is the final stage in lithium hydroxide monohydrate (LiOH · H2O) production, and antisolvent crystallization offers a lower‐energy route compared with evaporative methods. In this study, we investigated bench‐scale ethanol‐based antisolvent crystallization of LiOH · H2O, and identified the significant impact parameter via a ...
Chentao He, Liuyin Xia
wiley   +1 more source

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