Results 191 to 200 of about 132,637 (291)

Exploration of the Interconversion of Uranium Anilido and Imido Species

ChemistryEurope, EarlyView.
Exploring the reactivity of the trivalent U(NHDIPP)5K2(THF)4 (1) leads to the formation of uranium imido complexes. Treating 1 with 18c6 causes spontaneous oxidation and the formation of [U(NDIPP)(NHDIPP)4][K(18c6)(THF)]2 (2). Oxidation of 1 or 2 results in the formation of U(NDIPP)2(NHDIPP)2 (3).
Kelly L. Gullett, Nickolas H. Anderson, MacKenzie C. Weaver, Landon O. King, Matthias Zeller, Suzanne C. Bart   +5 more
wiley   +1 more source

AnACor2.0: a GPU-accelerated open-source software package for analytical absorption corrections in X-ray crystallography. [PDF]

J Appl Crystallogr
Lu Y, Adámek K, Stefanic T, Duman R, Wagner A, Armour W.   +5 more
europepmc   +1 more source

Aluminum versus Gallium: Differences in Bis(bis(trimethylsilyl)methyl) Element Halides, Hydrides, and Oxygen‐Bridged E/P Frustrated Lewis Pairs

ChemistryEurope, EarlyView.
Reacting Bis2GaBr (Bis = CH(SiMe3)2) with Bis2AlH selectively yields Bis2GaH, a monomeric hydride in solution, characterized by diffusion ordered spectroscopy NMR, infrared spectroscopy and indirectly via hydrogallation. A one‐pot route enables frustrated Lewis pairs Bis2EOPtBu2 (E = Al, Ga), with the gallium analog splitting H2 and showing a dynamic ...
Julian Buth, Maximilian J. Klingsiek, Yury V. Vishnevskiy, Andreas Mix, Jan-Hendrik Lamm, Beate Neumann, Hans-Georg Stammler, Norbert Werner Mitzel   +7 more
wiley   +1 more source

Direct observation of electron transfer in solids through X-ray crystallography. [PDF]

Nat Commun
Ogata D, Koide S, Kishi H, Yuasa J.
europepmc   +1 more source

The Challenging P‐Alkylation of Aromatic Phosphorus Heterocycles and Follow‐Up Reactions

ChemistryEurope, EarlyView.
P‐alkylation of λ3σ2‐phosphinines is hindered by weak nucleophilicity and scarce synthetic access, previously requiring multistep routes or extreme electrophiles. A direct ambient‐condition method is reported using 3,5‐bis(trimethylsilyl)‐phosphinine/B(C6F5)3 with esters or iso(thio)cyanates to generate stable 1‐R‐phosphininium salts.
Samantha Frank, Ádám Horváth, Duy Nguyen, Moritz J. Ernst, Simon Steinhauer, Zoltán Benkő, Christian Müller   +6 more
wiley   +1 more source

Automated multiconformer model building for X-ray crystallography and cryo-EM. [PDF]

Elife
Wankowicz SA, Ravikumar A, Sharma S, Riley B, Raju A, Hogan DW, Flowers J, van den Bedem H, Keedy DA, Fraser JS.   +9 more
europepmc   +1 more source

Stoructural science and various functions in hydorogen-bond materials. Hydration Structures of Protein Molecules Revealed by Cryogenic X-ray Crystallography.

, 1998
Masayoshi Nakasako
openalex   +2 more sources

Conformational Trajectory of the Molecular Chameleon Grazoprevir from Formulation to Target‐Bound

Chemistry – A European Journal, EarlyView.
ABSTRACT Macrocycles represent a promising class of beyond‐rule‐of‐5 (bRo5) therapeutics, capable of targeting proteins traditionally considered undruggable by conventional small molecules. Macrocycles exhibit intrinsic flexibility and often display a “chameleon‐like” ability to adapt to their environment, thereby enhancing their oral bioavailability ...
Lianne H. E. Wieske, Guanhong Bu, Máté Erdélyi, Jan Kihlberg, Tamir Gonen, Emma Rova Danelius   +5 more
wiley   +1 more source

Innovative Strategies in X-ray Crystallography for Exploring Structural Dynamics and Reaction Mechanisms in Metabolic Disorders. [PDF]

J Pers Med
Grieco A, Quereda-Moraleda I, Martin-Garcia JM.   +2 more
europepmc   +1 more source